GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
4th Edition
ISBN: 9781265982959
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 3, Problem 53P
What is the charge on the cation M in each of the following ionic compounds?
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Part II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization
of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm").
Determine the following:
(a) molecular Formula and Degree of unsaturation of compound Brian
(b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts
(ii) integration, ciii) multiplicity and (iv) interferences made for each signal
(c) Draw the structure of compound Brian.
)
ΕΙ
43
41
27
71
114 (M+)
Hmmm
20
30
40
50 60
70
80
90 100 110 120
1H NMR spectrum
300 MHz in CDCl3
2.0
alle
1.0
The iron-iron carbide phase diagram.
In the diagram, the letter L indicates that it
is a liquid. Indicate what its components
are.
Temperature (°C)
1600
10
Composition (at% C)
15
25
1538°C
-1493°C
8
1400
1200
1394°C
y+L
L
2500
1147°C
y. Austenite
2.14
4.30
2000
1000
912°C
y + Fe3C
800ㅏ
0.76
0.022
600
a, Ferrite
a + Fe3C
400
0
(Fe)
Composition (wt% C)
727°C
1500
Cementite (Fe3C)
1000
6
6.70
Temperature (°F)
Part V. Choose which isomer would give the 1H-NMR spectrum below. Justify your reasoning by assigning important signals to the
Corresponding protons of the correct molecule.
A
D
on of of of
H
H
88
2
90
7.8
7.6
7.4
80
5
6 [ppm]
7.2
6.8
6.6
6.4
ō [ppm]
Chapter 3 Solutions
GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
Ch. 3.1 - Predict whether the bonds in the following species...Ch. 3.1 - (a) Classify each example of molecular art as a...Ch. 3.1 - Label each of the following as a compound,...Ch. 3.1 - Vitamin C has the chemical formula C6H8O6. Even if...Ch. 3.2 - Prob. 3.3PPCh. 3.2 - Write the ion symbol for an atom with the given...Ch. 3.2 - How many protons and electrons are present in each...Ch. 3.2 - Prob. 3.3PCh. 3.2 - Prob. 3.6PPCh. 3.2 - Prob. 3.4P
Ch. 3.2 - How many electrons and protons are contained in...Ch. 3.2 - Prob. 3.6PCh. 3.2 - Mn2+ is an essential nutrient needed for blood...Ch. 3.3 - Prob. 3.7PPCh. 3.3 - Prob. 3.8PPCh. 3.3 - Prob. 3.8PCh. 3.4 - Prob. 3.9PCh. 3.4 - Prob. 3.10PCh. 3.4 - Prob. 3.9PPCh. 3.4 - Prob. 3.10PPCh. 3.4 - Prob. 3.11PCh. 3.4 - Prob. 3.12PCh. 3.4 - Prob. 3.11PPCh. 3.5 - List four physical properties of ionic compounds.Ch. 3.6 - Prob. 3.12PPCh. 3.6 - Prob. 3.14PCh. 3.6 - Prob. 3.15PCh. 3.6 - Prob. 3.13PPCh. 3.6 - Using the charges on the ions that compose...Ch. 3 - Which formulas represent ionic compounds and which...Ch. 3 - Which formulas represent ionic compound and which...Ch. 3 - Which pairs of elements are likely to form ionic...Ch. 3 - Which pairs of elements are likely to form ionic...Ch. 3 - Prob. 21PCh. 3 - Prob. 22PCh. 3 - Write the ion symbol for an atom with the given...Ch. 3 - How many protons and electrons are present in each...Ch. 3 - Prob. 25PCh. 3 - Prob. 26PCh. 3 - What species fits each description? a period 2...Ch. 3 - What species fits each description? a period 3...Ch. 3 - Give the ion symbol for each ion. sodium ion...Ch. 3 - Give the ion symbol for each ion. barium ion iron...Ch. 3 - What noble gas has the same electronic...Ch. 3 - Prob. 32PCh. 3 - Prob. 33PCh. 3 - How many electrons must be gained or lost by each...Ch. 3 - For each of the general electron-dot formulas for...Ch. 3 - Label each of the following elements or regions in...Ch. 3 - Prob. 37PCh. 3 - Prob. 38PCh. 3 - Prob. 39PCh. 3 - Prob. 40PCh. 3 - Prob. 41PCh. 3 - Prob. 42PCh. 3 - How many protons and electrons are contained in...Ch. 3 - How many protons and electrons are contained in...Ch. 3 - Identify the polyatomic anion (including its...Ch. 3 - Prob. 46PCh. 3 - Prob. 47PCh. 3 - Prob. 48PCh. 3 - Prob. 49PCh. 3 - Prob. 50PCh. 3 - Prob. 51PCh. 3 - Prob. 52PCh. 3 - What is the charge on the cation M in each of the...Ch. 3 - What is the charge on the anion Z in each of the...Ch. 3 - Prob. 55PCh. 3 - Prob. 56PCh. 3 - Write the formula for the ionic compound formed...Ch. 3 - Prob. 58PCh. 3 - Write the formula for the ionic compound formed...Ch. 3 - Write the formula for the ionic compound formed...Ch. 3 - Prob. 61PCh. 3 - Prob. 62PCh. 3 - Prob. 63PCh. 3 - Prob. 64PCh. 3 - Prob. 65PCh. 3 - Prob. 66PCh. 3 - Prob. 67PCh. 3 - Prob. 68PCh. 3 - Liquid nutritional shakes that contain protein,...Ch. 3 - Prob. 70PCh. 3 - Prob. 71PCh. 3 - Prob. 72PCh. 3 - Prob. 73PCh. 3 - Prob. 74PCh. 3 - Prob. 75PCh. 3 - Prob. 76PCh. 3 - Prob. 77PCh. 3 - Prob. 78PCh. 3 - Prob. 79PCh. 3 - Prob. 80PCh. 3 - Prob. 81PCh. 3 - Prob. 82PCh. 3 - Prob. 83PCh. 3 - Prob. 84PCh. 3 - Prob. 85PCh. 3 - Prob. 86PCh. 3 - Energy bars contain ionic compounds that serve as...Ch. 3 - Prob. 88CP
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