EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
6th Edition
ISBN: 9781305687875
Author: Gilbert
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Question
Chapter 4.4, Problem 5E
Interpretation Introduction
Interpretation: Drastic reduction of fractional distillation if heat is supplied to stillpot too rapidly should be explained.
Concept introduction: Fractional distillation is separation technique that separates various fractions of components in mixture. This process is based on vaporization of one or more fractions or parts of mixture. It is used to separate components of mixture that have difference in boiling points less than
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1. Which is more efficient for separating the components of a liquid mixture of a liquid mixture, simple or fractional distillation? Why?
2. Explain (in 1 – 3 sentences) how distillation works in separating simple mixtures.
What specifically occurs when a liquid mixture is distilled?
1)
Components of a solid mixture are separated by differences in boiling points
2)
Components of a solid mixture are separated by differences in melting points
3)
Components of a liquid mixture are separated by differences in boiling points
4)
Components of a liquid mixture are separated by differences in melting points
What specifically occurs when a liquid mixture is distilled?
O ) Components of a solid mixture are separated by differences in melting
points
2) Components of a solid mixture are separated by differences in boiling points
3) Components of a liquid mixture are separated by differences in boiling points
4) Components of a liquid mixture are separated by differences in melting
points
Chapter 4 Solutions
EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
Ch. 4.2 - Prob. 1ECh. 4.2 - Prob. 2ECh. 4.2 - Prob. 3ECh. 4.2 - Prob. 4ECh. 4.2 - Prob. 5ECh. 4.2 - Prob. 6ECh. 4.2 - Prob. 7ECh. 4.2 - Prob. 8ECh. 4.2 - Prob. 9ECh. 4.3 - Prob. 1E
Ch. 4.3 - Prob. 2ECh. 4.3 - Prob. 3ECh. 4.3 - Prob. 4ECh. 4.3 - Prob. 5ECh. 4.3 - Prob. 6ECh. 4.3 - Prob. 7ECh. 4.3 - Prob. 8ECh. 4.4 - Prob. 1ECh. 4.4 - Prob. 2ECh. 4.4 - Prob. 3ECh. 4.4 - Prob. 4ECh. 4.4 - Prob. 5ECh. 4.4 - Prob. 6ECh. 4.4 - Prob. 7ECh. 4.4 - Prob. 8ECh. 4.4 - Prob. 9ECh. 4.4 - Prob. 11ECh. 4.4 - Prob. 12ECh. 4.4 - Prob. 13ECh. 4.4 - Prob. 14ECh. 4.6 - Prob. 1ECh. 4.6 - Prob. 2ECh. 4.6 - Prob. 3ECh. 4.6 - Prob. 4ECh. 4.6 - Prob. 5ECh. 4.6 - Prob. 6ECh. 4.6 - Prob. 7ECh. 4.6 - Prob. 8ECh. 4.6 - Prob. 9E
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- Rank the dissolution of an ionic solid steps from first to last. - hydration of cations - hydration of anions - hydration cations and anions lose waters of hydration and deposit as the solid salt - dissolution of salt into its cations and anions - rate of dissolution is equal to the rate of recrystallizationarrow_forwardExplain the importance of using a thermometer in the simple distillation setup. Enumerate the characteristics of a substance for it to be separated from the heterogeneous mixture by steam distillation. How does steam facilitate the distillation of essential oils? Discuss some applications of simple distillation and steam distillation. Explain why you can use each method for the chosen application. What is the most dominant intermolecular forces of attraction that exist between: a. water and limonene, the major monoterpene component of lemon essential oil? b. water and constituent ions of sodium chloride? 6. Based on your answers in number 5, which pair (water-limonene or water-sodium chloride) exhibits a stronger attraction between their molecules/ions? 7. Describe what happens during the salting-out process in terms of the intermolecular forces of attraction involved as mentioned in your previous answers.arrow_forward22. Why is the "boiling chips" used in the process of distillation? * To get the stable bolling point temperature of the mixture. To avoid the bumping of molecules of the compound mixture. To distill the components of the mixture at the atmospheric temperature.arrow_forward
- A chemist is given a nonelectrolyte white powder for analysis. 38.7 g of this substance is dissolved in 100.0 g of water. It is determined that the resulting solution freezes at -4.0°C. Additionally, the elemental composition of the substance is identified and found to be 40.0% C, 6.7% H and 53.3 % O by mass. Find the molecular formula of this unknown white powder using these experimental evidences (Kr of water: 1.86°C/m, C: 12 g/mol, H: 1 g/mol, O: 16 g/mol).arrow_forwardGive answer all questions with explanation pleasearrow_forwardAny additional information is attachedarrow_forward
- A chemist is given a nonelectrolyte white powder for analysis. 38.7 g of this substance isdissolved in 100.0 g of water. It is determined that the resulting solution freezes at –4.0°C.Additionally, the elemental composition of the substance is identified and found to be 40.0%C, 6.7% H and 53.3 % O by mass. Find the molecular formula of this unknown white powderusing these experimental evidences (Kf of water: 1.86°C/m, C: 12 g/mol, H: 1 g/mol, O: 16g/mol)arrow_forward12. Answer Only Refer to the following mixtures: Mixture A: Liquid and solid mixture Mixture B. Liquid mixture whose boiling points are similar. Mixture C. Liquid mixture with high boiling point. Mixture D. Heat sensitive liquid mixture. Which of the following distillation can be applied for Mixture D? vacuum distillation fractional distillation simple distillation none of these ———— This is defined as the temperature at which the vapor pressure of the liquid phase of a compound equals the external pressure acting on the surface of the liquid. solubility melting point boiling point flash point optical rotation —————— Predict the color change if 1% ferric chloride (yellowish solution) is added to a test tube containing a mixture of ethanol and pure acetyl salicylic acid. purple to yellow yellow to dark blue light blue to pink yellow to purple no color changearrow_forward1. Steam distillation was performed to obtain geraniol (MM = 154.25 g/mol) from dried rose petals. At 99.25°C, the vapor pressure of water is 714 mmHg while that of geraniol was determined to be 46 mmHg. a. Determine the theoretical mass of geraniol that will distill per 100 g of water. b. If 150 g of dried rose petals were used, calculate the percent yield of the distillation.arrow_forward
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