ACHIEVE/CHEMICAL PRINCIPLES ACCESS 2TERM
7th Edition
ISBN: 9781319403959
Author: ATKINS
Publisher: MAC HIGHER
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Chapter 4, Problem 4D.14E
Interpretation Introduction
Interpretation:
The standard reaction enthalpy for the oxidation of nitric acid to nitrogen dioxidehas to be determined.
Concept Introduction:
Hess’s law is defined as the law which states that the enthalpy of a reaction does not depend on the path followed by reaction. It depends only on the standard enthalpy of formations for estimating the enthalpy of a reaction. The standard enthalpy of reaction that is
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Part VI.
Ca H 10 O is the molecular formula of compound Tom and gives the
in the table below. Give a possible structure for compound Tom.
13C
Signals summarized
C1
C2
C3
C4
C5
C6
C7
13C shift (ppm)
23.5
27.0
33.0
35.8
127
162
205
DEPT-90
+
DEPT-135
+
+
2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at
373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and
molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.
Part VII. Below are the 'HNMR
13
3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
ли
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8
f1 (ppm)
Chapter 4 Solutions
ACHIEVE/CHEMICAL PRINCIPLES ACCESS 2TERM
Ch. 4 - Prob. 4A.1ASTCh. 4 - Prob. 4A.1BSTCh. 4 - Prob. 4A.2ASTCh. 4 - Prob. 4A.2BSTCh. 4 - Prob. 4A.3ASTCh. 4 - Prob. 4A.3BSTCh. 4 - Prob. 4A.4ASTCh. 4 - Prob. 4A.4BSTCh. 4 - Prob. 4A.1ECh. 4 - Prob. 4A.2E
Ch. 4 - Prob. 4A.3ECh. 4 - Prob. 4A.4ECh. 4 - Prob. 4A.5ECh. 4 - Prob. 4A.6ECh. 4 - Prob. 4A.7ECh. 4 - Prob. 4A.8ECh. 4 - Prob. 4A.9ECh. 4 - Prob. 4A.10ECh. 4 - Prob. 4A.11ECh. 4 - Prob. 4A.12ECh. 4 - Prob. 4A.13ECh. 4 - Prob. 4A.14ECh. 4 - Prob. 4B.1ASTCh. 4 - Prob. 4B.1BSTCh. 4 - Prob. 4B.2ASTCh. 4 - Prob. 4B.2BSTCh. 4 - Prob. 4B.3ASTCh. 4 - Prob. 4B.3BSTCh. 4 - Prob. 4B.1ECh. 4 - Prob. 4B.2ECh. 4 - Prob. 4B.3ECh. 4 - Prob. 4B.4ECh. 4 - Prob. 4B.5ECh. 4 - Prob. 4B.6ECh. 4 - Prob. 4B.7ECh. 4 - Prob. 4B.8ECh. 4 - Prob. 4B.9ECh. 4 - Prob. 4B.10ECh. 4 - Prob. 4B.11ECh. 4 - Prob. 4B.12ECh. 4 - Prob. 4B.13ECh. 4 - Prob. 4B.14ECh. 4 - Prob. 4B.15ECh. 4 - Prob. 4B.16ECh. 4 - Prob. 4C.1ASTCh. 