Principles of Chemistry: A Molecular Approach Plus Mastering Chemistry with eText -- Access Card Package (3rd Edition) (New Chemistry Titles from Niva Tro)
3rd Edition
ISBN: 9780321971166
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 4, Problem 4E
Interpretation Introduction
Interpretation:
When each amount of given reactant completely reacts, the number of moles of
Concept introduction: The number of moles is calculated by the formula,
To determine: The number of moles of
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 4 Solutions
Principles of Chemistry: A Molecular Approach Plus Mastering Chemistry with eText -- Access Card Package (3rd Edition) (New Chemistry Titles from Niva Tro)
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2PCh. 4 - For Practice 4.3 Ammonia can also be synthesized...Ch. 4 - Prob. 4.4PCh. 4 - Prob. 4.5PCh. 4 - Prob. 4.5MPCh. 4 - Prob. 4.6PCh. 4 - Prob. 4.6MPCh. 4 - Prob. 4.7PCh. 4 - Prob. 4.7MP
Ch. 4 - Prob. 4.8PCh. 4 - Prob. 4.8MPCh. 4 - Prob. 4.9PCh. 4 - Prob. 4.10PCh. 4 - Prob. 4.11PCh. 4 - Prob. 4.12PCh. 4 - Prob. 4.12MPCh. 4 - Prob. 4.13PCh. 4 - Prob. 4.14PCh. 4 - Prob. 4.15PCh. 4 - For More Practice 4.15 Write a net ionic equation...Ch. 4 - For Practice 4.16 Assign an oxidation state to...Ch. 4 - Prob. 4.17PCh. 4 - Prob. 4.17MPCh. 4 - Prob. 4.18PCh. 4 - Prob. 4.19PCh. 4 - Prob. 1SAQCh. 4 - Q2. Sodium and chlorine react to form sodium...Ch. 4 - Prob. 3SAQCh. 4 - Prob. 4SAQCh. 4 - Prob. 5SAQCh. 4 - Prob. 6SAQCh. 4 - Prob. 7SAQCh. 4 - Potassium iodide reacts with lead(ll) nitrate in...Ch. 4 - Prob. 9SAQCh. 4 - Prob. 10SAQCh. 4 - Prob. 11SAQCh. 4 - Prob. 12SAQCh. 4 - Prob. 13SAQCh. 4 - Prob. 14SAQCh. 4 - Prob. 15SAQCh. 4 - Prob. 1ECh. 4 - Prob. 2ECh. 4 - Prob. 3ECh. 4 - Prob. 4ECh. 4 - Prob. 5ECh. 4 - Prob. 6ECh. 4 - Prob. 7ECh. 4 - Prob. 8ECh. 4 - Prob. 9ECh. 4 - Prob. 10ECh. 4 - Prob. 11ECh. 4 - For each precipitation reaction, calculate how...Ch. 4 - Prob. 13ECh. 4 - Prob. 14ECh. 4 - Prob. 15ECh. 4 - Prob. 16ECh. 4 - Prob. 17ECh. 4 - Prob. 18ECh. 4 - Prob. 19ECh. 4 - Prob. 20ECh. 4 - Prob. 21ECh. 4 - Prob. 22ECh. 4 - Prob. 23ECh. 4 - Prob. 24ECh. 4 - Prob. 25ECh. 4 - Prob. 26ECh. 4 - Prob. 27ECh. 4 - Prob. 28ECh. 4 - Prob. 29ECh. 4 - Prob. 30ECh. 4 - Prob. 31ECh. 4 - Prob. 32ECh. 4 - Prob. 33ECh. 4 - Prob. 34ECh. 4 - Prob. 35ECh. 4 - Prob. 36ECh. 4 - Prob. 37ECh. 4 - Prob. 38ECh. 4 - Prob. 39ECh. 4 - Prob. 40ECh. 4 - Prob. 41ECh. 4 - A 55.0 mL sample of a 0.102 M potassium sulfate...Ch. 4 - Prob. 43ECh. 4 - Prob. 44ECh. 4 - Determine whether each compound is soluble or...Ch. 4 - Prob. 46ECh. 4 - 47. Complete and balance each equation. If no...Ch. 4 - Complete and balance each equation. If no reactio...Ch. 4 - Prob. 49ECh. 4 - Prob. 50ECh. 4 - Prob. 51ECh. 4 - Prob. 52ECh. 4 - Prob. 53ECh. 4 - Prob. 54ECh. 4 - Prob. 55ECh. 4 - Prob. 56ECh. 4 - Prob. 57ECh. 4 - Prob. 58ECh. 4 - Prob. 59ECh. 4 - Prob. 60ECh. 4 - Complete and balance each gas-evolution reaction...Ch. 4 - 62. Complete and balance each gas-evolution...Ch. 4 - Prob. 63ECh. 4 - Prob. 64ECh. 4 - Prob. 65ECh. 4 - What is the oxidation state of CI in each ion? a....Ch. 4 - Indicate which reactions are redox reactions. For...Ch. 4 - Prob. 68ECh. 4 - Prob. 69ECh. 4 - Prob. 70ECh. 4 - Prob. 71ECh. 4 - Prob. 72ECh. 4 - Prob. 73ECh. 4 - Prob. 74ECh. 4 - Prob. 75ECh. 4 - Prob. 76ECh. 4 - Prob. 77ECh. 4 - Prob. 78ECh. 4 - Prob. 79ECh. 4 - Prob. 80ECh. 4 - Predict the products of each reaction and write...Ch. 4 - Prob. 82ECh. 4 - Hard water often contains dissloved Ca2+ and Mg2+...Ch. 4 - An acid solution is 0.100 M in HCl and 0.200 M in...Ch. 4 - Prob. 85ECh. 4 - A solution contains Cr3+ ion and Mg2+ ion. The...Ch. 4 - Prob. 87ECh. 4 - Prob. 88ECh. 4 - Prob. 89ECh. 4 - 90. A solution is prepared by mixing 0.10 L of...Ch. 4 - Prob. 91ECh. 4 - Prob. 92ECh. 4 - Prob. 93ECh. 4 - An ilmenite-sand mixture contains 22.8% ilmenite...Ch. 4 - Prob. 95ECh. 4 - Prob. 96ECh. 4 - Lead poisoning is a serious condition resulting...Ch. 4 - Prob. 98ECh. 4 - Metallic aluminum reacts with MnO2 at elevated...Ch. 4 - Prob. 100ECh. 4 - Prob. 101ECh. 4 - Consider the reaction....Ch. 4 - Prob. 103ECh. 4 - Prob. 104ECh. 4 - Consider the generic ionic compounds with the...
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
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