Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337399425
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Textbook Question
Chapter 3, Problem 4QAP
has a definite volume hut takes the shape of its container.
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Part I.
a) Elucidate
the structure of compound A using the following information.
• mass spectrum: m+ = 102, m/2=57
312=29
• IR spectrum:
1002.5
% TRANSMITTANCE
Ngg
50
40
30
20
90
80
70
60
MICRONS
5
8
9 10
12
13
14 15 16
19
1740 cm
M
10
0
4000
3600
3200
2800
2400
2000
1800
1600
13
• CNMR
'H
-NMR
Peak
8
ppm (H)
Integration
multiplicity
a
1.5 (3H)
triplet
b
1.3
1.5 (3H)
triplet
C
2.3
1 (2H)
quartet
d
4.1
1 (2H)
quartet
& ppm (c)
10
15
28
60
177 (C=0)
b) Elucidate the structure of compound B using the following information
13C/DEPT NMR 150.9 MHz
IIL
1400
WAVENUMBERS (CM-1)
DEPT-90
DEPT-135
85 80 75
70
65
60
55
50
45 40
35
30 25 20
ppm
1200
1000
800
600
400
•
Part II.
a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below:
• IR spectra
% TRANSMITTANCE
1002.5
90
80
70
60
50
40
30
20
10
0
4000
3600
3200
2800
2400
2000
1800
1600
• Information from 'HAMR
MICRONS
8 9 10
11
14 15 16
19
25
1400
WAVENUMBERS (CM-1)
1200
1000
800
600
400
peak
8 ppm
Integration
multiplicity
a
2.1
1.5 (3H)
Singlet
b
3.6
1 (2H)
singlet
с
3.8
1.5 (3H)
Singlet
d
6.8
1(2H)
doublet
7.1
1(2H)
doublet
Information from 13C-nmR
Normal carbon
29ppm
Dept 135
Dept -90
+
NO peak
NO peak
50 ppm
55 ppm
+
NO peak
114 ppm
t
126 ppm
No peak
NO peak
130 ppm
t
+
159 ppm
No peak
NO peak
207 ppm
по реак
NO peak
Could you redraw these and also explain how to solve them for me pleas
Chapter 3 Solutions
Introductory Chemistry: A Foundation
Ch. 3.2 - Exercise 3.1 Which of the following are physical...Ch. 3.2 - Prob. 3.2SCCh. 3.4 - Exercise 3.3 Classify each of the following as a...Ch. 3.5 - The scanning tunneling microscope allows us to...Ch. 3 - When water boils, you can see bubbles rising to...Ch. 3 - If you place a glass rod over a burning candle,...Ch. 3 - The boiling of water is a physical change because...Ch. 3 - Is there a difference between a homogeneous...Ch. 3 - Sketch a magnified view (showing atoms and/or...Ch. 3 - Are all physical changes accompanied by chemical...