4 - Prob. 4C.1BSTCh. 4 - Prob. 4C.2ASTCh. 4 - Prob. 4C.2BSTCh. 4 - Prob. 4C.3ASTCh. 4 - Prob. 4C.3BSTCh. 4 - Prob. 4C.4ASTCh. 4 - Prob. 4C.4BSTCh. 4 - Prob. 4C.1ECh. 4 - Prob. 4C.2ECh. 4 - Prob. 4C.3ECh. 4 - Prob. 4C.4ECh. 4 - Prob. 4C.5ECh. 4 - Prob. 4C.6ECh. 4 - Prob. 4C.7ECh. 4 - Prob. 4C.8ECh. 4 - Prob. 4C.9ECh. 4 - Prob. 4C.10ECh. 4 - Prob. 4C.11ECh. 4 - Prob. 4C.12ECh. 4 - Prob. 4C.13ECh. 4 - Prob. 4C.14ECh. 4 - Prob. 4C.15ECh. 4 - Prob. 4C.16ECh. 4 - Prob. 4D.1ASTCh. 4 - Prob. 4D.1BSTCh. 4 - Prob. 4D.2ASTCh. 4 - Prob. 4D.2BSTCh. 4 - Prob. 4D.3ASTCh. 4 - Prob. 4D.3BSTCh. 4 - Prob. 4D.4ASTCh. 4 - Prob. 4D.4BSTCh. 4 - Prob. 4D.5ASTCh. 4 - Prob. 4D.5BSTCh. 4 - Prob. 4D.6ASTCh. 4 - Prob. 4D.6BSTCh. 4 - Prob. 4D.7ASTCh. 4 - Prob. 4D.7BSTCh. 4 - Prob. 4D.1ECh. 4 - Prob. 4D.2ECh. 4 - Prob. 4D.3ECh. 4 - Prob. 4D.4ECh. 4 - Prob. 4D.5ECh. 4 - Prob. 4D.6ECh. 4 - Prob. 4D.7ECh. 4 - Prob. 4D.8ECh. 4 - Prob. 4D.10ECh. 4 - Prob. 4D.11ECh. 4 - Prob. 4D.13ECh. 4 - Prob. 4D.14ECh. 4 - Prob. 4D.15ECh. 4 - Prob. 4D.16ECh. 4 - Prob. 4D.17ECh. 4 - Prob. 4D.18ECh. 4 - Prob. 4D.19ECh. 4 - Prob. 4D.20ECh. 4 - Prob. 4D.21ECh. 4 - Prob. 4D.22ECh. 4 - Prob. 4D.23ECh. 4 - Prob. 4D.24ECh. 4 - Prob. 4D.25ECh. 4 - Prob. 4D.26ECh. 4 - Prob. 4D.29ECh. 4 - Prob. 4D.30ECh. 4 - Prob. 4E.1ASTCh. 4 - Prob. 4E.1BSTCh. 4 - Prob. 4E.2ASTCh. 4 - Prob. 4E.2BSTCh. 4 - Prob. 4E.5ECh. 4 - Prob. 4E.6ECh. 4 - Prob. 4E.7ECh. 4 - Prob. 4E.8ECh. 4 - Prob. 4E.9ECh. 4 - Prob. 4E.10ECh. 4 - Prob. 4F.1ASTCh. 4 - Prob. 4F.1BSTCh. 4 - Prob. 4F.2ASTCh. 4 - Prob. 4F.2BSTCh. 4 - Prob. 4F.3ASTCh. 4 - Prob. 4F.3BSTCh. 4 - Prob. 4F.4ASTCh. 4 - Prob. 4F.4BSTCh. 4 - Prob. 4F.5ASTCh. 4 - Prob. 4F.5BSTCh. 4 - Prob. 4F.6ASTCh. 4 - Prob. 4F.6BSTCh. 4 - Prob. 4F.7ASTCh. 4 - Prob. 4F.7BSTCh. 4 - Prob. 4F.8ASTCh. 4 - Prob. 4F.8BSTCh. 4 - Prob. 4F.9ASTCh. 4 - Prob. 4F.9BSTCh. 4 - Prob. 4F.1ECh. 4 - Prob. 4F.2ECh. 4 - Prob. 4F.3ECh. 4 - Prob. 4F.4ECh. 4 - Prob. 4F.5ECh. 4 - Prob. 4F.6ECh. 4 - Prob. 4F.7ECh. 4 - Prob. 4F.9ECh. 4 - Prob. 4F.10ECh. 4 - Prob. 4F.11ECh. 4 - Prob. 4F.12ECh. 4 - Prob. 4F.13ECh. 4 - Prob. 4F.14ECh. 4 - Prob. 4F.15ECh. 4 - Prob. 4F.16ECh. 4 - Prob. 4F.17ECh. 4 - Prob. 4G.1ASTCh. 