ORGANIC CHEMISTRY-OWL V2 ACCESS
ORGANIC CHEMISTRY-OWL V2 ACCESS
8th Edition
ISBN: 9781305582422
Author: Brown
Publisher: CENGAGE L
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Chapter 3.3, Problem 3.3P

(a)

Interpretation Introduction

Interpretation:

The configuration for the given moleculehas to be assigned.

Concept Introduction:

Priority rules:

  • Priorities based on atomic number

-H,-CH3,-NH2,-OH,-SH,-Cl,-Br,-IIncreasingpriority

  • When priority cannot be assigned on the basis of the atoms bonded directly to the chiral center

-CH2H,-CH2CH3,-CH2NH2,-CH2OH,-CH2ClIncreasingpriority

  • Atoms participating in a double or triple bond are considered to be bonded to an equivalent number of phantom atoms.

For example,

ORGANIC CHEMISTRY-OWL V2 ACCESS, Chapter 3.3, Problem 3.3P , additional homework tip  1

  • Priority assignment is made at the first point of difference between groups (should not be based on the larger group).

(b)

Interpretation Introduction

Interpretation:

The configuration for the given molecule has to be assigned.

Concept Introduction:

Priority rules:

  • Priorities based on atomic number

-H,-CH3,-NH2,-OH,-SH,-Cl,-Br,-IIncreasingpriority

  • When priority cannot be assigned on the basis of the atoms bonded directly to the chiral center

-CH2H,-CH2CH3,-CH2NH2,-CH2OH,-CH2ClIncreasingpriority

  • Atoms participating in a double or triple bond are considered to be bonded to an equivalent number of phantom atoms.

For example,

ORGANIC CHEMISTRY-OWL V2 ACCESS, Chapter 3.3, Problem 3.3P , additional homework tip  2

  • Priority assignment is made at the first point of difference between groups (should not be based on the larger group).

(c)

Interpretation Introduction

Interpretation:

The configuration for the given molecule has to be assigned.

Concept Introduction:

Priority rules:

  • Priorities based on atomic number

-H,-CH3,-NH2,-OH,-SH,-Cl,-Br,-IIncreasingpriority

  • When priority cannot be assigned on the basis of the atoms bonded directly to the chiral center

-CH2H,-CH2CH3,-CH2NH2,-CH2OH,-CH2ClIncreasingpriority

  • Atoms participating in a double or triple bond are considered to be bonded to an equivalent number of phantom atoms.

For example,

ORGANIC CHEMISTRY-OWL V2 ACCESS, Chapter 3.3, Problem 3.3P , additional homework tip  3

  • Priority assignment is made at the first point of difference between groups (should not be based on the larger group).

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f) The unusual molecule [2.2.2] propellane is pictured. 1) Given the bond length and bond angles in the image, what hybridization scheme best describes the carbons marked by the askerisks? 2) What types of orbitals are used in the bond between the two carbons marked by the askerisks? 3) How does this bond compare to an ordinary carbon-carbon bond (which is usually 1.54 Å long)? CH2 1.60Å H₂C * H₂C CH2 C H2C * C Of H₂ 120°
e) Determine the hybridization and geometry around the indicated carbon atoms. H3C CH3 B HC CH2 A C C C CH3
Don't used Ai solution and hand raiting

Chapter 3 Solutions

ORGANIC CHEMISTRY-OWL V2 ACCESS

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