Biochemistry, The Molecular Basis of Life, 6th Edition
Biochemistry, The Molecular Basis of Life, 6th Edition
6th Edition
ISBN: 9780190259204
Author: Trudy McKee, James R. McKee
Publisher: Oxford University Press
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Chapter 4, Problem 20RQ
Summary Introduction

To review:

The reason behind ATP (adenosine triphosphate) having an intermediate phosphoryl group transfer potential.

Introduction:

The phosphoryl group transfer potential of a compound can be defined as the measure of the strength of attachment of a group to the molecule. It usually refers to the differences in the standard free energies of the molecule with and without the group. The compounds are categorized as high-energy if they have free energy of more than 25 kJ/mol (kilojoule per mole).

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The two half reactions  for beginning and end of the electron transport chain are given below in standard form. Calculate & for the overall process. Using the Nernst equation (AG° = -n Fo, F= 96.485 kJ/volt mol), calculate AG°. Explain the need for a stepwise process in the electron transport chain. NAD* + H+ + 2 e- = NADH ½ 0г + 2H+ + 2е- = H20 = -0.32v E = +0.82V
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