
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 3, Problem 46P
Interpretation Introduction
Interpretation:
The
Concept introduction:
For a molecule to have a dipole moment, it must have at least one polar bond.
The molecules which have more than one polar bond, the individual bond dipoles may reinforce or cancel partly or wholly depending on their orientations.
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reducing a monosaccharide
a non reducing disaccharide
amylopectin
cellulose
1,4' beta- glycoside
Refer to the monosaccharides below to answer each of the following questions:
CH2OH
CHO
CH₂OH
CHZOH
0
H
OH
0
0
HO
H
H
OH
HO
H
HO
H
H
OH
HO
H
CHZOH
H
OH
HO
H
HO
H
CHZOH
CHZOH
CH3
a Sorbose
b. Rhamnose
c. Erythrulose
d. Xylulose
Classify each sugar by type; for example, glucose is an aldohexose.
A. Xylulose is
B. Erythrulose is
C. Sorbose is
D.
Rhamnose is
Refer to the sugars below to answer the following questions. Choose the sugar that best fits each
escription and place the letter of the sugar in the blank to the left of the description. There is only one
orrect answer for each question, but sugars may be used more than once.
CH₂OH
0
CHO
HO
H
CHO
CH₂OH
HO
H
HO
H
HO
H
H
OH
HH
OH
OH
H
OH
H
OH
HO
H
CH₂OH
H
OH
CH₂OH
CH₂OH
CH₂OH
a (-)-tagatose
b. (+) gulose
c. (-)-erythrose
d (-)-n bulos
A.
ARCD
a D-ketohexose
B.
C.
D.
oxidizes to an optically inactive aldaric acid
a dextrorotary hexose
a ketose with two chirality centers
Chapter 3 Solutions
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
Ch. 3.1 - Identify the alkanes corresponding to each of the...Ch. 3.1 - Find the conformations in Figure 3.4 in which the...Ch. 3.2 - Sketch a potential energy diagram for rotation...Ch. 3.2 - Acetylcholine is a neurotransmitter in the central...Ch. 3.2 - Prob. 5PCh. 3.5 - The heats of combustion of ethylcyclopropane and...Ch. 3.8 - Prob. 7PCh. 3.10 - The following questions relate to a cyclohexane...Ch. 3.10 - Draw the most stable conformation of...Ch. 3.11 - Prob. 10P
Ch. 3.11 - Prob. 11PCh. 3.12 - Based on what you know about disubstituted...Ch. 3.12 - Write structural formulas for the most stable...Ch. 3.14 - Cubane (C4H8) is the common name of the polycyclic...Ch. 3.14 - Prob. 15PCh. 3.14 - Prob. 16PCh. 3.14 - Prob. 17PCh. 3.14 - Prob. 18PCh. 3.15 - Prob. 19PCh. 3 - Give the IUPAC names of each of the following: (a)...Ch. 3 - Draw Newman projections for the gauche and...Ch. 3 - Identify all atoms that are (a) anti and (b)...Ch. 3 - Prob. 23PCh. 3 - Prob. 24PCh. 3 - Prob. 25PCh. 3 - Prob. 26PCh. 3 - Prob. 27PCh. 3 - Prob. 28PCh. 3 - Oxidation of 4-tert-butylthiane proceeds according...Ch. 3 - The following are representations of two forms of...Ch. 3 - Draw (a) a Newman projection of the most stable...Ch. 3 - Write a structural formula for the most stable...Ch. 3 - Sight down the C-2-C-3 bond, and draw Newman...Ch. 3 - Prob. 34PCh. 3 - Sketch an approximate potential energy diagram for...Ch. 3 - Prob. 36PCh. 3 - Even though the methyl group occupies an...Ch. 3 - Which do you expect to be the more stable...Ch. 3 - Arrange the trimethylcyclohexane isomers shown in...Ch. 3 - Identify the more stable stereoisomer in each of...Ch. 3 - One stereoisomer of 1,1,3,5-tetramethylcyclohexane...Ch. 3 - One of the following two stereoisomers is...Ch. 3 - In each of the following groups of compounds,...Ch. 3 - The heats of combustion of the more and less...Ch. 3 - The measured dipole moment of ClCH2CH2Cl is 1.12D....Ch. 3 - Prob. 46PCh. 3 - Prob. 47PCh. 3 - Prob. 48DSPCh. 3 - Prob. 49DSPCh. 3 - Prob. 50DSPCh. 3 - Prob. 51DSPCh. 3 - Prob. 52DSPCh. 3 - Prob. 53DSP
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