GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG
10th Edition
ISBN: 9781260699227
Author: Denniston
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Question
Chapter 4, Problem 4.30QP
Interpretation Introduction
Interpretation:
The number of carbon atoms that are present in
Concept Introduction:
Conversion steps - (Grams to Atoms):
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
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CI
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11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
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+
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occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
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3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
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B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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2
"Br
{t༐B,gt)-bemn€-nehpརི་ཚ༐lnoa
Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 4 Solutions
GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG
Ch. 4.1 - Calculate the mass, in g, of Avogadro’s number...Ch. 4.1 - Prob. 4.2PPCh. 4.1 - Prob. 4.3PPCh. 4.1 - What is the mass, in g, of 3.50 mol of the element...Ch. 4.1 - Calculate the number of mol of silver in a silver...Ch. 4.1 - Prob. 4.6PPCh. 4.1 - Prob. 4.1QCh. 4.1 - Prob. 4.2QCh. 4.2 - Prob. 4.7PPCh. 4.2 - Prob. 4.8PP
Ch. 4.2 - Prob. 4.3QCh. 4.2 - Prob. 4.4QCh. 4.3 - Prob. 4.5QCh. 4.3 - Prob. 4.6QCh. 4.4 - Prob. 4.9PPCh. 4.4 - Prob. 4.10PPCh. 4.5 - Prob. 4.11PPCh. 4.6 - Prob. 4.12PPCh. 4.6 - Prob. 4.7QCh. 4.6 - Prob. 4.8QCh. 4.9 - Prob. 4.13PPCh. 4.9 - When potassium cyanide (KCN) reacts with...Ch. 4.9 - Prob. 4.15PPCh. 4.9 - Prob. 4.16PPCh. 4.9 - Prob. 4.17PPCh. 4.9 - Barium carbonate decomposes upon heating to barium...Ch. 4.9 - Prob. 4.19PPCh. 4.9 - Prob. 4.9QCh. 4.9 - Prob. 4.10QCh. 4 - Prob. 4.11QPCh. 4 - What is the average mass (in amu) of:
Zr
Cs
Ca
Ch. 4 - What is the average molar mass of:
Si
Ag
As
Ch. 4 - What is the average molar mass of:
S
Na
Hg
Ch. 4 - What is the mass, in g, of Avogadro’s number of...Ch. 4 - What is the mass, in g, of Avogadro’s number of...Ch. 4 - How many carbon atoms are present in 1.0 × 10−4...Ch. 4 - How many mercury atoms are present in 1.0 × 10−10...Ch. 4 - How many mol of arsenic correspond to 1.0 × 102...Ch. 4 - How many mol of sodium correspond to 1.0 × 1015...Ch. 4 - How many g of neon are contained in 2.00 mol of...Ch. 4 - How many g of carbon are contained in 3.00 mol of...Ch. 4 - What is the mass, in g, of 1.00 mol of helium...Ch. 4 - What is the mass, in g, of 1.00 mol of nitrogen...Ch. 4 - Calculate the number of mol corresponding to:
20.0...Ch. 4 - Calculate the number of mol corresponding to:
0.10...Ch. 4 - What is the mass, in g, of 15.0 mol of silver?
Ch. 4 - What is the mass, in g, of 15.0 mol of carbon?
