EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 8220103151757
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 4, Problem 4.34P
Interpretation Introduction

(a)

Interpretation:

The five isomeric structures of alkene C6H12 that give hexane as a product on catalytic hydrogenation are to be stated.

Concept introduction:

Alkenes are the unsaturated class of organic compounds which have a double bond in their structure. The general formula of alkene which is written as CnH2n. It is more reactive than alkanes which have only a single bond in their structure. Constitutional isomers are compounds that have the same molecular formula but different bond connectivity.

Interpretation Introduction

(b)

Interpretation:

The number of alkenes that on catalytic hydrogenation gives cyclopentane and its structures is to be stated.

Concept introduction:

Alkenes are the unsaturated class of organic compounds which have a double bond in their structure. The general formula of alkene which is written as CnH2n. It is more reactive than alkanes which have only a single bond in their structure. Constitutional isomers are compounds that have the same molecular formula but different bond connectivity.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.
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