(a) Interpretation: The given isomeric carbocations are to be classified as primary, secondary and tertiary and the most stable carbocation is to be predicted. Concept introduction: Carbocations are the reaction intermediates and they contain the electron deficient positively charged carbon atom. The electron deficient carbon is s p 2 hybridized. A carbocation has the tendency to rearrange itself to become a more stable carbocation.

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Answer 1

Question

Chapter 4, Problem 4.20P

Interpretation Introduction

(a)

Interpretation:

The given isomeric carbocations are to be classified as primary, secondary and tertiary and the most stable carbocation is to be predicted.

Concept introduction:

Carbocations are the reaction intermediates and they contain the electron deficient positively charged carbon atom. The electron deficient carbon is sp2 hybridized. A carbocation has the tendency to rearrange itself to become a more stable carbocation.

Interpretation Introduction

(b)

Interpretation:

The given isomeric carbocations are to be classified as primary, secondary and tertiary and the most stable carbocation is to be predicted.

Concept introduction:

Carbocations are the reaction intermediates and they contain the electron deficient positively charged carbon atom. The electron deficient carbon is sp2 hybridized. A carbocation has the tendency to rearrange itself to become a more stable carbocation.

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3

Answer 2

Question

Chapter 4, Problem 4.20P

Interpretation Introduction

(a)

Interpretation:

The given isomeric carbocations are to be classified as primary, secondary and tertiary and the most stable carbocation is to be predicted.

Concept introduction:

Carbocations are the reaction intermediates and they contain the electron deficient positively charged carbon atom. The electron deficient carbon is sp2 hybridized. A carbocation has the tendency to rearrange itself to become a more stable carbocation.

Interpretation Introduction

(b)

Interpretation:

The given isomeric carbocations are to be classified as primary, secondary and tertiary and the most stable carbocation is to be predicted.

Concept introduction:

Carbocations are the reaction intermediates and they contain the electron deficient positively charged carbon atom. The electron deficient carbon is sp2 hybridized. A carbocation has the tendency to rearrange itself to become a more stable carbocation.

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Answer 3

Question

Chapter 4, Problem 4.20P

Interpretation Introduction

(a)

Interpretation:

The given isomeric carbocations are to be classified as primary, secondary and tertiary and the most stable carbocation is to be predicted.

Concept introduction:

Carbocations are the reaction intermediates and they contain the electron deficient positively charged carbon atom. The electron deficient carbon is sp2 hybridized. A carbocation has the tendency to rearrange itself to become a more stable carbocation.

Interpretation Introduction

(b)

Interpretation:

The given isomeric carbocations are to be classified as primary, secondary and tertiary and the most stable carbocation is to be predicted.

Concept introduction:

Carbocations are the reaction intermediates and they contain the electron deficient positively charged carbon atom. The electron deficient carbon is sp2 hybridized. A carbocation has the tendency to rearrange itself to become a more stable carbocation.

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Answer 4

Question

Chapter 4, Problem 4.20P

Interpretation Introduction

(a)

Interpretation:

The given isomeric carbocations are to be classified as primary, secondary and tertiary and the most stable carbocation is to be predicted.

Concept introduction:

Carbocations are the reaction intermediates and they contain the electron deficient positively charged carbon atom. The electron deficient carbon is sp2 hybridized. A carbocation has the tendency to rearrange itself to become a more stable carbocation.

Interpretation Introduction

(b)

Interpretation:

The given isomeric carbocations are to be classified as primary, secondary and tertiary and the most stable carbocation is to be predicted.

Concept introduction:

Carbocations are the reaction intermediates and they contain the electron deficient positively charged carbon atom. The electron deficient carbon is sp2 hybridized. A carbocation has the tendency to rearrange itself to become a more stable carbocation.

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Answer 5

Chapter 4, Problem 4.20P

Interpretation Introduction

(a)

Interpretation:

The given isomeric carbocations are to be classified as primary, secondary and tertiary and the most stable carbocation is to be predicted.

Concept introduction:

Carbocations are the reaction intermediates and they contain the electron deficient positively charged carbon atom. The electron deficient carbon is sp2 hybridized. A carbocation has the tendency to rearrange itself to become a more stable carbocation.

Interpretation Introduction

(b)

Interpretation:

The given isomeric carbocations are to be classified as primary, secondary and tertiary and the most stable carbocation is to be predicted.

Concept introduction:

Carbocations are the reaction intermediates and they contain the electron deficient positively charged carbon atom. The electron deficient carbon is sp2 hybridized. A carbocation has the tendency to rearrange itself to become a more stable carbocation.

Answer 6

Chapter 4, Problem 4.20P

Interpretation Introduction

(a)

Interpretation:

The given isomeric carbocations are to be classified as primary, secondary and tertiary and the most stable carbocation is to be predicted.

Concept introduction:

Carbocations are the reaction intermediates and they contain the electron deficient positively charged carbon atom. The electron deficient carbon is sp2 hybridized. A carbocation has the tendency to rearrange itself to become a more stable carbocation.

Answer 7

Chapter 4, Problem 4.20P

Interpretation Introduction

(a)

Interpretation:

The given isomeric carbocations are to be classified as primary, secondary and tertiary and the most stable carbocation is to be predicted.

Concept introduction:

Carbocations are the reaction intermediates and they contain the electron deficient positively charged carbon atom. The electron deficient carbon is sp2 hybridized. A carbocation has the tendency to rearrange itself to become a more stable carbocation.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The given isomeric carbocations are to be classified as primary, secondary and tertiary and the most stable carbocation is to be predicted.

Concept introduction:

Carbocations are the reaction intermediates and they contain the electron deficient positively charged carbon atom. The electron deficient carbon is sp2 hybridized. A carbocation has the tendency to rearrange itself to become a more stable carbocation.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The given isomeric carbocations are to be classified as primary, secondary and tertiary and the most stable carbocation is to be predicted.

Concept introduction:

Carbocations are the reaction intermediates and they contain the electron deficient positively charged carbon atom. The electron deficient carbon is sp2 hybridized. A carbocation has the tendency to rearrange itself to become a more stable carbocation.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 4 - Prob. 4.1P Ch. 4 - Prob. 4.2P Ch. 4 - Prob. 4.3P Ch. 4 - Prob. 4.4P Ch. 4 - Prob. 4.5P Ch. 4 - Prob. 4.6P Ch. 4 - Prob. 4.7P Ch. 4 - Prob. 4.8P Ch. 4 - Prob. 4.9P Ch. 4 - Prob. 4.10P

Solution Summary: The author explains that the isomeric carbocations are to be classified as primary, secondary, and tertiary.

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Chapter 4 Solutions