Ch. 4 - Calculate the number of silver atoms in 15.0 g of...Ch. 4 - Calculate the number of carbon atoms in 15.0 g of...Ch. 4 - Prob. 4.31QPCh. 4 - Distinguish between the terms formula mass and...Ch. 4 - Calculate formula mass and the molar mass of each...Ch. 4 - Calculate formula mass and the molar mass of each...Ch. 4 - Calculate formula mass and the molar mass of...Ch. 4 - Calculate formula mass and the molar mass of...Ch. 4 - Calculate formula mass and the molar mass of CuSO4...Ch. 4 - Calculate formula mass and the molar mass of CaCl2...Ch. 4 - Calculate the number of mol corresponding to:
15.0...Ch. 4 - Calculate the number of mol corresponding to:
15.0...Ch. 4 - Calculate the mass in g corresponding to:
1.000...Ch. 4 - Calculate the mass in g corresponding to:
0.400...Ch. 4 - How many g are required to have 0.100 mol of each...Ch. 4 - Prob. 4.44QPCh. 4 - How many mol are in 50.0 g of each of the...Ch. 4 - How many mol are in 50.0 g of each of the...Ch. 4 - What law is the ultimate basis for a balanced...Ch. 4 - List the general types of information that a...Ch. 4 - Prob. 4.49QPCh. 4 - Prob. 4.50QPCh. 4 - Prob. 4.51QPCh. 4 - What is the meaning of (s), (l), (g), and (aq)...Ch. 4 - Prob. 4.53QPCh. 4 - Prob. 4.54QPCh. 4 - What is the meaning of the subscript in a chemical...Ch. 4 - What is the meaning of the coefficient in a...Ch. 4 - When you are balancing an equation, why must the...Ch. 4 - Describe the process of checking to ensure that an...Ch. 4 - Prob. 4.59QPCh. 4 - Prob. 4.60QPCh. 4 - Prob. 4.61QPCh. 4 - Prob. 4.62QPCh. 4 - Prob. 4.63QPCh. 4 - Balance each of the following equations:
Ch. 4 - Write a balanced equation for each of the...Ch. 4 - Prob. 4.66QPCh. 4 - 4.67 Which of the following ionic compounds will...Ch. 4 - Prob. 4.68QPCh. 4 - Will a precipitate form if solutions of the...Ch. 4 - Prob. 4.70QPCh. 4 - Solutions containing (NH4)2CO3(aq) and CaCl2(aq)...Ch. 4 - Prob. 4.72QPCh. 4 - Describe the difference between the terms ionic...Ch. 4 - Prob. 4.74QPCh. 4 - Write the net ionic equation for the reaction of...Ch. 4 - Prob. 4.76QPCh. 4 - Does an acid gain or lose a hydrogen cation, H+,...Ch. 4 - Prob. 4.78QPCh. 4 - Identify the acid and base in the following...Ch. 4 - Prob. 4.80QPCh. 4 - Does the following equation represent oxidation or...Ch. 4 - Prob. 4.82QPCh. 4 - In the following reaction, identify the species...Ch. 4 - Prob. 4.84QPCh. 4 - Why is it essential to use balanced equations to...Ch. 4 - Describe the steps used in the calculation of g of...Ch. 4 - How many g of B2H6 will react with 3.00 mol of...Ch. 4 - How many g of Al will react with 3.00 mol of O2?
Ch. 4 - Calculate the number of moles of CrCl3 that could...Ch. 4 - A 3.5-g sample of water reacts with PCl3 according...Ch. 4 - Prob. 4.91QPCh. 4 - Prob. 4.92QPCh. 4 - Prob. 4.93QPCh. 4 - Triglycerides (Chapters 17 and 23) are used in...Ch. 4 - Joseph Priestley discovered oxygen in the...Ch. 4 - Dinitrogen monoxide (also known as nitrous oxide...Ch. 4 - The burning of acetylene (C2H2) in oxygen is the...Ch. 4 - Prob. 4.98QPCh. 4 - Various members of a class of compounds called...Ch. 4 - Prob. 4.100QPCh. 4 - A rocket can be powered by the reaction between...Ch. 4 - A 4.00-g sample of Fe3O4 reacts with O2 to produce...Ch. 4 - If the actual yield of decane in Question 4.99 is...Ch. 4 - If the actual yield of oxygen gas in Question...Ch. 4 - If the % yield of nitrogen gas in Question 4.101...Ch. 4 - If the % yield of Fe2O3 in Question 4.102 is...Ch. 4 - Prob. 1MCPCh. 4 - Prob. 2MCPCh. 4 - Prob. 3MCPCh. 4 - Prob. 4MCPCh. 4 - Prob. 5MCPCh. 4 - Prob. 7MCPCh. 4 - Prob. 8MCPCh. 4 - Prob. 9MCP
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