(a) Interpretation: The number of moles of platinum in the cone should be calculated. Concept introduction: The number of moles of a substance is related to molar mass of the substance as follows: n = m M Here, m is mass and M is molar mass. In 1 mol of a substance there are 6.023 × 10 23 units of that substance. Also, density of a substance is related to mass and volume as follows: d = m V Here, m is mass and V is volume of the substance.
(a) Interpretation: The number of moles of platinum in the cone should be calculated. Concept introduction: The number of moles of a substance is related to molar mass of the substance as follows: n = m M Here, m is mass and M is molar mass. In 1 mol of a substance there are 6.023 × 10 23 units of that substance. Also, density of a substance is related to mass and volume as follows: d = m V Here, m is mass and V is volume of the substance.
Definition Definition Number of atoms/molecules present in one mole of any substance. Avogadro's number is a constant. Its value is 6.02214076 × 10 23 per mole.
Chapter 3, Problem 6QAP
Interpretation Introduction
(a)
Interpretation:
The number of moles of platinum in the cone should be calculated.
Concept introduction:
The number of moles of a substance is related to molar mass of the substance as follows:
n=mM
Here, m is mass and M is molar mass.
In 1 mol of a substance there are 6.023×1023 units of that substance.
Also, density of a substance is related to mass and volume as follows:
d=mV
Here, m is mass and V is volume of the substance.
Interpretation Introduction
(b)
Interpretation:
The number of electrons in there in the cone should be calculated.
Concept introduction:
The number of moles of a substance is related to molar mass of the substance as follows:
n=mM
Here, m is mass and M is molar mass.
According to Avogadro’s law, in 1 mol of a substance there are 6.023×1023 units of that substance.
Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.
(c)
(4pts)
Mechanism:
heat
(E1)
CH3OH
+
1.5pts each
_E1 _ (1pt)
Br
CH3OH
(d)
(4pts)
Mechanism:
SN1
(1pt)
(e)
(3pts)
1111 I
H
10
Ill!!
H
LDA
THF (solvent)
Mechanism: E2
(1pt)
NC
(f)
Bri!!!!!
CH3
NaCN
(3pts)
acetone
Mechanism: SN2
(1pt)
(SN1)
-OCH3
OCH3
1.5pts each
2pts for either product
1pt if incorrect
stereochemistry
H
Br
(g)
“,、
(3pts)
H
CH3OH
+21
Mechanism:
SN2
(1pt)
H
CH3
2pts
1pt if incorrect
stereochemistry
H
2pts
1pt if incorrect
stereochemistry
A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixture