Physical Chemistry
2nd Edition
ISBN: 9781285969770
Author: Ball
Publisher: Cengage
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Chapter 4, Problem 4.17E
For the reaction
at
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8
00
6
= 10
10
Decide whether each of the molecules in the table below is stable, in the exact form in which it is drawn, at pH = 11.
If
you decide at least one molecule is not stable, then redraw one of the unstable molecules in its stable form below the table. (If more than
unstable, you can pick any of them to redraw.)
Check
OH
stable
HO
stable
Ounstable
unstable
O
OH
stable
unstable
OH
80
F6
F5
stable
Ounstable
X
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2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy C
ཀྭ་
A
F7
매
F8
F9
4
F10
Just try completing it and it should be straightforward according to the professor and TAs.
The grading is not on correctness, so if you can just get to the correct answers without perfectionism that would be great. They care about the steps and reasoning and that you did something. I asked for an extension, but was denied the extension.
Chapter 4 Solutions
Physical Chemistry
Ch. 4 - List the sets of conditions that allow dS, dU, and...Ch. 4 - Explain why conditions for using S>0 as a strict...Ch. 4 - Explain how the equation dU+pdVTdS0 is consistent...Ch. 4 - Explain why the spontaneity conditions given in...Ch. 4 - Prove that the adiabatic free expansion of an...Ch. 4 - Derive equation 4.6 from equation 4.5.Ch. 4 - Derive equation 4.8 from equation 4.7.Ch. 4 - The third part of equation 4.9 mentions a...Ch. 4 - Calculate A for a process in which 0.160mole of an...Ch. 4 - What is the maximum amount of non-pV work that can...
Ch. 4 - Consider a piston whose compression ratio is 10:1;...Ch. 4 - When one dives, water pressure increases by 1atm...Ch. 4 - Calculate G(25C) for this chemical reaction, which...Ch. 4 - Thermodynamic properties can also be determined...Ch. 4 - Calculate G in two different ways for the...Ch. 4 - Calculate G in two different ways for the...Ch. 4 - For the reaction C(graphite)C(diamond) at 25C,...Ch. 4 - Determine G for the following reaction at 0C and...Ch. 4 - What is the maximum amount of electrical that is,...Ch. 4 - When a person performs work, it is non-pV work....Ch. 4 - Can non-pV work be obtained from a process for...Ch. 4 - Can pV work be obtained from a process for which...Ch. 4 - Batteries are chemical systems that can be used to...Ch. 4 - The value of G for any phase change at constant p...Ch. 4 - The value of G for any phase change at constant p...Ch. 4 - Under what conditions is A=0 for a phase change?...Ch. 4 - Example 4.2 calculated A for one step of a Carnot...Ch. 4 - Can CV and Cp be easily defined using the natural...Ch. 4 - Analogous to equation 4.26, what is the expression...Ch. 4 - Prob. 4.30ECh. 4 - Prob. 4.31ECh. 4 - Prob. 4.32ECh. 4 - Although ideally, U=H=0 for a gas-phase process at...Ch. 4 - Use equations 4.21 and 4.25 to explain why H and G...Ch. 4 - Prob. 4.35ECh. 4 - Which of the following functions are exact...Ch. 4 - Prob. 4.37ECh. 4 - Prob. 4.38ECh. 4 - Prob. 4.39ECh. 4 - Equation 4.19 says that (UV)S=p If we are...Ch. 4 - For an isentropic process, what is the approximate...Ch. 4 - Use the ideal gas law to demonstrate the cyclic...Ch. 4 - Prob. 4.43ECh. 4 - Prob. 4.44ECh. 4 - Evaluate (U/V)T for an ideal gas. Use the...Ch. 4 - Evaluate (U/V)T for a van der Waals gas. Use the...Ch. 4 - Repeat the previous exercise for a gas that...Ch. 4 - Determine an expression for (p/S)T for an ideal...Ch. 4 - Determine the value of the derivative {[(G)]/T}p...Ch. 4 - Prob. 4.50ECh. 4 - Prob. 4.51ECh. 4 - A 0.988-mole sample of argon expands from 25.0L to...Ch. 4 - A 3.66-mol sample of He contracts from 15.5L to...Ch. 4 - Prob. 4.54ECh. 4 - Prob. 4.55ECh. 4 - Use the Gibbs-Helmholtz equation to demonstrate...Ch. 4 - For the equation 2H2(g)+O2(g)2H2O(g)...Ch. 4 - Use equation 4.46 as an example and find an...Ch. 4 - What is the value of G when 1.00mol of water at...Ch. 4 - Prob. 4.60ECh. 4 - Prob. 4.61ECh. 4 - Prob. 4.62ECh. 4 - Prob. 4.63ECh. 4 - Prob. 4.64ECh. 4 - What is the change in the chemical potential of a...Ch. 4 - Prob. 4.66ECh. 4 - Prob. 4.67ECh. 4 - Prob. 4.68ECh. 4 - Prob. 4.69ECh. 4 - Can equation 4.62 be used to calculate for an...Ch. 4 - Prob. 4.71ECh. 4 - Of helium and oxygen gases, which one do you...Ch. 4 - Prob. 4.73ECh. 4 - Use equation 4.39 to determine a numerical value...Ch. 4 - Prob. 4.75ECh. 4 - Prob. 4.76E
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- Show your work and do something that is reasonable. It does not have to be 100% correct. Just show something that looks good or pretty good as acceptable answers. Something that looks reasonable or correct would be sufficient. If you can get many of them correct that would be great!arrow_forwardShow your work and do something that is reasonable. It does not have to be 100% correct. Just show something that looks good or pretty good as acceptable answers. Something that looks reasonable or correct would be sufficient. If you can get many of them correct that would be great!arrow_forwardTake a look at the following molecule, and then answer the questions in the table below it. (You can click the other tab to see the molecule without the colored regions.) with colored region plain 0= CH2-0-C-(CH2)16-CH3 =0 CH-O-C (CH2)7-CH=CH-(CH2)5-CH3 D CH3 | + OMPLO CH3-N-CH2-CH2-0-P-O-CH2 B CH3 A Try again * 000 Ar 8 0 ?arrow_forward
- Show your work and do something that is reasonable. It does not have to be 100% correct. Just show something that looks good or pretty good as acceptable answers.arrow_forwardShow your work and do something that is reasonable. It does not have to be 100% correct. Just show something that looks good or pretty good as acceptable answers.arrow_forward= 1 = 2 3 4 5 6 ✓ 7 8 ✓ 9 =10 Devise a synthesis to prepare the product from the given starting material. Complete the following reaction scheme. Part 1 of 3 -Br Draw the structure for compound A. Check Step 1 Step 2 A Click and drag to start drawing a structure. × ↓m + OH Save For Later S 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privaarrow_forward
- Predict the products of this organic reduction: 田 Check AP + + H2 Lindlar catalyst Click an drawing 2025 McGraw Hill LLC. All Rigarrow_forward70 Suppose the molecule below is in acidic aqueous solution. Is keto-enol tautomerization possible? • If a keto-enol tautomerization is possible, draw the mechanism for it. Be sure any extra reagents you add to the left-hand sid available in this solution. • If a keto-enol tautomerization is not possible, check the box under the drawing area. : ☐ Add/Remove step Click and drag to st drawing a structure Check Save For Late. 2025 McGraw Hill LLC. All Rights Reserved. Terms of Usearrow_forwardThe problem will not be graded for correctness, but you have to get a reasonable answer something that is either correct or very closer to the correct answer. The instructor professor wants us to do something that shows the answer but everything does not have to be correct. Ideally, yes, it has to be correct. Give it your best shot.arrow_forward
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