Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337399425
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 3, Problem 19QAP
Interpretation Introduction
Interpretation:
The given sentence should be completed.
Concept Introduction:
Two or more elements combine to form a compound. Covalent bonds exist in a covalent compound. Ionic bond exists in an ionic compound.
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For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 →> NO₂+ NO3_(K1)
NO2 + NO3 → N2O5 (k-1)
NO2 + NO3 →
→
NO2 + O2 + NO (K2)
NO + N2O5-
NO2 + NO2 + NO2 (K3)
d[N₂O5] __2k‚k₂[N2O5]
Indicate whether the following rate expression is acceptable:
dt
k₁₁+ k₂
Consider the following decomposition reaction of N2O5(g):
For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 → NO2 + NO3 (K1)
NO2 + NO3 → N2O5 (k-1)
NO2 + NO3 → NO2 + O2 + NO (K2)
NO + N2O5 → NO2 + NO2 + NO2 (K3)
Indicate whether the following rate expression is acceptable:
d[N2O5]
= -k₁[N₂O₂] + K¸₁[NO₂][NO3] - K¸[NO₂]³
dt
In a reaction of A + B to give C, another compound other than A, B or C may appear in the kinetic equation.
Chapter 3 Solutions
Introductory Chemistry: A Foundation
Ch. 3.2 - Exercise 3.1 Which of the following are physical...Ch. 3.2 - Prob. 3.2SCCh. 3.4 - Exercise 3.3 Classify each of the following as a...Ch. 3.5 - The scanning tunneling microscope allows us to...Ch. 3 - When water boils, you can see bubbles rising to...Ch. 3 - If you place a glass rod over a burning candle,...Ch. 3 - The boiling of water is a physical change because...Ch. 3 - Is there a difference between a homogeneous...Ch. 3 - Sketch a magnified view (showing atoms and/or...Ch. 3 - Are all physical changes accompanied by chemical...
Ch. 3 - Why would a chemist find fault with the phrase...Ch. 3 - Are separations of mixtures physical or chemical...Ch. 3 - Explain the termselement, afoul, and compound....Ch. 3 - Mixtures can be classified as either homogeneous...Ch. 3 - Prob. 11ALQCh. 3 - Look at Table 2.8 in your text. How do the...Ch. 3 - Label of the following as an atomic element, a...Ch. 3 - Match each description below with the following...Ch. 3 - Prob. 1QAPCh. 3 - What is the chief factor that determines...Ch. 3 - Of the three stales of matter, and are not very...Ch. 3 - has a definite volume hut takes the shape of its...Ch. 3 - Compare and contrast the ease with which molecules...Ch. 3 - Matter in the __________ state has no shape and...Ch. 3 - What similarities are there between the solid and...Ch. 3 - A sample of matter that is “rigid” has...Ch. 3 - Consider three 10-g samples of water: one as ice,...Ch. 3 - ¡n a sample of a gaseous substance, more than 99%...Ch. 3 - Elemental bromine is a dense, dark-red,...Ch. 3 - Is the process represented below a physical or...Ch. 3 - From the information given above, indicate...Ch. 3 - Prob. 14QAPCh. 3 - You want to cook some raw noodles to make a pasta...Ch. 3 - Which of the following is/are examples of a...Ch. 3 - Classify each of the following as a physical or...Ch. 3 - Classify each of the following as aphysical or...Ch. 3 - Prob. 19QAPCh. 3 - What is acompound? What are compounds composed of?...Ch. 3 - Certain elements have special affinities for other...Ch. 3 - _________ can he broken down into the component...Ch. 3 - The composition of a given pure compound is always...Ch. 3 - Which of the following are considered compounds...Ch. 3 - If iron filings are placed with excess powdered...Ch. 3 - If the combination of iron filings and sulfur in...Ch. 3 - Prob. 27QAPCh. 3 - Which of the following substances is(are)...Ch. 3 - Classify the following asmixturesorpure...Ch. 3 - Classify the following asmixturesorpure...Ch. 3 - Classify the following mixtures...Ch. 3 - Read the “Chemistry in Focus” segmentConcrete—An...Ch. 3 - Prob. 33QAPCh. 