(a) Interpretation: For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable. Concept introduction: In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

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Answer 1

Question

Chapter 4, Problem 4.44P

Interpretation Introduction

(a)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Interpretation Introduction

(b)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Interpretation Introduction

(c)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

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Part V. Label ad match the carbons in compounds Jane and Diane w/ the corresponding peak no. in the Spectra (Note: use the given peak no. To label the carbons, other peak no are intentionally omitted) 7 4 2 -0.13 -0.12 -0.11 -0.10 -0.08 8 CI Jane 1 -0.09 5 210 200 190 180 170 160 150 140 130 120 110 100 -8 90 f1 (ppm) 11 8 172.4 172.0 f1 (ppr HO CI NH Diane 7 3 11 80 80 -80 -R 70 60 60 2 5 -8 50 40 8. 170 160 150 140 130 120 110 100 90 -0 80 70 20 f1 (ppm) 15 30 -20 20 -60 60 -0.07 -0.06 -0.05 -0.04 -0.03 -0.02 -0.01 -0.00 -0.01 10 -0.17 16 15 56 16 -0.16 -0.15 -0.14 -0.13 -0.12 -0.11 -0.10 -0.09 -0.08 -0.07 -0.06 -0.05 -0.04 17.8 17.6 17.4 17.2 17.0 f1 (ppm) -0.03 -0.02 550 106 40 30 20 20 -0.01 -0.00 F-0.01 10 0

Answer 2

Question

Chapter 4, Problem 4.44P

Interpretation Introduction

(a)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Interpretation Introduction

(b)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Interpretation Introduction

(c)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

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Answer 3

Question

Chapter 4, Problem 4.44P

Interpretation Introduction

(a)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Interpretation Introduction

(b)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Interpretation Introduction

(c)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

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Answer 4

Question

Chapter 4, Problem 4.44P

Interpretation Introduction

(a)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Interpretation Introduction

(b)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Interpretation Introduction

(c)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

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Answer 5

Chapter 4, Problem 4.44P

Interpretation Introduction

(a)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Interpretation Introduction

(b)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Interpretation Introduction

(c)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Answer 6

Chapter 4, Problem 4.44P

Interpretation Introduction

(a)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Answer 7

Chapter 4, Problem 4.44P

Interpretation Introduction

(a)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Answer 8

Interpretation Introduction

(b)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Answer 9

Interpretation Introduction

(b)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Answer 10

Interpretation Introduction

(c)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Answer 11

Interpretation Introduction

(c)

Interpretation:

For the given disubstituted cyclohexane, it is to be determined if the cis or trans isomer is more stable.

Concept introduction:

In the disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other and the substituents which are on the same side are cis to each other. In the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 4 - Prob. 4.1P Ch. 4 - Prob. 4.2P Ch. 4 - Prob. 4.3P Ch. 4 - Prob. 4.4P Ch. 4 - Prob. 4.5P Ch. 4 - Prob. 4.6P Ch. 4 - Prob. 4.7P Ch. 4 - Prob. 4.8P Ch. 4 - Prob. 4.9P Ch. 4 - Prob. 4.10P

Solution Summary: The author explains that in the case of disubstituted cyclohexane, the conformation in which maximum substituents are in equatorial position is favored and is more stable.

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