The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn. Concept introduction: In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.

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Answer 1

Question

Chapter 4, Problem 4.21YT

(a)

Interpretation Introduction

Interpretation:

The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.

(b)

Interpretation Introduction

Interpretation:

The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.

(c)

Interpretation Introduction

Interpretation:

The line structure (including with dash-wedge notation) for the given Haworth projection of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane. To draw the line structure from its Haworth projection, view the molecule either from the top of the plane or from the bottom of the plane.

(d)

Interpretation Introduction

Interpretation:

The line structure (including with dash-wedge notation) for the given Haworth projection of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane. To draw the line structure from its Haworth projection, view the molecule either from the top of the plane or from the bottom of the plane.

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B 1 of 2 Additional problems in preparation to Midterm #1: 1.) How can the following compounds be prepared using Diels-Alder reaction: CH3 O CN (a) (b) CN CH3 2.) What is the missing reagent in the shown reaction? H3C + ? H3C H3C CN H3C ''CN (၁) H 3.) Write the products 1,2-addition and 1,4-addition of DBr to 1,3-cyclohexadiene. Remember, D is deuterium, a heavy isotope of hydrogen. It reacts exactly like hydrogen. 4.) In the shown reaction, which will be the kinetic product and which will be the thermodynamic product? H3C CI H3C HCI H3C + 5.) Which of the following molecules is aromatic? (a) (b) (c) H 6.) Which of the following molecules is aromatic? (a) (b) (c) 7.) Write the mechanism for the shown reaction. + Ха AICI 3 CI 8.) Suggest reagents that would convert benzene into the shown compounds. CI NO2 -8-6-6-8-a (a) (b) (c) (d) (e) (a) SO3H Br

The number of 2sp^2 hybridized atoms in is: A. 8; B. 6; C.4; D.2; E.0;

Answer 2

Question

Chapter 4, Problem 4.21YT

(a)

Interpretation Introduction

Interpretation:

The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.

(b)

Interpretation Introduction

Interpretation:

The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.

(c)

Interpretation Introduction

Interpretation:

The line structure (including with dash-wedge notation) for the given Haworth projection of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane. To draw the line structure from its Haworth projection, view the molecule either from the top of the plane or from the bottom of the plane.

(d)

Interpretation Introduction

Interpretation:

The line structure (including with dash-wedge notation) for the given Haworth projection of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane. To draw the line structure from its Haworth projection, view the molecule either from the top of the plane or from the bottom of the plane.

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Answer 3

Question

Chapter 4, Problem 4.21YT

(a)

Interpretation Introduction

Interpretation:

The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.

(b)

Interpretation Introduction

Interpretation:

The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.

(c)

Interpretation Introduction

Interpretation:

The line structure (including with dash-wedge notation) for the given Haworth projection of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane. To draw the line structure from its Haworth projection, view the molecule either from the top of the plane or from the bottom of the plane.

(d)

Interpretation Introduction

Interpretation:

The line structure (including with dash-wedge notation) for the given Haworth projection of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane. To draw the line structure from its Haworth projection, view the molecule either from the top of the plane or from the bottom of the plane.

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Answer 4

Question

Chapter 4, Problem 4.21YT

(a)

Interpretation Introduction

Interpretation:

The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.

(b)

Interpretation Introduction

Interpretation:

The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.

(c)

Interpretation Introduction

Interpretation:

The line structure (including with dash-wedge notation) for the given Haworth projection of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane. To draw the line structure from its Haworth projection, view the molecule either from the top of the plane or from the bottom of the plane.

(d)

Interpretation Introduction

Interpretation:

The line structure (including with dash-wedge notation) for the given Haworth projection of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane. To draw the line structure from its Haworth projection, view the molecule either from the top of the plane or from the bottom of the plane.

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Answer 5

Chapter 4, Problem 4.21YT

(a)

Interpretation Introduction

Interpretation:

The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.

(b)

Interpretation Introduction

Interpretation:

The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.

(c)

Interpretation Introduction

Interpretation:

The line structure (including with dash-wedge notation) for the given Haworth projection of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane. To draw the line structure from its Haworth projection, view the molecule either from the top of the plane or from the bottom of the plane.

(d)

Interpretation Introduction

Interpretation:

The line structure (including with dash-wedge notation) for the given Haworth projection of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane. To draw the line structure from its Haworth projection, view the molecule either from the top of the plane or from the bottom of the plane.

Answer 6

Chapter 4, Problem 4.21YT

(a)

Interpretation Introduction

Interpretation:

The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.

Answer 7

Chapter 4, Problem 4.21YT

(a)

Interpretation Introduction

Interpretation:

The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The Haworth projection (including with dash-wedge notation) for the given line structure of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The line structure (including with dash-wedge notation) for the given Haworth projection of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane. To draw the line structure from its Haworth projection, view the molecule either from the top of the plane or from the bottom of the plane.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The line structure (including with dash-wedge notation) for the given Haworth projection of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane. To draw the line structure from its Haworth projection, view the molecule either from the top of the plane or from the bottom of the plane.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The line structure (including with dash-wedge notation) for the given Haworth projection of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane. To draw the line structure from its Haworth projection, view the molecule either from the top of the plane or from the bottom of the plane.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The line structure (including with dash-wedge notation) for the given Haworth projection of a disubstituted cyclohexane is to be drawn.

Concept introduction:

In the case of disubstituted cyclohexane, the relationship between these two substituents with the ring is explained with the help of a Haworth projection. Since cyclohexane ring undergoes chair flipping with no switching either substituent from their side, the relationship between these substituents on a cyclohexane ring does not change on flipping, that is, the cis substituents remain cis and trans remains trans on flipping. In a Haworth projection, the ring is depicted as being planar, and bonds to substituents are drawn perpendicular to that plane in such way that these substituents come in the plane of the ring, and one side of a ring will be either above this plane or below this plane, depending on the rotation around the plane. To draw the line structure from its Haworth projection, view the molecule either from the top of the plane or from the bottom of the plane.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 4 - Prob. 4.1P Ch. 4 - Prob. 4.2P Ch. 4 - Prob. 4.3P Ch. 4 - Prob. 4.4P Ch. 4 - Prob. 4.5P Ch. 4 - Prob. 4.6P Ch. 4 - Prob. 4.7P Ch. 4 - Prob. 4.8P Ch. 4 - Prob. 4.9P Ch. 4 - Prob. 4.10P

Solution Summary: The author explains the Haworth projection for the given line structure of a disubstituted cyclohexane.

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