Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Textbook Question
Chapter 4.7, Problem 4.22YT
Skill Building Methane—Flat or Tetrahedral?
- a. If the methane molecule were flat, as the two-dimensional Lewis structure seems to predict, what would the H─C─H bond angle be?
- b. Offer a reason why the tetrahedral shape, not the two-dimensional flat shape, is more advantageous for this molecule.
Hint: Think about the position of electrons around the carbon atom.
- c. Consider the part of the music stand circled in yellow, shown in Figure 4.9. In the analogy of shape using a music stand, where would the carbon atom be located? Where would each of the hydrogen atoms be?
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Q1: Predict the major organic product(s) of the following reactions. Include stereochemistry
when necessary. Write NR if no reaction, try to explain.
1.) LDA, THF
2.)
СОН
CI
OH
H2SO4, heat
OH
m......
OH
1.) PCC, CH2Cl2
2.) CH3CH2MgBr, THF
3.) H3O+
4.) TsCl, pyr
5.) tBuOK, tBuOH
1.) SOCI 2, CHCI 3
2.) CH3CH2ONA, DMF
OH
1.) HBr
2.) Mg, THF
3.) H₂CO, THE
4.) H3O+
OH
NaH, THF
What is the stepwise mechanism for this reaction?
Draw the major product of this reaction
Chapter 4 Solutions
Chemistry In Context
Ch. 4.1 - You Decide What Do You Know About the Big C? In...Ch. 4.1 - Prob. 4.3YTCh. 4.1 - Prob. 4.4YTCh. 4.1 - Skill Building Polyatomic Ions II Name each of...Ch. 4.1 - Prob. 4.6YTCh. 4.2 - Prob. 4.7YTCh. 4.2 - Prob. 4.8YTCh. 4.3 - Skill Building Isotopes of Nitrogen Nitrogen (N2)...Ch. 4.3 - You Decide Marshmallows and Pennies Avogadros...Ch. 4.3 - Skill Building Calculating the Mass of Atoms...
Ch. 4.4 - Prob. 4.12YTCh. 4.4 - Prob. 4.13YTCh. 4.4 - Prob. 4.14YTCh. 4.4 - You Decide Checking Carbon from Cars A...Ch. 4.5 - Skill Building Light from the Sun Refresher In...Ch. 4.5 - Prob. 4.17YTCh. 4.6 - You Decide Evaporating Coal Mines Writing in the...Ch. 4.6 - Prob. 4.19YTCh. 4.6 - Prob. 4.20YTCh. 4.6 - Prob. 4.21YTCh. 4.7 - Skill Building MethaneFlat or Tetrahedral? a. If...Ch. 4.7 - Prob. 4.23YTCh. 4.7 - Skill Building Predicting Molecular Shapes, Part 2...Ch. 4.8 - Skill Building How Will a Molecule Stretch? For...Ch. 4.8 - Scientific Practices Greenhouse Gas Spectra a. Use...Ch. 4.8 - Scientific Practices Greenhouse Gas Spectra We...Ch. 4.8 - Prob. 4.28YTCh. 4.9 - Prob. 4.29YTCh. 4.9 - Prob. 4.30YTCh. 4.9 - Prob. 4.31YTCh. 4.9 - Prob. 4.32YTCh. 4.9 - Prob. 4.33YTCh. 4.9 - Prob. 4.34YTCh. 4.9 - Prob. 4.35YTCh. 4.9 - Prob. 4.36YTCh. 4.9 - Prob. 4.37YTCh. 4.10 - Prob. 4.38YTCh. 4.10 - Prob. 4.39YTCh. 4.10 - Prob. 4.40YTCh. 4.10 - Prob. 4.41YTCh. 4.11 - For each of the conclusions presented in Table...Ch. 4.11 - Prob. 4.43YTCh. 4.11 - Prob. 4.44YTCh. 4.12 - Skill Building Footprint Calculations Investigate...Ch. 4.12 - Scientific Practices Your Personal Share of the...Ch. 4.12 - Prob. 4.47YTCh. 4.12 - Prob. 4.48YTCh. 4.12 - Prob. 4.49YTCh. 4.12 - Prob. 4.50YTCh. 4.12 - You Decide Climate Change Insurance? Mitigation of...Ch. 4.12 - Prob. 4.52YTCh. 4.12 - You Decide The Big Question Revisited Answer these...Ch. 4 - i. Earth has increased in temperature by 6 C (10.8...Ch. 4 - The chapter concluded with a quote from John...Ch. 4 - Prob. 2QCh. 4 - Prob. 3QCh. 4 - Prob. 5QCh. 4 - a. It is estimated that 29 megajoules per square...Ch. 4 - Consider Figure 4.23. a. How does the present...Ch. 4 - Understanding Earths energy balance is essential...Ch. 4 - Explain each of these observations. a. A car...Ch. 4 - Prob. 10QCh. 4 - Draw the Lewis structure and name the molecular...Ch. 4 - Draw the Lewis structure and name the molecular...Ch. 4 - a. Draw the Lewis structure for methanol (wood...Ch. 4 - a. Draw the Lewis structure for ethene (ethylene),...Ch. 4 - Prob. 15QCh. 4 - Prob. 16QCh. 4 - Prob. 17QCh. 4 - Prob. 18QCh. 4 - Termites possess enzymes that allow them to break...Ch. 4 - Consider Figure 4.4. a. Which sector has the...Ch. 4 - Silver has an atomic number of 47. a. Give the...Ch. 4 - Silver only has two naturally occurring isotopes:...Ch. 4 - a. Calculate the average mass in grams of an...Ch. 4 - Prob. 24QCh. 4 - Prob. 25QCh. 4 - The total mass of carbon in living systems is...Ch. 4 - Prob. 27QCh. 4 - Give the number of protons, neutrons, and...Ch. 4 - Give the symbol showing the atomic number and the...Ch. 4 - Prob. 30QCh. 4 - The Arctic has been called our canary in the coal...Ch. 4 - Do you think the comment made in the cartoon is...Ch. 4 - Prob. 33QCh. 4 - Prob. 34QCh. 4 - Over the last 20 years, about 120 billion tons of...Ch. 4 - Prob. 36QCh. 4 - Prob. 37QCh. 4 - Prob. 38QCh. 4 - Ethanol, C2H5OH, can be produced from sugars and...Ch. 4 - Prob. 40QCh. 4 - Prob. 41QCh. 4 - Prob. 42QCh. 4 - Prob. 43QCh. 4 - Prob. 44QCh. 4 - Prob. 45QCh. 4 - Prob. 46QCh. 4 - Prob. 47QCh. 4 - Prob. 48QCh. 4 - Former vice president Al Gore writes in his 2006...Ch. 4 - Prob. 50QCh. 4 - Prob. 51QCh. 4 - Data taken over time reveal an increase in CO2 in...Ch. 4 - In the energy industry, 1 standard cubic foot...Ch. 4 - Prob. 54QCh. 4 - A solar oven is a low-tech, low-cost device for...Ch. 4 - In 2005, the European Union adopted a...
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