Basic Chemistry Plus Mastering Chemistry With Pearson Etext -- Access Card Package (6th Edition)
6th Edition
ISBN: 9780134983783
Author: Karen C. Timberlake
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Question
Chapter 3.3, Problem 15PP
Interpretation Introduction
Interpretation: The temperature of body should be calculated in Celsius unit.
Concept Introduction:
- Equation used to convert the temperature from Fahrenheit to Celsius units:
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 3 Solutions
Basic Chemistry Plus Mastering Chemistry With Pearson Etext -- Access Card Package (6th Edition)
Ch. 3.1 - Classify each of the following pure substances as...Ch. 3.1 - Classify each of the following pure substances as...Ch. 3.1 - Classify each of the following as a pure substance...Ch. 3.1 - Classify each of the following as a pure substance...Ch. 3.1 - A dietitian includes one of the following mixtures...Ch. 3.1 - A dietitian includes one of the following mixtures...Ch. 3.2 - Indicate whether each of the following describes a...Ch. 3.2 - Indicate whether each of the following describes a...Ch. 3.2 - Describe each of the following as a physical or...Ch. 3.2 - Describe each of the following as a physical or...
Ch. 3.2 - Prob. 11PPCh. 3.2 - Prob. 12PPCh. 3.2 - Prob. 13PPCh. 3.2 - Describe each of the following properties for the...Ch. 3.3 - Prob. 15PPCh. 3.3 - Prob. 16PPCh. 3.3 - Prob. 17PPCh. 3.3 - Calculate the unknown temperature in each of the...Ch. 3.3 - Prob. 19PPCh. 3.3 - Prob. 20PPCh. 3.4 - Prob. 21PPCh. 3.4 - Prob. 22PPCh. 3.4 - Prob. 23PPCh. 3.4 - Prob. 24PPCh. 3.4 - Prob. 25PPCh. 3.4 - Prob. 26PPCh. 3.4 - Prob. 27PPCh. 3.4 - Prob. 28PPCh. 3.5 - If the same amount of heat is supplied to samples...Ch. 3.5 - Substances A and B are the same mass and at the...Ch. 3.5 - Calculate the specific heat (J/g °C) for each of...Ch. 3.5 - Calculate the specific heat (J/g °C) for each of...Ch. 3.5 - Use the heat equation to calculate the energy, in...Ch. 3.5 - Use the heat equation to calculate the energy, in...Ch. 3.5 - Calculate the mass, in grams, for each of the...Ch. 3.5 - Prob. 36PPCh. 3.5 - Prob. 37PPCh. 3.5 - Prob. 38PPCh. 3.5 - Prob. 39PPCh. 3.5 - a. A 22.8-g piece of metal at 92.6 °C is dropped...Ch. 3.6 - Prob. 41PPCh. 3.6 - Prob. 42PPCh. 3.6 - Prob. 43PPCh. 3.6 - Prob. 44PPCh. 3.6 - Prob. 45PPCh. 3.6 - Prob. 46PPCh. 3.6 - Prob. 47PPCh. 3.6 - Prob. 48PPCh. 3.6 - When a 1.50-g sample of walnuts is burned in a...Ch. 3.6 - Prob. 50PPCh. 3.6 - Prob. 51PPCh. 3.6 - Prob. 52PPCh. 3 - Prob. 53UTCCh. 3 - Prob. 54UTCCh. 3 - Prob. 55UTCCh. 3 - Classify each of the following as a homogeneous or...Ch. 3 - Prob. 57UTCCh. 3 - Prob. 58UTCCh. 3 - Prob. 59UTCCh. 3 - Prob. 60UTCCh. 3 - Prob. 61UTCCh. 3 - Prob. 62UTCCh. 3 - Prob. 63UTCCh. 3 - Prob. 64UTCCh. 3 - Prob. 65APPCh. 3 - Classify each of the following as an element, a...Ch. 3 - Classify each of the following mixtures as...Ch. 3 - Prob. 68APPCh. 3 - Prob. 69APPCh. 3 - Prob. 70APPCh. 3 - Prob. 71APPCh. 3 - Prob. 72APPCh. 3 - Prob. 73APPCh. 3 - Prob. 74APPCh. 3 - Prob. 75APPCh. 3 - Calculate each of the following temperatures in...Ch. 3 - Prob. 77APPCh. 3 - Prob. 78APPCh. 3 - Prob. 79APPCh. 3 - Prob. 80APPCh. 3 - A 0.50-g sample of vegetable oil is placed in a...Ch. 3 - A 1.3-g sample of rice is placed in a calorimeter....Ch. 3 - A hot-water bottle for a patient contains 725 g of...Ch. 3 - Prob. 84APPCh. 3 - Prob. 85APPCh. 3 - Prob. 86APPCh. 3 - The following problems are related to the topics...Ch. 3 - The following problems are related to the topics...Ch. 3 - The following problems are related to the topics...Ch. 3 - The following problems are related to the topics...Ch. 3 - Prob. 91CPCh. 3 - Prob. 92CPCh. 3 - Gold, one of the most sought-after metals in the...Ch. 3 - Prob. 2CICh. 3 - Prob. 3CICh. 3 - Prob. 4CICh. 3 - In one box of nails weighing 0.250 lb, there are...Ch. 3 - A hot tub is filled with 450 gal of water. (2.5,...
