The optically inactive compound for the given molecular formula has to be drawn. Concept introduction: Optical activity of a molecule is the interaction between molecule and plane-polarized light. Molecule having asymmetric center shows optical activity except mesocompounds. Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups. Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral. If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

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Answer 1

Question

Chapter 4, Problem 73P

(a)

Interpretation Introduction

Interpretation:

The optically inactive compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

(b)

Interpretation Introduction

Interpretation:

The mesocompound (optically inactive compound) for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

(c)

Interpretation Introduction

Interpretation:

The optically active compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound is identical, then the compound is a mesocompound.

If a cyclic compound has two asymmetric centers with identical substituents, then cis-isomer of the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

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1. An object is chiral if it A. is superimposable on its mirror image B. is not superimposable on its mirror image C. has no mirror image D. is identical to each mirror image of itself

Answer 2

Question

Chapter 4, Problem 73P

(a)

Interpretation Introduction

Interpretation:

The optically inactive compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

(b)

Interpretation Introduction

Interpretation:

The mesocompound (optically inactive compound) for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

(c)

Interpretation Introduction

Interpretation:

The optically active compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound is identical, then the compound is a mesocompound.

If a cyclic compound has two asymmetric centers with identical substituents, then cis-isomer of the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

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Answer 3

Question

Chapter 4, Problem 73P

(a)

Interpretation Introduction

Interpretation:

The optically inactive compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

(b)

Interpretation Introduction

Interpretation:

The mesocompound (optically inactive compound) for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

(c)

Interpretation Introduction

Interpretation:

The optically active compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound is identical, then the compound is a mesocompound.

If a cyclic compound has two asymmetric centers with identical substituents, then cis-isomer of the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

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Answer 4

Question

Chapter 4, Problem 73P

(a)

Interpretation Introduction

Interpretation:

The optically inactive compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

(b)

Interpretation Introduction

Interpretation:

The mesocompound (optically inactive compound) for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

(c)

Interpretation Introduction

Interpretation:

The optically active compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound is identical, then the compound is a mesocompound.

If a cyclic compound has two asymmetric centers with identical substituents, then cis-isomer of the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

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Answer 5

Chapter 4, Problem 73P

(a)

Interpretation Introduction

Interpretation:

The optically inactive compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

(b)

Interpretation Introduction

Interpretation:

The mesocompound (optically inactive compound) for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

(c)

Interpretation Introduction

Interpretation:

The optically active compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound is identical, then the compound is a mesocompound.

If a cyclic compound has two asymmetric centers with identical substituents, then cis-isomer of the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

Answer 6

Chapter 4, Problem 73P

(a)

Interpretation Introduction

Interpretation:

The optically inactive compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Answer 7

Chapter 4, Problem 73P

(a)

Interpretation Introduction

Interpretation:

The optically inactive compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The mesocompound (optically inactive compound) for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The mesocompound (optically inactive compound) for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The optically active compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound is identical, then the compound is a mesocompound.

If a cyclic compound has two asymmetric centers with identical substituents, then cis-isomer of the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The optically active compound for the given molecular formula has to be drawn.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound is identical, then the compound is a mesocompound.

If a cyclic compound has two asymmetric centers with identical substituents, then cis-isomer of the compound is a mesocompound.

Asymmetric center is arises to hydrocarbons if the carbon is bonded to four different groups.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 4.1 - Prob. 2P Ch. 4.1 - Prob. 3P Ch. 4.1 - Prob. 4P Ch. 4.1 - Prob. 5P Ch. 4.1 - Which of the roll owing compounds have a dipole...Ch. 4.2 - Draw and label the E and Z isomers for each of the...Ch. 4.2 - Assign relative priorities to each set of...Ch. 4.2 - Tamoxifen slows the growth of some breast tumors...Ch. 4.2 - Prob. 10P Ch. 4.2 - Name each of the following:

Solution Summary: The author explains that the optically inactive compound for the given molecular formula has to be drawn.

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