ORGANIC CHEMISTRY
6th Edition
ISBN: 9781260826791
Author: SMITH
Publisher: MCG
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Chapter 3, Problem 43P
Rank the compounds in each group in order of increasing boiling point.
a. 
b. 
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"Water gas" is an industrial fuel composed of a mixture of carbon monoxide and hydrogen gases. When this
fuel is burned, carbon dioxide and water result. From the information given below, write a balanced equation
and determine the enthalpy of this reaction:
CO(g) + O2(g) → CO₂(g) + 282.8 kJ
H2(g) + O2(g) → H₂O(g) + 241.8 kJ
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4. Calculate AG for the following reaction at 25°C. Will the reaction occur (be spontaneous)? How do you
know?
NH3(g) + HCl(g) → NH4Cl(s)
AH=-176.0 kJ
AS-284.8 J-K-1
Chapter 3 Solutions
ORGANIC CHEMISTRY
Ch. 3.1 - Prob. 1PCh. 3.2 - (a) Classify the carbon atoms in each compound as...Ch. 3.2 - Problem 3.3 Classify a carbon atom by the number...Ch. 3.2 - Classify each alkyl halide and alcohol as , or...Ch. 3.2 - Prob. 5PCh. 3.2 - Prob. 6PCh. 3.2 - Draw the structure of a compound of molecular...Ch. 3.2 - Prob. 8PCh. 3.2 - Prob. 9PCh. 3.2 - Draw the structure of a compound fitting each...
Ch. 3.4 - Predict which compound in each pair has the higher...Ch. 3.4 - Prob. 17PCh. 3.4 - a Label the hydrophobic and hydrophilic portions...Ch. 3.5 - Prob. 21PCh. 3 - 3.29
Identify the functional groups in the...Ch. 3 - Prob. 32PCh. 3 - 3.31 For each alkane: (a) classify each carbon...Ch. 3 - 3.32 Identify the functional groups in each...Ch. 3 - 3.33 Identify each functional group located in the...Ch. 3 - 3.34 (a)Identify the functional groups in...Ch. 3 - Draw seven constitutional isomers with molecular...Ch. 3 - Prob. 38PCh. 3 - Prob. 39PCh. 3 - Prob. 40PCh. 3 - Intramolecular force of attraction are often...Ch. 3 - 3.40 (a) Draw four compounds with molecular...Ch. 3 - 3.41 Rank the compounds in each group in order of...Ch. 3 - Explain why CH3CH2NHCH3 has higher boiling point...Ch. 3 - Prob. 45PCh. 3 - 3.44 Rank the following compounds in order of...Ch. 3 - Prob. 47PCh. 3 - 3.50 Predict the solubility of each of the...Ch. 3 - Prob. 52PCh. 3 - Prob. 53PCh. 3 - 3.53 THC is the active component in marijuana, and...Ch. 3 - Prob. 55PCh. 3 - Prob. 56PCh. 3 - 3.60 Quinapril (trade name Accupril) is a drug...Ch. 3 - 3.61 Answer each question about oxycodone, a...Ch. 3 - Prob. 65PCh. 3 - Prob. 66PCh. 3 - 3.64 Explain why A is less water soluble than B,...Ch. 3 - 3.65 Recall from section 1.10B that there is...
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- true or false The equilibrium constant for this reaction is 0.20. N2O4(g) ⇔ 2NO2(g) Based on the above, the equilibrium constant for the following reaction is 5. 4NO2(g) ⇔ 2N2O4(g)arrow_forwardtrue or false The equilibrium constant for this reaction is 0.20. N2O4(g) ⇔ 2NO2(g) Based on the above, the equilibrium constant for the following reaction is 0.4. 2N2O4(g) ⇔ 4NO2(g)arrow_forwardtrue or false Using the following equilibrium, if heat is added the equilibrium will shift toward the reactants. N2(g) + 3H2(g) ⇔ 2NH3(g) + heatarrow_forward
- True or False Using the following equilibrium, if heat is added the equilibrium will shift toward the products. N2O4(g) + heat ⇔ 2NO2(g)arrow_forwardtrue or false Using the following equilibrium, if solid carbon is added the equilibrium will shift toward the products. C(s) + CO2(g) ⇔ 2CO(g)arrow_forwardProvide the complete mechanism for the reaction below. You must include appropriate arrows,intermediates, and formal charges. Please also provide a reason to explain why the 1,4-adduct is preferred over the 1,3-adduct.arrow_forward
- Which of the following pairs are resonance structures of one another? I. III. || III IV + II. :0: n P !༠ IV. EN: Narrow_forwardPredict the major organic product(s) and byproducts (either organic or inorganic) for thefollowing reactions.arrow_forwardA 8.25 g sample of aluminum at 55°C released 2500 J of heat. The specific heat of aluminum is 0.900 J/g°C. The density of aluminum is 2.70 g/mL. Calculate the final temperature of the aluminum sample in °C.arrow_forward
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