Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
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Textbook Question
Chapter 4.2, Problem 4.3E
Use the procedure described previously to verify the point groups of the molecules in Table 4.4.
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Chapter 4 Solutions
Inorganic Chemistry
Ch. 4.1 - Prob. 4.1ECh. 4.1 - Find all the symmetry elements in the following...Ch. 4.2 - Use the procedure described previously to verify...Ch. 4.3 - Prob. 4.4ECh. 4.3 - Verify the transformation matrices for the E and...Ch. 4.3 - Prepare a representation flowchart according to...Ch. 4.4 - Which point groups are possible for chiral...Ch. 4.4 - Write the corresponding 99 transformation matrices...Ch. 4.4 - Using the x, y, and z coordinates for each atom in...Ch. 4.4 - Reduce the following representations to their...
Ch. 4.4 - Prob. 4.11ECh. 4.4 - Analysis of the x, y, and z coordinates of each...Ch. 4.4 - Determine the number of IR-active CO stretching...Ch. 4.4 - Prob. 4.14ECh. 4 - Determine the point groups for a. Ethane...Ch. 4 - Determine the point groups for a. Ethylene b....Ch. 4 - Determine the point groups for a. Acetylene b....Ch. 4 - Determine the point groups for a. Naphthalene b....Ch. 4 - Determine the point groups for a. 1,1’ ...Ch. 4 - Determine the point groups for a. Cyclohexane...Ch. 4 - Determine the point groups for a. A sheet of...Ch. 4 - Determine the point groups for a. A flat oval...Ch. 4 - Determine the point groups for a. A triangular...Ch. 4 - Determine the point groups for the examples of...Ch. 4 - Determine the point groups of the molecules in the...Ch. 4 - Determine the point groups of the molecules and...Ch. 4 - Determine the point groups of the following atomic...Ch. 4 - a. Show that a cube has the same symmetry elements...Ch. 4 - Suppose an octahedron can have either yellow or...Ch. 4 - What point groups are represented by the symbols...Ch. 4 - Prob. 4.17PCh. 4 - Determine the point groups for the following flags...Ch. 4 - Prepare a representation flowchart according to...Ch. 4 - For trans-1,2-dichloroethylene, which has C2h...Ch. 4 - Ethylene has D2h symmetry. a. List all the...Ch. 4 - Using the D2d character table, a. Determine the...Ch. 4 - Reduce the following representations to...Ch. 4 - For D4h symmetry use sketches to show that dxy...Ch. 4 - Prob. 4.25PCh. 4 - XeOF4 has one of the more interesting structures...Ch. 4 - Repeat the procedure from the previous problem,...Ch. 4 - For the following molecules, determine the number...Ch. 4 - Prob. 4.29PCh. 4 - The structure of 1,1,2,2-tetraiododisilane is...Ch. 4 - Both cis and trans isomers of IO2F4 have been...Ch. 4 - White elemental phosphorus consists of tetrahedral...Ch. 4 - Complexes of the general formula Fe(CO)5x( PR3)x...Ch. 4 - Prob. 4.35PCh. 4 - Prob. 4.36PCh. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Determine the point groups of the following...Ch. 4 - Prob. 4.40PCh. 4 - Determine the point groups of the following: a....Ch. 4 - Use the Internet to search for molecules with the...
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- Show that the irreducible representations of the D2d point group satisfy the closure requirement. You will have to use the great orthogonality theorem to reduce one combination.arrow_forwarda Show that the C3v point group satisfies the closure property of a mathematical group. b Show that the C3v point group satisfies the associative law by evaluating v(EC3) and (vE)C3.arrow_forwardConstruct the symmetry-adapted linear combination molecular orbitals for hydrogen sulfide, H2S.arrow_forward
- Show that any irreducible representation of these point groups is normalized. a C2 b D2d c Oh d C4h e C6varrow_forward1. Find the point groups of the following shapes, interpreting (a) as a square and (b)-(p) as derivatives with lines perpendiarrow_forwardDetermine the point groups for Chloroethylene.arrow_forward
- Please help me Point group of square Antiprismatic is D4darrow_forwardAssign the following molecules to point groups: (i) HF, (ii) IF7 (pentagonal bipyramid), (iii) CIF3 (T-shaped), (iv) Fe2(CO)9 (Image 3), (v) cubane (C8H8), (vi) tetrafluorocubane (C8H4F4) (Image 4).arrow_forward(ii) List and depict all the symmetry elements and deduce the point group. NH2 N' NH2 Barrow_forward
- 1) Using corresponding matrices for the operations of C3V point group, show that they fulfill the requirement of making group.arrow_forwardDetermine the point group for dichloro(phenyl)phosphine. Please see photo attached.arrow_forwardDevelop a multiplication table for NH3 for the point group to which this molecule belongs. Show all work/proofs!arrow_forward
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