Inorganic Chemistry
Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
bartleby

Videos

Textbook Question
100%
Book Icon
Chapter 4, Problem 4.20P

For trans-1,2-dichloroethylene, which has C 2h symmetry,
a. List all the symmetry operations for this molecule.
b. Write a set of transformation matrices that describe the effect of each symmetry operationin the C 2h group on a set of coordinates x, y, z for a point (your answer should consist offour 3 × 3 transformation matrices).
c. Using the terms along the diagonal, obtain as many irreducible representations aspossible from the transformation matrices. You should be able to obtain three irreduciblerepresentations in this way, but two will be duplicates. You may check your results usingthe C 2h character table.
d. Using the C 2h character table, verify that the irreducible representations are mutuallyorthogonal,

Blurred answer
Students have asked these similar questions
When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.
When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.   Which experimental number must be initialled by the Lab TA for the first run of Part 1 of the experiment? a) the heat capacity of the calorimeter b) Mass of sample c) Ti d) The molarity of the HCl e) Tf
Predict products for the Following organic rxn/s by writing the structurels of the correct products. Write above the line provided" your answer D2 ①CH3(CH2) 5 CH3 + D₂ (adequate)" + 2 mited) 19 Spark Spark por every item. 4 CH 3 11 3 CH 3 (CH2) 4 C-H + CH3OH CH2 CH3 + CH3 CH2OH 0 CH3 fou + KMnDy→ C43 + 2 KMn Dy→→ C-OH ") 0 C-OH 1110 (4.) 9+3 =C CH3 + HNO 3 0 + Heat> + CH3 C-OH + Heat CH2CH3 - 3 2 + D Heat H 3 CH 3 CH₂ CH₂ C = CH + 2 H₂ → 2 2

Chapter 4 Solutions

Inorganic Chemistry

Ch. 4.4 - Prob. 4.11ECh. 4.4 - Analysis of the x, y, and z coordinates of each...Ch. 4.4 - Determine the number of IR-active CO stretching...Ch. 4.4 - Prob. 4.14ECh. 4 - Determine the point groups for a. Ethane...Ch. 4 - Determine the point groups for a. Ethylene b....Ch. 4 - Determine the point groups for a. Acetylene b....Ch. 4 - Determine the point groups for a. Naphthalene b....Ch. 4 - Determine the point groups for a. 1,1’ ...Ch. 4 - Determine the point groups for a. Cyclohexane...Ch. 4 - Determine the point groups for a. A sheet of...Ch. 4 - Determine the point groups for a. A flat oval...Ch. 4 - Determine the point groups for a. A triangular...Ch. 4 - Determine the point groups for the examples of...Ch. 4 - Determine the point groups of the molecules in the...Ch. 4 - Determine the point groups of the molecules and...Ch. 4 - Determine the point groups of the following atomic...Ch. 4 - a. Show that a cube has the same symmetry elements...Ch. 4 - Suppose an octahedron can have either yellow or...Ch. 4 - What point groups are represented by the symbols...Ch. 4 - Prob. 4.17PCh. 4 - Determine the point groups for the following flags...Ch. 4 - Prepare a representation flowchart according to...Ch. 4 - For trans-1,2-dichloroethylene, which has C2h...Ch. 4 - Ethylene has D2h symmetry. a. List all the...Ch. 4 - Using the D2d character table, a. Determine the...Ch. 4 - Reduce the following representations to...Ch. 4 - For D4h symmetry use sketches to show that dxy...Ch. 4 - Prob. 4.25PCh. 4 - XeOF4 has one of the more interesting structures...Ch. 4 - Repeat the procedure from the previous problem,...Ch. 4 - For the following molecules, determine the number...Ch. 4 - Prob. 4.29PCh. 4 - The structure of 1,1,2,2-tetraiododisilane is...Ch. 4 - Both cis and trans isomers of IO2F4 have been...Ch. 4 - White elemental phosphorus consists of tetrahedral...Ch. 4 - Complexes of the general formula Fe(CO)5x( PR3)x...Ch. 4 - Prob. 4.35PCh. 4 - Prob. 4.36PCh. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Determine the point groups of the following...Ch. 4 - Prob. 4.40PCh. 4 - Determine the point groups of the following: a....Ch. 4 - Use the Internet to search for molecules with the...
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning
Text book image
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Group Theory - Learn like Expert with 3D animation | Introduction for Beginners | ONE Chemistry; Author: One Chemistry;https://www.youtube.com/watch?v=Lz2ih8fkgDs;License: Standard YouTube License, CC-BY