4 - Prob. 4G.1BSTCh. 4 - Prob. 4G.2ASTCh. 4 - Prob. 4G.2BSTCh. 4 - Prob. 4G.1ECh. 4 - Prob. 4G.2ECh. 4 - Prob. 4G.3ECh. 4 - Prob. 4G.5ECh. 4 - Prob. 4G.7ECh. 4 - Prob. 4G.8ECh. 4 - Prob. 4G.9ECh. 4 - Prob. 4G.10ECh. 4 - Prob. 4H.1ASTCh. 4 - Prob. 4H.1BSTCh. 4 - Prob. 4H.2ASTCh. 4 - Prob. 4H.2BSTCh. 4 - Prob. 4H.1ECh. 4 - Prob. 4H.2ECh. 4 - Prob. 4H.3ECh. 4 - Prob. 4H.4ECh. 4 - Prob. 4H.5ECh. 4 - Prob. 4H.6ECh. 4 - Prob. 4H.7ECh. 4 - Prob. 4H.8ECh. 4 - Prob. 4H.9ECh. 4 - Prob. 4H.10ECh. 4 - Prob. 4H.11ECh. 4 - Prob. 4I.1ASTCh. 4 - Prob. 4I.1BSTCh. 4 - Prob. 4I.2ASTCh. 4 - Prob. 4I.2BSTCh. 4 - Prob. 4I.3ASTCh. 4 - Prob. 4I.3BSTCh. 4 - Prob. 4I.4ASTCh. 4 - Prob. 4I.4BSTCh. 4 - Prob. 4I.1ECh. 4 - Prob. 4I.2ECh. 4 - Prob. 4I.3ECh. 4 - Prob. 4I.4ECh. 4 - Prob. 4I.5ECh. 4 - Prob. 4I.6ECh. 4 - Prob. 4I.7ECh. 4 - Prob. 4I.8ECh. 4 - Prob. 4I.9ECh. 4 - Prob. 4I.10ECh. 4 - Prob. 4I.11ECh. 4 - Prob. 4I.12ECh. 4 - Prob. 4J.1ASTCh. 4 - Prob. 4J.1BSTCh. 4 - Prob. 4J.2ASTCh. 4 - Prob. 4J.2BSTCh. 4 - Prob. 4J.3ASTCh. 4 - Prob. 4J.3BSTCh. 4 - Prob. 4J.4ASTCh. 4 - Prob. 4J.4BSTCh. 4 - Prob. 4J.5ASTCh. 4 - Prob. 4J.5BSTCh. 4 - Prob. 4J.6ASTCh. 4 - Prob. 4J.6BSTCh. 4 - Prob. 4J.1ECh. 4 - Prob. 4J.2ECh. 4 - Prob. 4J.3ECh. 4 - Prob. 4J.4ECh. 4 - Prob. 4J.5ECh. 4 - Prob. 4J.6ECh. 4 - Prob. 4J.7ECh. 4 - Prob. 4J.8ECh. 4 - Prob. 4J.9ECh. 4 - Prob. 4J.11ECh. 4 - Prob. 4J.12ECh. 4 - Prob. 4J.13ECh. 4 - Prob. 4J.14ECh. 4 - Prob. 4J.15ECh. 4 - Prob. 4J.16ECh. 4 - Prob. 4.8ECh. 4 - Prob. 4.14ECh. 4 - Prob. 4.16ECh. 4 - Prob. 4.19ECh. 4 - Prob. 4.20ECh. 4 - Prob. 4.21ECh. 4 - Prob. 4.23ECh. 4 - Prob. 4.25ECh. 4 - Prob. 4.27ECh. 4 - Prob. 4.28ECh. 4 - Prob. 4.29ECh. 4 - Prob. 4.30ECh. 4 - Prob. 4.31ECh. 4 - Prob. 4.32ECh. 4 - Prob. 4.33ECh. 4 - Prob. 4.34ECh. 4 - Prob. 4.35ECh. 4 - Prob. 4.36ECh. 4 - Prob. 4.37ECh. 4 - Prob. 4.39ECh. 4 - Prob. 4.40ECh. 4 - Prob. 4.41ECh. 4 - Prob. 4.45ECh. 4 - Prob. 4.46ECh. 4 - Prob. 4.48ECh. 4 - Prob. 4.49ECh. 4 - Prob. 4.53ECh. 4 - Prob. 4.57ECh. 4 - Prob. 4.59E
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