The highest and lowest energy conformations of giving compound should be drawn. Concept Introduction: Newman projection: The conformational isomers are representing by the Newman projection drawing . Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom. The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain. In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle. The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained. The highest energy conformation is eclipsed and lowest energy conformation is staggered. Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Question

Macmillan Learning Draw the major, neutral organic product for each substitution reaction. For this question, assume that each substitution reaction goes to completion. Disregard elimination. Reaction A. CI H₂O Select Draw Templates More Erase C H

Answer 1

Question

Chapter 4.8, Problem 20PTS

(a)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(b)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(c)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(d)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

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Macmillan Learning Draw the major, neutral organic product for each substitution reaction. For this question, assume that each substitution reaction goes to completion. Disregard elimination. Reaction A. CI H₂O Select Draw Templates More Erase C H

Macmillan Learning Reaction B: CI HO_ 곳으 / Select Draw Templates More с € H D Erase

When 2-bromo-93-dimethylbutane is heated with sodium methoxide, one majors.. në la formed. 4th attempt Part 1 (0.5 point) t Ji See Periodic Table See Hint Draw the major alkene product and all other byproducts. Be sure to include lone-pair electrons and charges. Part 2 (0.5 point) What type of mechanism is occuring? Choose one: AS1 3rd attempt X H 41 See Hint Part 1 (0.5 point) Feedback See Periodic Table See Hint

Answer 2

Question

Chapter 4.8, Problem 20PTS

(a)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(b)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(c)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(d)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

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Answer 3

Question

Chapter 4.8, Problem 20PTS

(a)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(b)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(c)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(d)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

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Answer 4

Question

Chapter 4.8, Problem 20PTS

(a)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(b)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(c)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(d)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

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Answer 5

Chapter 4.8, Problem 20PTS

(a)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(b)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(c)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

(d)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 6

Chapter 4.8, Problem 20PTS

(a)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 7

Chapter 4.8, Problem 20PTS

(a)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The highest and lowest energy conformations of giving compound should be drawn.

Concept Introduction:

Newman projection:

The conformational isomers are representing by the Newman projection drawing.

Newman projection representing by front carbon atom connected to 3 groups then the 3 groups connected circle is a back carbon atom.

The dark wedge is represent the out of the plain then the light wedge is represent the inside the plain.

In the Newman projection, the atoms or groups are attached to the center carbon by angle of 60° and this is called as a dihedral angle.

The dihedral angle is varying by the rotation of C-C bond, result of this there are two conformations are obtained and this are staggered and eclipsed conformations obtained.

The highest energy conformation is eclipsed and lowest energy conformation is staggered.

Interaction between the groups present in the front and back carbon atoms are increases the energy of a compound all so increases.

Answer 14

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Ch. 4.2 - Prob. 1LTS Ch. 4.2 - Prob. 1PTS Ch. 4.2 - Prob. 2ATS Ch. 4.2 - Prob. 3ATS Ch. 4.2 - Prob. 4ATS Ch. 4.2 - Prob. 2LTS Ch. 4.2 - Prob. 5PTS Ch. 4.2 - Prob. 6ATS Ch. 4.2 - Prob. 3LTS Ch. 4.2 - Prob. 7PTS

Chapter 4 Solutions