Ch. 3 - Why would a chemist find fault with the phrase...Ch. 3 - Are separations of mixtures physical or chemical...Ch. 3 - Explain the termselement, afoul, and compound....Ch. 3 - Mixtures can be classified as either homogeneous...Ch. 3 - Prob. 11ALQCh. 3 - Look at Table 2.8 in your text. How do the...Ch. 3 - Label of the following as an atomic element, a...Ch. 3 - Match each description below with the following...Ch. 3 - Prob. 1QAPCh. 3 - What is the chief factor that determines...Ch. 3 - Of the three stales of matter, and are not very...Ch. 3 - has a definite volume hut takes the shape of its...Ch. 3 - Compare and contrast the ease with which molecules...Ch. 3 - Matter in the __________ state has no shape and...Ch. 3 - What similarities are there between the solid and...Ch. 3 - A sample of matter that is “rigid” has...Ch. 3 - Consider three 10-g samples of water: one as ice,...Ch. 3 - ¡n a sample of a gaseous substance, more than 99%...Ch. 3 - Elemental bromine is a dense, dark-red,...Ch. 3 - Is the process represented below a physical or...Ch. 3 - From the information given above, indicate...Ch. 3 - Prob. 14QAPCh. 3 - You want to cook some raw noodles to make a pasta...Ch. 3 - Which of the following is/are examples of a...Ch. 3 - Classify each of the following as a physical or...Ch. 3 - Classify each of the following as aphysical or...Ch. 3 - Prob. 19QAPCh. 3 - What is acompound? What are compounds composed of?...Ch. 3 - Certain elements have special affinities for other...Ch. 3 - _________ can he broken down into the component...Ch. 3 - The composition of a given pure compound is always...Ch. 3 - Which of the following are considered compounds...Ch. 3 - If iron filings are placed with excess powdered...Ch. 3 - If the combination of iron filings and sulfur in...Ch. 3 - Prob. 27QAPCh. 3 - Which of the following substances is(are)...Ch. 3 - Classify the following asmixturesorpure...Ch. 3 - Classify the following asmixturesorpure...Ch. 3 - Classify the following mixtures...Ch. 3 - Read the “Chemistry in Focus” segmentConcrete—An...Ch. 3 - Prob. 33QAPCh. 3 - Describe how the process offiltrationcould be used...Ch. 3 - In a common laboratory experiment in general...Ch. 3 - During a filtration or distillation experiment, we...Ch. 3 - Prob. 37APCh. 3 - Classify each of the following as a(n) element,...Ch. 3 - 1f a piece of hard, white blackboard chalk is...Ch. 3 - During a very cold winter, the temperature may...Ch. 3 - Prob. 41APCh. 3 - True or false? Salad dressing (such as oil and...Ch. 3 - Prob. 43APCh. 3 - Which of (he following are true? P4 is considered...Ch. 3 - (For Exercises 4546) Solutions containing...Ch. 3 - (For Exercises 4546) Solutions containing...Ch. 3 - The processes of melting and evaporation involve...Ch. 3 - A(n) always has the same composition.Ch. 3 - Classify each of the following as...Ch. 3 - Which of the following contains an element, a...Ch. 3 - Classify the following mixtures...Ch. 3 - Which of the following best describes the air...Ch. 3 - Give three examples each ofheterogeneousmixtures...Ch. 3 - True or false? Mixtures always result in a...Ch. 3 - Choose an element or compound with which you are...Ch. 3 - Prob. 56APCh. 3 - Give an example of each of the following: a...Ch. 3 - Prob. 58APCh. 3 - Sketch the apparatus commonly used for simple...Ch. 3 - Prob. 60APCh. 3 - Which of the following best describes the...Ch. 3 - Prob. 62CPCh. 3 - Which of the following describes a chemical...Ch. 3 - Prob. 64CPCh. 3 - Prob. 1CRCh. 3 - Prob. 2CRCh. 3 - You have learned the basic way in which scientists...Ch. 3 - Many college students would not choose to take a...Ch. 3 - Prob. 5CRCh. 3 - Prob. 6CRCh. 3 - Prob. 7CRCh. 3 - Prob. 8CRCh. 3 - Prob. 9CRCh. 3 - What ismatter? What is matter composed of? What...Ch. 3 - Prob. 11CRCh. 3 - Prob. 12CRCh. 3 - Prob. 13CRCh. 3 - Prob. 14CRCh. 3 - Prob. 15CRCh. 3 - Prob. 16CRCh. 3 - Prob. 17CRCh. 3 - a. Given that 1100. mL of ethyl alcohol weighs...Ch. 3 - Which of the following represent physical...
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- In the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forwardNonearrow_forwardNonearrow_forward
- Nonearrow_forwardWhat spectral features allow you to differentiate the product from the starting material? Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.arrow_forwardQuestion 6 What is the major product of the following Diels-Alder reaction? ? Aldy by day of A. H о B. C. D. E. OB OD Oc OE OAarrow_forward
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