3 - Describe how the process offiltrationcould be used...Ch. 3 - In a common laboratory experiment in general...Ch. 3 - During a filtration or distillation experiment, we...Ch. 3 - Prob. 37APCh. 3 - Classify each of the following as a(n) element,...Ch. 3 - 1f a piece of hard, white blackboard chalk is...Ch. 3 - During a very cold winter, the temperature may...Ch. 3 - Prob. 41APCh. 3 - True or false? Salad dressing (such as oil and...Ch. 3 - Prob. 43APCh. 3 - Which of (he following are true? P4 is considered...Ch. 3 - (For Exercises 4546) Solutions containing...Ch. 3 - (For Exercises 4546) Solutions containing...Ch. 3 - The processes of melting and evaporation involve...Ch. 3 - A(n) always has the same composition.Ch. 3 - Classify each of the following as...Ch. 3 - Which of the following contains an element, a...Ch. 3 - Classify the following mixtures...Ch. 3 - Which of the following best describes the air...Ch. 3 - Give three examples each ofheterogeneousmixtures...Ch. 3 - True or false? Mixtures always result in a...Ch. 3 - Choose an element or compound with which you are...Ch. 3 - Prob. 56APCh. 3 - Give an example of each of the following: a...Ch. 3 - Prob. 58APCh. 3 - Sketch the apparatus commonly used for simple...Ch. 3 - Prob. 60APCh. 3 - Which of the following best describes the...Ch. 3 - Prob. 62CPCh. 3 - Which of the following describes a chemical...Ch. 3 - Prob. 64CPCh. 3 - Prob. 1CRCh. 3 - Prob. 2CRCh. 3 - You have learned the basic way in which scientists...Ch. 3 - Many college students would not choose to take a...Ch. 3 - Prob. 5CRCh. 3 - Prob. 6CRCh. 3 - Prob. 7CRCh. 3 - Prob. 8CRCh. 3 - Prob. 9CRCh. 3 - What ismatter? What is matter composed of? What...Ch. 3 - Prob. 11CRCh. 3 - Prob. 12CRCh. 3 - Prob. 13CRCh. 3 - Prob. 14CRCh. 3 - Prob. 15CRCh. 3 - Prob. 16CRCh. 3 - Prob. 17CRCh. 3 - a. Given that 1100. mL of ethyl alcohol weighs...Ch. 3 - Which of the following represent physical...
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Similar questions
- For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forwardGiven the reaction R + Q → P, indicate the rate law with respect to R, with respect to P and with respect to P.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forward
- k₁ Given the reaction A B, indicate k-1 d[A] (A). the rate law with respect to A: (B). the rate law with respect to B: d[B] dt dtarrow_forwardk₁ Given the reaction R₂ R + R, indicate k-1 (A). the rate law with respect to R2: (B). the rate law with respect to R: d[R₂] dt d[R] dtarrow_forwardGiven the reaction R+ Q → P, indicate (A). the rate law with respect to P: (B). the rate law with respect to R: (C). the rate law with respect to Q: d[P] dt d[R] dt d[Q] dtarrow_forward
- The reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism: 1) NO + NO ⇄ N2O2 (fast); 2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.arrow_forwarda. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)? b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forward
- a. The first three lines of this procedure describe the reaction used to make compound 5b. In the fourth line, hexane and sodium bicarbonate are added. What organic lab technique is being used here? b. What is the purpose of the Na2SO4? c. What equipment would you use to “concentrate [a solution] under reduced pressure”?arrow_forwardWhen N,N-dimethylaniline is treated with bromine both the ortho and para products are observed. However when treated with a mixture of nitric acid and sulfuric acid only the meta product is observed. Explain these results and support your answer with the appropriate drawings *Hint amines are bases* N HNO3 H2SO4 N NO2 N Br2 N Br + N 8-8-8 FeBr3 Brarrow_forwardDraw a mechanism that explains the formation of compound OMe SO3H 1. Fuming H2SO4arrow_forward
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