Basic Chemistry Plus Mastering Chemistry With Pearson Etext -- Access Card Package (6th Edition)
6th Edition
ISBN: 9780134983783
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 3.6, Problem 42PP
Interpretation Introduction
Interpretation: How many Kilocalories are produced in following should be calculated-
- Burning of a cup of popcorn that gives 131 kJ when it is burned in calorimeter
- Burning of a sample of butter which gives 23.4 kJ when it is burned in calorimeter.
Concept Introduction:
- conversion factor used is-
Or,
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 3 Solutions
Basic Chemistry Plus Mastering Chemistry With Pearson Etext -- Access Card Package (6th Edition)
Ch. 3.1 - Classify each of the following pure substances as...Ch. 3.1 - Classify each of the following pure substances as...Ch. 3.1 - Classify each of the following as a pure substance...Ch. 3.1 - Classify each of the following as a pure substance...Ch. 3.1 - A dietitian includes one of the following mixtures...Ch. 3.1 - A dietitian includes one of the following mixtures...Ch. 3.2 - Indicate whether each of the following describes a...Ch. 3.2 - Indicate whether each of the following describes a...Ch. 3.2 - Describe each of the following as a physical or...Ch. 3.2 - Describe each of the following as a physical or...
Ch. 3.2 - Prob. 11PPCh. 3.2 - Prob. 12PPCh. 3.2 - Prob. 13PPCh. 3.2 - Describe each of the following properties for the...Ch. 3.3 - Prob. 15PPCh. 3.3 - Prob. 16PPCh. 3.3 - Prob. 17PPCh. 3.3 - Calculate the unknown temperature in each of the...Ch. 3.3 - Prob. 19PPCh. 3.3 - Prob. 20PPCh. 3.4 - Prob. 21PPCh. 3.4 - Prob. 22PPCh. 3.4 - Prob. 23PPCh. 3.4 - Prob. 24PPCh. 3.4 - Prob. 25PPCh. 3.4 - Prob. 26PPCh. 3.4 - Prob. 27PPCh. 3.4 - Prob. 28PPCh. 3.5 - If the same amount of heat is supplied to samples...Ch. 3.5 - Substances A and B are the same mass and at the...Ch. 3.5 - Calculate the specific heat (J/g °C) for each of...Ch. 3.5 - Calculate the specific heat (J/g °C) for each of...Ch. 3.5 - Use the heat equation to calculate the energy, in...Ch. 3.5 - Use the heat equation to calculate the energy, in...Ch. 3.5 - Calculate the mass, in grams, for each of the...Ch. 3.5 - Prob. 36PPCh. 3.5 - Prob. 37PPCh. 3.5 - Prob. 38PPCh. 3.5 - Prob. 39PPCh. 3.5 - a. A 22.8-g piece of metal at 92.6 °C is dropped...Ch. 3.6 - Prob. 41PPCh. 3.6 - Prob. 42PPCh. 3.6 - Prob. 43PPCh. 3.6 - Prob. 44PPCh. 3.6 - Prob. 45PPCh. 3.6 - Prob. 46PPCh. 3.6 - Prob. 47PPCh. 3.6 - Prob. 48PPCh. 3.6 - When a 1.50-g sample of walnuts is burned in a...Ch. 3.6 - Prob. 50PPCh. 3.6 - Prob. 51PPCh. 3.6 - Prob. 52PPCh. 3 - Prob. 53UTCCh. 3 - Prob. 54UTCCh. 3 - Prob. 55UTCCh. 3 - Classify each of the following as a homogeneous or...Ch. 3 - Prob. 57UTCCh. 3 - Prob. 58UTCCh. 3 - Prob. 59UTCCh. 3 - Prob. 60UTCCh. 3 - Prob. 61UTCCh. 3 - Prob. 62UTCCh. 3 - Prob. 63UTCCh. 3 - Prob. 64UTCCh. 3 - Prob. 65APPCh. 3 - Classify each of the following as an element, a...Ch. 3 - Classify each of the following mixtures as...Ch. 3 - Prob. 68APPCh. 3 - Prob. 69APPCh. 3 - Prob. 70APPCh. 3 - Prob. 71APPCh. 3 - Prob. 72APPCh. 3 - Prob. 73APPCh. 3 - Prob. 74APPCh. 3 - Prob. 75APPCh. 3 - Calculate each of the following temperatures in...Ch. 3 - Prob. 77APPCh. 3 - Prob. 78APPCh. 3 - Prob. 79APPCh. 3 - Prob. 80APPCh. 3 - A 0.50-g sample of vegetable oil is placed in a...Ch. 3 - A 1.3-g sample of rice is placed in a calorimeter....Ch. 3 - A hot-water bottle for a patient contains 725 g of...Ch. 3 - Prob. 84APPCh. 3 - Prob. 85APPCh. 3 - Prob. 86APPCh. 3 - The following problems are related to the topics...Ch. 3 - The following problems are related to the topics...Ch. 3 - The following problems are related to the topics...Ch. 3 - The following problems are related to the topics...Ch. 3 - Prob. 91CPCh. 3 - Prob. 92CPCh. 3 - Gold, one of the most sought-after metals in the...Ch. 3 - Prob. 2CICh. 3 - Prob. 3CICh. 3 - Prob. 4CICh. 3 - In one box of nails weighing 0.250 lb, there are...Ch. 3 - A hot tub is filled with 450 gal of water. (2.5,...
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