An Introduction to Thermal Physics
An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Chapter 3.4, Problem 31P

Experimental measurements of heat capacities are often represented in reference works as empirical formulas. For graphite, a formula that works well over a fairly wide range of temperatures is (for one mole) C p = a + b T c T 2 , where a = 16.86 J / K , b = 4.77 × 10 3 J / K 2 , and c = 8.54 × 10 5 J K . Suppose, then, that a mole of graphite is heated at constant pressure from 298 K to 500 K. Calculate the increase in its entropy during this process. Add on the tabulated value of S ( 298 K ) (from the back of this book) to obtain S ( 500 K ) .

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