Basic Chemistry (5th Edition)
Basic Chemistry (5th Edition)
5th Edition
ISBN: 9780134138046
Author: Karen C. Timberlake
Publisher: PEARSON
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Chapter 3.5, Problem 3.36QAP
Interpretation Introduction

(a)

Interpretation:

The mass of water that absorbs 8250 J of heat to raise its temperature from 18.4C0 to 92.6C0 should be calculated.

Concept Introduction:

  • Specific heat is the amount of heat in joules required to raise the temperature of 1 gram of a substance by 1C0 . It is expressed in terms of J/gC0
  • The amount of heat absorbed or evolved as the temperature changes from T1 to T2 is given as:

  Q = mcΔT = mc(T2-T1) -----(1)m = mass of the substancec = specific heat

Interpretation Introduction

(b)

Interpretation:

The mass of silver that loses 3.22 kJ of heat to lower its temperature from 145C0 to 24C0 should be calculated.

Concept Introduction:

  • Specific heat is the amount of heat in joules required to raise the temperature of 1 gram of a substance by 1C0 . It is expressed in terms of J/gC0
  • The amount of heat absorbed or evolved as the temperature changes from T1 to T2 is given as:

  Q = mcΔT = mc(T2-T1) -----(1)m = mass of the substancec = specific heat

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(a) Verify that the lattice energies of the alkali metal iodides are inversely proportional to the distances between the ions in MI (M = alkali metal) by plotting the lattice energies given below against the internuclear distances dMI. Is the correlation good? Would a better fit be obtained by plotting the lattice energies as a function of (1 — d*/d)/d, as theoretically suggested, with d* = 34.5 pm? You must use a standard graphing program to plot the graph. It generates an equation for the line and calculates a correlation coefficient. (b) From the graph obtained in (a), estimate the lattice energy of silver iodide. (c) Compare the results of (b) with the experimental value of 886 kJ/mol. If they do not agree, explain the deviation.
Can I please get help with #3 & 4? Thanks you so much!
A solution consisting of 0.200 mol methylbenzene, C,H,CH,, in 500. g of nitrobenzene, CH,NO₂, freezes at 3.2°C. Pure nitrobenzene freezes at 6.0°C. The molal freezing point constant of nitrobenzene is _ °C/m. a) 2.8 b) 3.2 c) 5.6 d) 7.0 e) 14.0

Chapter 3 Solutions

Basic Chemistry (5th Edition)

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