
Concept explainers
- a. Draw the Lewis structure for ethene (ethylene), H2CCH2, a small hydrocarbon with a
double bond.
- b. Based on this structure, predict the H–C–H bond angle. Explain your reasoning.
- c. Sketch the molecule showing the predicted bond angles.
(a)

Interpretation:
The Lewis structure for ethylene has to be drawn.
Concept Introduction:
Lewis structures are diagrams that represent the chemical bonding of covalently bonded molecules and coordination compounds.
The chemical bonding present in covalently bonded molecules and in coordination compounds are represented using Lewis structures.
It is also known as Lewis dot structures which represents the bonding between atoms of a molecule and the lone pairs of electrons that may exist in the molecule.
The Lewis structure is based on the concept of the octet rule so that the electrons shared in each atom should have 8 electrons in its outer shell.
Sometimes the chemical bonding of a molecule cannot be represented using a single Lewis structure. In these cases, the chemical bonding are described by delocalization of electrons and is known as resonance.
All the possible resonance structures are imaginary whereas the resonance hybrid is real.
These structures will differ only in the arrangement of the electrons not in the relative position of the atomic nuclei.
Lewis structure for any molecule is drawn by using the following steps,
First the skeletal structure for the given molecule is drawn then the total number of valence electrons for all atoms present in the molecule is determined
The next step is to subtract the electrons present in the total number of bonds present in the skeletal structure of the molecule with the total valence electrons such that considering each bond contains two electrons with it.
Finally, the electrons which got after subtractions have to be equally distributed such that each atom contains eight electrons in its valence shell.
Molecular geometry is the shape of a molecule predicted by considering only bond pair of electrons.
Geometry of different type of molecules with respect to the number of electron pairs are mentioned below,
Explanation of Solution
The Lewis electron dot structure for given molecules are determined by first drawing the skeletal structure for the given molecules, then the total number of valence electrons for all atoms present in the molecules are determined.
The next step is to subtract the electrons present in the total number of bonds present in the skeletal structure of the molecule with the total valence electrons such that considering each bond contains two electrons with it.
Finally, the electrons which got after subtractions have to be equally distributed considering each atom contains eight electrons in its valence shell.
The given moleucle is ethylene
Thus, the Lewis structure of given compound is,
(b)

Interpretation:
The bond angle value in
Concept Introduction:
Molecular geometry is the shape of a molecule predicted by considering only bond pair of electrons.
Geometry of different type of molecules with respect to the number of electron pairs are mentioned below,
Explanation of Solution
Lewis structure for the given compound ethylene is,
Here, the carbon atom does not have lone pair of electrons and the geometry around the carbon atom is triogonal planar, thus the bond angle in between
(c)

Interpretation:
The ethylene molecule has to be sketched and the predicted bond angle should be shown in the structure.
Concept Introduction:
Molecular geometry is the shape of a molecule predicted by considering only bond pair of electrons.
Geometry of different type of molecules with respect to the number of electron pairs are mentioned below,
Explanation of Solution
Lewis structure for the given compound ethylene is,
Here, the carbon atom does not have lone pair of electrons and the geometry around the carbon atom is triogonal planar, thus the bond angle in between
According to the predicted bond angle the structure can be sketched as follows,
Want to see more full solutions like this?
Chapter 4 Solutions
Chemistry In Context
Additional Science Textbook Solutions
Human Anatomy & Physiology (2nd Edition)
Brock Biology of Microorganisms (15th Edition)
Human Biology: Concepts and Current Issues (8th Edition)
Organic Chemistry (8th Edition)
- Draw the Haworth projection of the disaccharide made by joining D-glucose and D-mannose with a ẞ(1-4) glycosidic bond. If the disaccharide has more than one anomer, you can draw any of them. Click and drag to start drawing a structure. Xarrow_forwardEpoxides can be opened in aqueous acid or aqueous base to produce diols (molecules with two OH groups). In this question, you'll explore the mechanism of epoxide opening in aqueous acid. 2nd attempt Be sure to show all four bonds at stereocenters using hash and wedge lines. 0 0 Draw curved arrows to show how the epoxide reacts with hydronium ion. 100 +1: 1st attempt Feedback Be sure to show all four bonds at stereocenters using hash and wedge lines. See Periodic Table See Hint H A 5 F F Hr See Periodic Table See Hintarrow_forward03 Question (1 point) For the reaction below, draw both of the major organic products. Be sure to consider stereochemistry. > 1. CH₂CH₂MgBr 2. H₂O 3rd attempt Draw all four bonds at chiral centers. Draw all stereoisomers formed. Draw the structures here. e 130 AN H See Periodic Table See Hint P C Brarrow_forward
- You may wish to address the following issues in your response if they are pertinent to the reaction(s) you propose to employ:1) Chemoselectivity (why this functional group and not another?) 2) Regioselectivity (why here and not there?) 3) Stereoselectivity (why this stereoisomer?) 4) Changes in oxidation state. Please make it in detail and draw it out too in what step what happens. Thank you for helping me!arrow_forward1) Chemoselectivity (why this functional group and not another?) 2) Regioselectivity (why here and not there?) 3) Stereoselectivity (why this stereoisomer?) 4) Changes in oxidation state. Everything in detail and draw out and write it.arrow_forwardCalculating the pH at equivalence of a titration 3/5 Izabella A chemist titrates 120.0 mL of a 0.7191M dimethylamine ((CH3)2NH) solution with 0.5501 M HBr solution at 25 °C. Calculate the pH at equivalence. The pk of dimethylamine is 3.27. Round your answer to 2 decimal places. Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of HBr solution added. pH = ☐ ✓ 18 Ar Boarrow_forward
- Alcohols can be synthesized using an acid-catalyzed hydration of an alkene. An alkene is combined with aqueous acid (e.. sulfuric acid in water). The reaction mechanism typically involves a carbocation intermediate. > 3rd attempt 3343 10 8 Draw arrows to show the reaction between the alkene and hydronium ion. that 2nd attempt Feedback 1st attempt تعمال Ju See Periodic Table See Hint F D Ju See Periodic Table See Hintarrow_forwardDraw the simplified curved arrow mechanism for the reaction of acetone and CHgLi to give the major product. 4th attempt Π Draw the simplified curved arrow mechanism T 3rd attempt Feedback Ju See Periodic Table See Hint H -H H -I H F See Periodic Table See Hintarrow_forwardSelect the correct reagent to accomplish the first step of this reaction. Then draw a mechanism on the Grignard reagent using curved arrow notation to show how it is converted to the final product. 4th attempt Part 1 (0.5 point) Select the correct reagent to accomplish the first step of this reaction. Choose one: OA Mg in ethanol (EtOH) OB. 2 Li in THF O C. Li in THF D. Mg in THF O E Mg in H2O Part 2 (0.5 point) Br Part 1 Bri Mg CH B CH, 1 Draw intermediate here, but no arrows. © TE See Periodic Table See Hint See Hint ין Harrow_forward
- Select the product for the following reaction. HO HO PCC OH ○ OH O HO ○ HO HO HOarrow_forward5:45 Х Select the final product for the following reaction sequence. O O 1. Mg. ether 2.D.Oarrow_forwardBased on the chart Two similarities between the molecule with alpha glycosidic linkages. Two similarities between the molecules with beta glycosidtic linkages. Two differences between the alpha and beta glycosidic linkages.arrow_forward
- Introductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning



