ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
10th Edition
ISBN: 9781259972348
Author: Carey
Publisher: MCG CUSTOM
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Chapter 4.13, Problem 22P
Interpretation Introduction
Interpretation:
Fischer projections of the two stereoisomeric tartaric acids are to be written and the configurations at each of their chirality centers is to be specified.
Concept introduction:
The absolute configuration is the three-dimensional spatial arrangement of substituents attached at the chiral center.
In Fischer projections, the molecule is oriented so that the vertical bonds at the chiral center are directed away from the observer and the horizontal bonds point towards the observer. A projection of the bonds onto the page is a cross.
In a Fischer projection, exchange of two groups reverses the configuration of the chirality center.
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8)
FCI II
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Br Br
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-C=C-Br
-CEC-C-C-
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CH3CHFCHFC=CH
C(OH)Br2CHF(CH2)4CH2CH3
CH3(CH2)3CH=CH(CH2)2CH3
Name
1) 3-fluoro, 1-butene
2) 2-heptene
2,3-difluoro-
1-pentene
4) 6-iodo,4-methyl-
2-decyne
5) 4,4-dibromo-
1,2-butandiol
Complete structural formula
F
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Line formula
Condensed structural formula
N
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CH2=CHCHFCH3
1.
Part 1: Naming Organic Compounds
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H₁C-C-CH3
CH3
Br
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2. Br-CH-CH-CH₂
H₂C-CH-C= -CH-CH2-CH3
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HC-CH-CH-C-OH
5. H₂C-CH-CH₂-OH
7.
OH
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CH
CH₂-CH₂
6.
сно
CH-CH-CH-CH₂-CH₂
H₁₂C-CH-CH-CH-CH₁₂-CH₁₂
8.
OH
Chapter 4 Solutions
ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
Ch. 4.2 - Examine the following for chirality centers:Ch. 4.2 - Prob. 2PCh. 4.3 - Prob. 3PCh. 4.3 - Prob. 4PCh. 4.4 - Prob. 5PCh. 4.4 - Prob. 6PCh. 4.5 - Does the molecular model shown represent...Ch. 4.6 - Assign absolute configurations as R or S to each...Ch. 4.6 - Draw three-dimensional representations ofCh. 4.7 - Prob. 10P
Ch. 4.7 - Using the Fischer projection of (R)-2-butanol...Ch. 4.8 - Prob. 12PCh. 4.9 - Prob. 13PCh. 4.9 - Prob. 14PCh. 4.10 - Prob. 15PCh. 4.10 - Draw Fischer projections of the four...Ch. 4.10 - Prob. 17PCh. 4.11 - A meso stereoisomer is possible for one of the...Ch. 4.11 - One of the stereoisomers of...Ch. 4.12 - Prob. 20PCh. 4.12 - Prob. 21PCh. 4.13 - Prob. 22PCh. 4.13 - Prob. 23PCh. 4.13 - Prob. 24PCh. 4.14 - Prob. 25PCh. 4 - Prob. 26PCh. 4 - Including stereoisomers, write structural formulas...Ch. 4 - Prob. 28PCh. 4 - Prob. 29PCh. 4 - Prob. 30PCh. 4 - Prob. 31PCh. 4 - Prob. 32PCh. 4 - Prob. 33PCh. 4 - Prob. 34PCh. 4 - Prob. 35PCh. 4 - Prob. 36PCh. 4 - Prob. 37PCh. 4 - Prob. 38PCh. 4 - Prob. 39PCh. 4 - (-)-Menthol is the most stable stereoisomer of...Ch. 4 - Prob. 41PCh. 4 - Prob. 42PCh. 4 - (a) An aqueous solution containing 10 g of...Ch. 4 - Prob. 44DSPCh. 4 - Prob. 45DSPCh. 4 - Consider two chemical changes: one occurring at a...Ch. 4 - Consider two chemical changes: one occurring at a...Ch. 4 - Prob. 48DSPCh. 4 - Consider two chemical changes: one occurring at a...Ch. 4 - Consider two chemical changes: one occurring at a...
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