Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
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Chapter 4, Problem 4.36P
Interpretation Introduction
Interpretation: The formula of the Mo carbonyl complex consistent with IR spectra should be proposed.
Concept Introduction: If the point group of the molecule and the symmetry labels for the normal modes are known, then with the help of normal modes, IR and/or Raman active vibrations can be predicted.
If the symmetry label of the normal mode corresponds to
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Draw the epoxide formed when the following alkene is treated with mCPBA. Click the "draw
structure" button to launch the drawing utility.
draw structure ...
Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
Check
CF3
(Choose one)
OH
(Choose one)
H
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
Resonance Effects
Overall Electron-Density
CF3
O donating
O donating
O electron-rich
O withdrawing
withdrawing
O no inductive effects
O no resonance effects
O electron-deficient
O similar to benzene
OCH3
Explanation
Check
O donating
O donating
○ withdrawing
withdrawing
O no inductive effects
no resonance effects
electron-rich
electron-deficient
O similar to benzene
Х
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Chapter 4 Solutions
Inorganic Chemistry
Ch. 4.1 - Prob. 4.1ECh. 4.1 - Find all the symmetry elements in the following...Ch. 4.2 - Use the procedure described previously to verify...Ch. 4.3 - Prob. 4.4ECh. 4.3 - Verify the transformation matrices for the E and...Ch. 4.3 - Prepare a representation flowchart according to...Ch. 4.4 - Which point groups are possible for chiral...Ch. 4.4 - Write the corresponding 99 transformation matrices...Ch. 4.4 - Using the x, y, and z coordinates for each atom in...Ch. 4.4 - Reduce the following representations to their...
Ch. 4.4 - Prob. 4.11ECh. 4.4 - Analysis of the x, y, and z coordinates of each...Ch. 4.4 - Determine the number of IR-active CO stretching...Ch. 4.4 - Prob. 4.14ECh. 4 - Determine the point groups for a. Ethane...Ch. 4 - Determine the point groups for a. Ethylene b....Ch. 4 - Determine the point groups for a. Acetylene b....Ch. 4 - Determine the point groups for a. Naphthalene b....Ch. 4 - Determine the point groups for a. 1,1’ ...Ch. 4 - Determine the point groups for a. Cyclohexane...Ch. 4 - Determine the point groups for a. A sheet of...Ch. 4 - Determine the point groups for a. A flat oval...Ch. 4 - Determine the point groups for a. A triangular...Ch. 4 - Determine the point groups for the examples of...Ch. 4 - Determine the point groups of the molecules in the...Ch. 4 - Determine the point groups of the molecules and...Ch. 4 - Determine the point groups of the following atomic...Ch. 4 - a. Show that a cube has the same symmetry elements...Ch. 4 - Suppose an octahedron can have either yellow or...Ch. 4 - What point groups are represented by the symbols...Ch. 4 - Prob. 4.17PCh. 4 - Determine the point groups for the following flags...Ch. 4 - Prepare a representation flowchart according to...Ch. 4 - For trans-1,2-dichloroethylene, which has C2h...Ch. 4 - Ethylene has D2h symmetry. a. List all the...Ch. 4 - Using the D2d character table, a. Determine the...Ch. 4 - Reduce the following representations to...Ch. 4 - For D4h symmetry use sketches to show that dxy...Ch. 4 - Prob. 4.25PCh. 4 - XeOF4 has one of the more interesting structures...Ch. 4 - Repeat the procedure from the previous problem,...Ch. 4 - For the following molecules, determine the number...Ch. 4 - Prob. 4.29PCh. 4 - The structure of 1,1,2,2-tetraiododisilane is...Ch. 4 - Both cis and trans isomers of IO2F4 have been...Ch. 4 - White elemental phosphorus consists of tetrahedral...Ch. 4 - Complexes of the general formula Fe(CO)5x( PR3)x...Ch. 4 - Prob. 4.35PCh. 4 - Prob. 4.36PCh. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Determine the point groups of the following...Ch. 4 - Prob. 4.40PCh. 4 - Determine the point groups of the following: a....Ch. 4 - Use the Internet to search for molecules with the...
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