Connect 2-Year Online Access for General, Organic, and Biochemistry
9th Edition
ISBN: 9781259677946
Author: Denniston
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 4, Problem 4.98QP
Interpretation Introduction
Interpretation:
An application of electrolytic cells has to be described.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 4 Solutions
Connect 2-Year Online Access for General, Organic, and Biochemistry
Ch. 4.1 - Calculate the mass, in g, of Avogadro’s number...Ch. 4.1 - Prob. 4.2PPCh. 4.1 - Prob. 4.3PPCh. 4.1 - What is the mass, in g, of 3.50 mol of the element...Ch. 4.1 - Calculate the number of mol of silver in a silver...Ch. 4.1 - Prob. 4.6PPCh. 4.1 - Prob. 4.1QCh. 4.1 - Prob. 4.2QCh. 4.2 - Prob. 4.7PPCh. 4.2 - Prob. 4.8PP
Ch. 4.2 - Prob. 4.3QCh. 4.2 - Prob. 4.4QCh. 4.3 - Prob. 4.5QCh. 4.3 - Prob. 4.6QCh. 4.4 - Prob. 4.9PPCh. 4.4 - Prob. 4.10PPCh. 4.5 - Prob. 4.11PPCh. 4.6 - Prob. 4.12PPCh. 4.6 - Prob. 4.7QCh. 4.6 - Prob. 4.8QCh. 4.8 - Prob. 4.9QCh. 4.8 - Prob. 4.10QCh. 4.8 - Prob. 4.11QCh. 4.8 - Prob. 4.12QCh. 4.8 - Chrome plating involves the reduction of Cr3+(aq)...Ch. 4.8 - Prob. 4.14QCh. 4.9 - Prob. 4.13PPCh. 4.9 - When potassium cyanide (KCN) reacts with...Ch. 4.9 - Prob. 4.15PPCh. 4.9 - Prob. 4.16PPCh. 4.9 - Prob. 4.17PPCh. 4.9 - Barium carbonate decomposes upon heating to barium...Ch. 4.9 - Prob. 4.19PPCh. 4.9 - Prob. 4.15QCh. 4.9 - Prob. 4.16QCh. 4 - Prob. 4.17QPCh. 4 - What is the average mass (in amu) of:
Zr
Cs
Ca
Ch. 4 - What is the average molar mass of:
Si
Ag
As
Ch. 4 - What is the average molar mass of:
S
Na
Hg
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0.10...Ch. 4 - What is the mass, in g, of 15.0 mol of silver?
Ch. 4 - What is the mass, in g, of 15.0 mol of carbon?
Ch. 4 - Calculate the number of silver atoms in 15.0 g of...Ch. 4 - Calculate the number of carbon atoms in 15.0 g of...Ch. 4 - Prob. 4.37QPCh. 4 - Distinguish between the terms formula mass and...Ch. 4 - Calculate formula mass and the molar mass of each...Ch. 4 - Calculate formula mass and the molar mass of each...Ch. 4 - Calculate formula mass and the molar mass of...Ch. 4 - Calculate formula mass and the molar mass of...Ch. 4 - Calculate formula mass and the molar mass of CuSO4...Ch. 4 - Calculate formula mass and the molar mass of CaCl2...Ch. 4 - Calculate the number of mol corresponding to:
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15.0...Ch. 4 - Calculate the mass in g corresponding to:
1.000...Ch. 4 - Calculate the mass in g corresponding to:
0.400...Ch. 4 - How many g are required to have 0.100 mol of each...Ch. 4 - Prob. 4.50QPCh. 4 - How many mol are in 50.0 g of each of the...Ch. 4 - How many mol are in 50.0 g of each of the...Ch. 4 - What law is the ultimate basis for a balanced...Ch. 4 - List the general types of information that a...Ch. 4 - Prob. 4.55QPCh. 4 - Prob. 4.56QPCh. 4 - Prob. 4.57QPCh. 4 - What is the meaning of (s), (l), (g), and (aq)...Ch. 4 - Prob. 4.59QPCh. 4 - Prob. 4.60QPCh. 4 - What is the meaning of the subscript in a chemical...Ch. 4 - What is the meaning of the coefficient in a...Ch. 4 - When you are balancing an equation, why must the...Ch. 4 - Describe the process of checking to ensure that an...Ch. 4 - Prob. 4.65QPCh. 4 - Prob. 4.66QPCh. 4 - Prob. 4.67QPCh. 4 - Prob. 4.68QPCh. 4 - Prob. 4.69QPCh. 4 - Balance each of the following equations:
Ch. 4 - Write a balanced equation for each of the...Ch. 4 - Prob. 4.72QPCh. 4 - 4.67 Which of the following ionic compounds will...Ch. 4 - Prob. 4.74QPCh. 4 - Will a precipitate form if solutions of the...Ch. 4 - Prob. 4.76QPCh. 4 - Solutions containing (NH4)2CO3(aq) and CaCl2(aq)...Ch. 4 - Prob. 4.78QPCh. 4 - Describe the difference between the terms ionic...Ch. 4 - Prob. 4.80QPCh. 4 - Write the net ionic equation for the reaction of...Ch. 4 - Prob. 4.82QPCh. 4 - Does an acid gain or lose a hydrogen cation, H+,...Ch. 4 - Prob. 4.84QPCh. 4 - Identify the acid and base in the following...Ch. 4 - Prob. 4.86QPCh. 4 - Prob. 4.87QPCh. 4 - Prob. 4.88QPCh. 4 - Prob. 4.89QPCh. 4 - Prob. 4.90QPCh. 4 - In the following reaction, identify the oxidized...Ch. 4 - Prob. 4.92QPCh. 4 - Prob. 4.93QPCh. 4 - Prob. 4.94QPCh. 4 - Prob. 4.95QPCh. 4 - Prob. 4.96QPCh. 4 - Prob. 4.97QPCh. 4 - Prob. 4.98QPCh. 4 - Why is it essential to use balanced equations to...Ch. 4 - Describe the steps used in the calculation of g of...Ch. 4 - How many g of B2H6 will react with 3.00 mol of...Ch. 4 - How many g of Al will react with 3.00 mol of O2?
Ch. 4 - Calculate the number of moles of CrCl3 that could...Ch. 4 - A 3.5-g sample of water reacts with PCl3 according...Ch. 4 - Prob. 4.105QPCh. 4 - Prob. 4.106QPCh. 4 - Prob. 4.107QPCh. 4 - Triglycerides (Chapters 17 and 23) are used in...Ch. 4 - Joseph Priestley discovered oxygen in the...Ch. 4 - Dinitrogen monoxide (also known as nitrous oxide...Ch. 4 - The burning of acetylene (C2H2) in oxygen is the...Ch. 4 - Prob. 4.112QPCh. 4 - Various members of a class of compounds called...Ch. 4 - Prob. 4.114QPCh. 4 - A rocket can be powered by the reaction between...Ch. 4 - A 4.00-g sample of Fe3O4 reacts with O2 to produce...Ch. 4 - If the actual yield of decane in Question 4.99 is...Ch. 4 - If the actual yield of oxygen gas in Question...Ch. 4 - If the % yield of nitrogen gas in Question 4.101...Ch. 4 - If the % yield of Fe2O3 in Question 4.102 is...Ch. 4 - Prob. 1CPCh. 4 - Prob. 2CPCh. 4 - Prob. 3CPCh. 4 - Prob. 4CPCh. 4 - Prob. 5CP
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