EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Question
Chapter 4.12, Problem 11LTS
Interpretation Introduction
Interpretation:
The axial and equatorial chair conformation of Bromocyclohexane should be drawn.
Concept Introduction:
Conformational isomers:
- The two or more compounds have same molecular formula and different structural formulas are called conformational isomers.
- The cyclohexanes have a chair and boat conformations.
- The boat conformation of cyclohexane is more stable than boat form.
- The boat conformation of cyclohexane has two positions of substituent's which are axial and equatorial.
- The substituent occupy at similar to a vertical axis passing through the chair conformation of cyclohexane ring is called axial position.
- The substituent occupy at similar to a horizontal axis passing through the chair conformation of cyclohexane ring is called equatorial position.
To draw the axial and equatorial chair conformations of Bromocyclohexane.
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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter 4 Solutions
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
Ch. 4.2 - Prob. 1LTSCh. 4.2 - Prob. 1PTSCh. 4.2 - Prob. 2PTSCh. 4.2 - Prob. 3ATSCh. 4.2 - Prob. 2LTSCh. 4.2 - Prob. 4PTSCh. 4.2 - Prob. 5ATSCh. 4.2 - Prob. 3LTSCh. 4.2 - Prob. 6PTSCh. 4.2 - Prob. 7ATS
Ch. 4.2 - Prob. 4LTSCh. 4.2 - Prob. 8PTSCh. 4.2 - Prob. 9PTSCh. 4.2 - Prob. 10ATSCh. 4.2 - Prob. 5LTSCh. 4.3 - Prob. 6LTSCh. 4.3 - Prob. 14PTSCh. 4.6 - Prob. 7LTSCh. 4.6 - Prob. 16PTSCh. 4.8 - Prob. 8LTSCh. 4.12 - Prob. 11LTSCh. 4.12 - Prob. 25PTSCh. 4.14 - Prob. 33CCCh. 4.14 - Prob. 34CCCh. 4.14 - Prob. 35CCCh. 4 - Prob. 36PPCh. 4 - Prob. 51PPCh. 4 - Prob. 52PPCh. 4 - Prob. 53PPCh. 4 - Prob. 54PPCh. 4 - Prob. 55PPCh. 4 - Prob. 56PPCh. 4 - Prob. 57PPCh. 4 - Prob. 58PPCh. 4 - Prob. 59PPCh. 4 - Prob. 69ACPCh. 4 - Prob. 73IPCh. 4 - Prob. 76IP
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