The boiling point of methyl amine is to be estimated using Trouton’s Rule. Concept Introduction: The substance is said to be boiling when its pressure is in equilibrium with the atmospheric pressure. When substance is boiling, the standard entropy change can be measured by knowing the standard enthalpy change. Trouton’s rule is used in this measurement which states that “entropy of vaporization for most of the liquid is constant which is equal to 10.5 R ”.

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Chapter 4, Problem 4F.16E

(a)

Interpretation Introduction

Interpretation:

The boiling point of methyl amine is to be estimated using Trouton’s Rule.

Concept Introduction:

The substance is said to be boiling when its pressure is in equilibrium with the atmospheric pressure. When substance is boiling, the standard entropy change can be measured by knowing the standard enthalpy change. Trouton’s rule is used in this measurement which states that “entropy of vaporization for most of the liquid is constant which is equal to 10.5R”.

(b)

Interpretation Introduction

Interpretation:

The literature value and value obtained of boiling point of methyl amine by above part has to be compared.

Concept Introduction:

The substance is said to be boiling when its pressure is in equilibrium with the atmospheric pressure. When substance is boiling, the standard entropy change can be measured by knowing the standard enthalpy change. Trouton’s rule is used in this measurement which states that “entropy of vaporization for most of the liquid is constant which is equal to 10.5R”.

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