EBK CHEMISTRY: PRINCIPLES AND REACTIONS
8th Edition
ISBN: 9780100547964
Author: Hurley
Publisher: YUZU
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Textbook Question
Chapter 3, Problem 21QAP
You are asked to prepare a 0.8500 M solution of aluminum nitrate. You find that you have only 50.00 g of the solid.
(a) What is the maximum volume of solution that you can prepare?
(b) How many milliliters of this prepared solution are required to furnish 0.5000 mol of aluminum nitrate to a reaction?
(c) If 2.500 L of the prepared solution are required, how much more aluminum nitrate would you need?
(d) Fifty milliliters of a 0.450 M solution of aluminum nitrate are needed. How would you prepare the required solution from the solution prepared in (a)?
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(a)
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2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
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Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
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Chapter 3 Solutions
EBK CHEMISTRY: PRINCIPLES AND REACTIONS
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