Physical Chemistry
2nd Edition
ISBN: 9781285969770
Author: Ball
Publisher: Cengage
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Chapter 4, Problem 4.4E
Explain why the spontaneity conditions given in the equation
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Chapter 4 Solutions
Physical Chemistry
Ch. 4 - List the sets of conditions that allow dS, dU, and...Ch. 4 - Explain why conditions for using S>0 as a strict...Ch. 4 - Explain how the equation dU+pdVTdS0 is consistent...Ch. 4 - Explain why the spontaneity conditions given in...Ch. 4 - Prove that the adiabatic free expansion of an...Ch. 4 - Derive equation 4.6 from equation 4.5.Ch. 4 - Derive equation 4.8 from equation 4.7.Ch. 4 - The third part of equation 4.9 mentions a...Ch. 4 - Calculate A for a process in which 0.160mole of an...Ch. 4 - What is the maximum amount of non-pV work that can...
Ch. 4 - Consider a piston whose compression ratio is 10:1;...Ch. 4 - When one dives, water pressure increases by 1atm...Ch. 4 - Calculate G(25C) for this chemical reaction, which...Ch. 4 - Thermodynamic properties can also be determined...Ch. 4 - Calculate G in two different ways for the...Ch. 4 - Calculate G in two different ways for the...Ch. 4 - For the reaction C(graphite)C(diamond) at 25C,...Ch. 4 - Determine G for the following reaction at 0C and...Ch. 4 - What is the maximum amount of electrical that is,...Ch. 4 - When a person performs work, it is non-pV work....Ch. 4 - Can non-pV work be obtained from a process for...Ch. 4 - Can pV work be obtained from a process for which...Ch. 4 - Batteries are chemical systems that can be used to...Ch. 4 - The value of G for any phase change at constant p...Ch. 4 - The value of G for any phase change at constant p...Ch. 4 - Under what conditions is A=0 for a phase change?...Ch. 4 - Example 4.2 calculated A for one step of a Carnot...Ch. 4 - Can CV and Cp be easily defined using the natural...Ch. 4 - Analogous to equation 4.26, what is the expression...Ch. 4 - Prob. 4.30ECh. 4 - Prob. 4.31ECh. 4 - Prob. 4.32ECh. 4 - Although ideally, U=H=0 for a gas-phase process at...Ch. 4 - Use equations 4.21 and 4.25 to explain why H and G...Ch. 4 - Prob. 4.35ECh. 4 - Which of the following functions are exact...Ch. 4 - Prob. 4.37ECh. 4 - Prob. 4.38ECh. 4 - Prob. 4.39ECh. 4 - Equation 4.19 says that (UV)S=p If we are...Ch. 4 - For an isentropic process, what is the approximate...Ch. 4 - Use the ideal gas law to demonstrate the cyclic...Ch. 4 - Prob. 4.43ECh. 4 - Prob. 4.44ECh. 4 - Evaluate (U/V)T for an ideal gas. Use the...Ch. 4 - Evaluate (U/V)T for a van der Waals gas. Use the...Ch. 4 - Repeat the previous exercise for a gas that...Ch. 4 - Determine an expression for (p/S)T for an ideal...Ch. 4 - Determine the value of the derivative {[(G)]/T}p...Ch. 4 - Prob. 4.50ECh. 4 - Prob. 4.51ECh. 4 - A 0.988-mole sample of argon expands from 25.0L to...Ch. 4 - A 3.66-mol sample of He contracts from 15.5L to...Ch. 4 - Prob. 4.54ECh. 4 - Prob. 4.55ECh. 4 - Use the Gibbs-Helmholtz equation to demonstrate...Ch. 4 - For the equation 2H2(g)+O2(g)2H2O(g)...Ch. 4 - Use equation 4.46 as an example and find an...Ch. 4 - What is the value of G when 1.00mol of water at...Ch. 4 - Prob. 4.60ECh. 4 - Prob. 4.61ECh. 4 - Prob. 4.62ECh. 4 - Prob. 4.63ECh. 4 - Prob. 4.64ECh. 4 - What is the change in the chemical potential of a...Ch. 4 - Prob. 4.66ECh. 4 - Prob. 4.67ECh. 4 - Prob. 4.68ECh. 4 - Prob. 4.69ECh. 4 - Can equation 4.62 be used to calculate for an...Ch. 4 - Prob. 4.71ECh. 4 - Of helium and oxygen gases, which one do you...Ch. 4 - Prob. 4.73ECh. 4 - Use equation 4.39 to determine a numerical value...Ch. 4 - Prob. 4.75ECh. 4 - Prob. 4.76E
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- Please correct answer and don't used hand raitingarrow_forwardPlease correct answer and don't used hand raitingarrow_forward(a) The following synthesis of the molecule shown in the circle has a major problem. What is this problem? (2 pts) 1) HBr (no peroxides) 2) H- NaNH2 Br 3) NaNH, 4) CH3Br 5) H2, Pd (b) Starting with the molecule shown below and any other materials with two carbons or less, write out an alternate synthesis of the circled molecule. More than one step is needed. Indicate the reagent(s) and the major product in all the steps in your synthesis. (5 pts) 2024 Fall Term (1) Organic Chemistry 1 (Lec) CHEM 22204 02[6386] (Hunter College) (c) Using the same starting material as in part (b) and any other materials win two carpons or less, write out syntheses of the circled molecules shown below. More than one step is needed in each case. Indicate the reagent(s) and the major product in all the steps in your synthesis. You may use reactions and products from your synthesis in part (b). (5 pts)arrow_forward
- alt ons for Free Response Questions FRQ 1: 0/5 To spectrophotometrically determine the mass percent of cobalt in an ore containing cobalt and some inert materials, solutions with known [Co?) are prepared and absorbance of each of the solutions is measured at the wavelength of optimum absorbance. The data are used to create a calibration plot, shown below. 0.90- 0.80- 0.70 0.60 0.50 0.40- 0.30 0.20- 0.10- 0.00- 0.005 0.010 Concentration (M) 0.015 A 0.630 g sample of the ore is completely dissolved in concentrated HNO3(aq). The mixture is diluted with water to a final volume of 50.00 ml. Assume that all the cobalt in the ore sample is converted to Co2+(aq). a. What is the [Co2] in the solution if the absorbance of a sample of the solution is 0.74? 13 ✗ b. Calculate the number of moles of Co2+(aq) in the 50.00 mL solution. 0.008 mols Coarrow_forwardPlease correct answer and don't used hand raitingarrow_forwardCloso-boranes and arachno-boranes are structures that exhibit B-B, B-H-B, and B-H bonds. Correct?arrow_forward
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