ORGANIC CHEMISTRY-ACCESS
6th Edition
ISBN: 9781260475586
Author: SMITH
Publisher: MCG
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Chapter 4.15, Problem 33P
Interpretation Introduction
Interpretation: To determine the solubility of beeswax in water, ethanol, and chloroform.
Concept Introduction: "Like dissolves like" would be a condensed version of the "Solubility Rule". Each polar substance would therefore only disperse inside another polar substance, but a non-polar material would also dissolve inside another polar substance.
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Chapter 4 Solutions
ORGANIC CHEMISTRY-ACCESS
Ch. 4.1 - Prob. 1PCh. 4.1 - Problem 4.2 Which of the following is not another...Ch. 4.1 - Problem 4.3 Draw the five constitutional isomers...Ch. 4.1 - Prob. 4PCh. 4.1 - Prob. 5PCh. 4.2 - Draw the five constitutional isomers that have...Ch. 4.4 - Problem 4.7 Give the IUPAC name for each...Ch. 4.4 - Give the IUPAC name for each compound. a....Ch. 4.4 - Problem 4.9 Give the structure corresponding to...Ch. 4.4 - Prob. 10P
Ch. 4.5 - Give the IUPAC name for each compound.Ch. 4.5 - Give the structure corresponding to each IUPAC...Ch. 4.8 - Arrange the following compounds in order of...Ch. 4.9 - Problem 4.14 Draw the staggered and eclipsed...Ch. 4.9 - Prob. 15PCh. 4.9 - Prob. 16PCh. 4.10 - Problem 4.17 a. Draw the three staggered and...Ch. 4.10 - Problem 4.18 Rank the following conformations in...Ch. 4.10 - Problem 4.19 Consider rotation around the...Ch. 4.10 - Calculate the destabilization present in each...Ch. 4.12 - Problem 4.21 Classify the ring carbons as up or...Ch. 4.12 - Problem 4.22 Using the cyclohexane with the C’s...Ch. 4.13 - Draw a second chair conformation for each...Ch. 4.13 - Problem 4.24 Draw both conformations for and...Ch. 4.13 - Problem 4.25 Draw the structure for each compound...Ch. 4.13 - Prob. 26PCh. 4.14 - Prob. 31PCh. 4.14 - Prob. 32PCh. 4.15 - Prob. 33PCh. 4 - Name each alkane using the ball-and-stick model,...Ch. 4 -
4.40 Draw the structure corresponding to each...Ch. 4 - 4.42 Give the IUPAC name for each compound.
a....Ch. 4 - Prob. 42PCh. 4 - 4.46 Considering rotation around the bond...Ch. 4 - 4.50 Calculate the barrier to rotation for each...Ch. 4 - 4.51 The eclipsed conformation of is less...Ch. 4 - (a) Draw the anti and gauche conformations for...Ch. 4 - For each compound drawn below: a.Label each OH,Br...Ch. 4 - Draw the two possible chair conformations for...Ch. 4 - For each compound drawn below: a. Draw...Ch. 4 - Classify each pair of compounds as constitutional...Ch. 4 - Prob. 66PCh. 4 - 4.64 Draw the products of combustion of each...Ch. 4 - 4.65 Hydrocarbons like benzene are metabolized in...Ch. 4 - Prob. 69PCh. 4 - Prob. 70PCh. 4 - Cyclopropane and cyclobutane have similar strain...Ch. 4 - Prob. 72PCh. 4 - Haloethanes (CH3CH2X,X=Cl,Br,I) have similar...Ch. 4 - Prob. 74PCh. 4 - Prob. 75PCh. 4 - Consider the tricyclic structure B (a) Label each...Ch. 4 - Read Appendix B on naming branched alkyl...Ch. 4 - Read Appendix B on naming bicyclic compounds. Then...
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- Account for these facts: (a) Although ethanol (C2H5OH) (bp, 80 C) has a higher molar mass than water (bp, 100 C), the alcohol has a lower boiling point. (b) Mixing 50 mL of ethanol with 50 mL of water produces a solution with a volume slightly less than 100 mL.arrow_forwardHow could the data in Table 13.2 be used to predict the solubility in water of 1-octanol or 1-decanol? Table 13.2 Solubilities of Alcohols in Water, 20°Carrow_forwardConsider this information regarding two compounds. Thallium azide: yellow crystalline solid; melting point = 330 C; slightly soluble in water, more soluble in hot water; insoluble in ethanol or diethyl ether. Camphene: colorless, cubic crystals; melting point = 51 C; boiling point = 159 C; insoluble in water; moderately soluble in ethanol; soluble in diethyl ether. (a) Is camphene an ionic or molecular compound? Explain your answer. (b) Is thallium azide an ionic or molecular compound? Explain your answer.arrow_forward
- The terms nonpolar and polar as well as hydrophilic andhydrophobic can also be used to describe molecules. Howare these terms related to lipid-soluble and non-lipid-soluble?arrow_forwardAscorbic acid has a chemical formula of C6H8O6 and is water soluble. A solution containing 80.5 g of ascorbic acid is dissolved in 210g of water. The resulting solution has a density of 1.22g/mL at 55°C. Calculate the molarity of the ascorbic acid in the solution.arrow_forwardAscorbic acid has a chemical formula of C6H8O6 and is water soluble. A solution containing 80.5 g of ascorbic acid is dissolved in 210g of water. The resulting solution has a density of 1.22g/mL at 55°C. Calculate the molar mass of ascorbic acidarrow_forward
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