Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
6th Edition
ISBN: 9781305080461
Author: John C. Gilbert, Stephen F. Martin
Publisher: Brooks Cole
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Chapter 3.3, Problem 17E
Interpretation Introduction

Interpretation:Whether two compounds with same Rf and produce one spot are same or not should be determined.

Concept introduction:Retention factor or Rf refers to distance that is travelled by liquid to reach top of chromatographic plate. All compounds have particular value of Rf for specific solvent. This value is used for comparison of unknown samples with known compounds.

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Draw the stepwise mechanism (with arrow pushing)
a) Explain why product 1 is the kinetic product and product 2 is the thermodynamic product. b) Draw the reaction coordinate diagram for the reaction pathway generating each product. c) State the Arrhenius Equation and explain the terms with their physical significance. d) State and explain which reaction pathway has a higher rate constant. What happens to the rate constant if the temperature has increased?
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