Knowledge Booster
Similar questions
- elow are experimentally determined van Deemter plots of column efficiency, H, vs. flow rate. H is a quantitative measurement of band broadening. The left plot is for a liquid chromatography application and the night is for gas chromatography. Compare and contrast these two plots in terms of the three band broadening mechanisms presented in this activity. How are they similar? How do they differ? Justify your answers.? 0.4 H (mm) 0.2 0.1- 0.3- 0 0.5 H (mm) 8.0 7.0 6.0 5.0 4.0- 3.0 T +++ 1.0 1.5 0 2.0 4.0 Flow Rate, u (cm/s) 6.0 8.0 Flow Rate, u (cm/s)arrow_forwardPredict the products of this organic reaction: + H ZH NaBH3CN H+ n. ? Click and drag to start drawing a structure. Xarrow_forwardWhat is the missing reactant R in this organic reaction? + R H3O+ + • Draw the structure of R in the drawing area below. • Be sure to use wedge and dash bonds if it's necessary to draw one particular enantiomer. Click and drag to start drawing a structure.arrow_forward
- What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1 1. PPh3 2. n-BuLi 2 • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure.arrow_forwardThe product on the right-hand side of this reaction can be prepared from two organic reactants, under the conditions shown above and below the arrow. Draw 1 and 2 below, in any arrangement you like. 1+2 NaBH₂CN H+ N Click and drag to start drawing a structure. X $arrow_forwardExplain what is the maximum absorbance of in which caffeine absorbs?arrow_forward
- Explain reasons as to why the amount of caffeine extracted from both a singular extraction (5ml Mountain Dew) and a multiple extraction (2 x 5.0ml Mountain Dew) were severely high when compared to coca-cola?arrow_forwardProtecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑arrow_forwardDraw the complete mechanism for the acid-catalyzed hydration of this alkene. esc 田 Explanation Check 1 888 Q A slock Add/Remove step Q F4 F5 F6 A བྲA F7 $ % 5 @ 4 2 3 & 6 87 Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Ce W E R T Y U S D LL G H IK DD 요 F8 F9 F10 F1 * ( 8 9 0 O P J K L Z X C V B N M H He commandarrow_forward
- Explanation Check F1 H₂O H₂ Pd 1) MCPBA 2) H3O+ 1) Hg(OAc)2, H₂O 2) NaBH4 OH CI OH OH OH hydration halohydrin formation addition halogenation hydrogenation inhalation hydrogenation hydration ☐ halohydrin formation addition halogenation formation chelation hydrogenation halohydrin formation substitution hydration halogenation addition Ohalohydrin formation subtraction halogenation addition hydrogenation hydration F2 80 F3 σ F4 F5 F6 1 ! 2 # 3 $ 4 % 05 Q W & Å © 2025 McGraw Hill LLC. All Rights Reserved. F7 F8 ( 6 7 8 9 LU E R T Y U A F9arrow_forwardShow the mechanism steps to obtain the lowerenergy intermediate: *see imagearrow_forwardSoap is made by the previous reaction *see image. The main difference between one soap and another soap isthe length (number of carbons) of the carboxylic acid. However, if a soap irritates your skin, they mostlikely used too much lye.Detergents have the same chemical structure as soaps except for the functional group. Detergentshave sulfate (R-SO4H) and phosphate (R-PO4H2) functional groups. Draw the above carboxylic acidcarbon chain but as the two variants of detergents. *see imagearrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning