The axial 5-hydroxy-1,3dioxane is more stable than equatorial position should be explained. Concept Introduction: Conformational isomers: The two or more compounds have same molecular formula and different structural formulas are called conformational isomers. The Cyclohexane have a chair and boat conformations. The chair conformations of Cyclohexane have a axial and equatorial positions. The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position. The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position . The substitution present in the equatorial position is more stable than axial because of 1,3-diaxial interactions are less in equatorial position. Intramolecular hydrogen bonding: The bond between the electronegative atom and bonded hydrogen present in the same compound is called is called intramolecular hydrogen bonding.

Question

Want to see the full answer?

Answer 1

Question

Chapter 4.12, Problem 30CC

Interpretation Introduction

Interpretation:

The axial 5-hydroxy-1,3dioxane is more stable than equatorial position should be explained.

Concept Introduction:

Conformational isomers:

The two or more compounds have same molecular formula and different structural formulas are called conformational isomers.

The Cyclohexane have a chair and boat conformations.

The chair conformations of Cyclohexane have a axial and equatorial positions.

The atom or group is occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.

The atom or group is occupy at similar to horizontal axis passing through the chair conformation of ring is called equatorial position.

The substitution present in the equatorial position is more stable than axial because of 1,3-diaxial interactions are less in equatorial position.

Intramolecular hydrogen bonding:

The bond between the electronegative atom and bonded hydrogen present in the same compound is called is called intramolecular hydrogen bonding.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

20.17 Predict the structure of the major product formed by 1,2-addition of HBr to 3-methylenecyclohexene. 3-Methylenecyclohexene 20.18 Predict the major product formed by 1,4-addition of HBr to 3-methylenecyclohexene.

+ Draw a vicinal alkyl bromide that would produce the following alkene in an E2 elimination. Use a dash or wedge bond to indicate stereochemistry on asymmetric centers, where applicable. Ignore any inorganic byproducts. Br Drawing Strong Base H Q Atoms, Bonds Charges and Rings Draw or tap a new bond to see suggestions. Remove Done 語 Reset Undo + Drag To Pan

Draw a vicinal alkyl bromide that would produce the following alkene in an E2 elimination. Use a dash or wedge bond to indicate stereochemistry on asymmetric centers, where applicable. Ignore any inorganic byproducts. + Drawing Į Strong Base H Br Q Atoms, Bonds and Rings Charges Draw or tap a new bond to see suggestions. Undo Reset 謂 Remove Done Drag To Pan +