(a) Interpretation: The given compounds in each group are to be ranked in the order of increasing strength of intermolecular forces. Concept introduction: Intermolecular forces are also known as non-covalent interactions. The interactions present between molecules are known as intermolecular forces. A functional group present in a molecule decides the type of interaction. The increasing order of intermolecular force strength is as follows: Van der Waals < Dipole − Dipole < Hydrogen bonding

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Answer 1

Question

Chapter 3, Problem 39P

Interpretation Introduction

(a)

Interpretation: The given compounds in each group are to be ranked in the order of increasing strength of intermolecular forces.

Concept introduction: Intermolecular forces are also known as non-covalent interactions. The interactions present between molecules are known as intermolecular forces. A functional group present in a molecule decides the type of interaction. The increasing order of intermolecular force strength is as follows:

Van der Waals<Dipole−Dipole<Hydrogen bonding

Interpretation Introduction

(b)

Interpretation: The given compounds in each group are to be ranked in the order of increasing strength of intermolecular forces.

Concept introduction: Intermolecular forces are also known as non-covalent interactions. The interactions present between molecules are known as intermolecular forces. A functional group present in a molecule decides the type of interaction. The increasing order of intermolecular force strength is as follows:

Van der Waals<Dipole−Dipole<Hydrogen bonding

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter 3, Problem 39P

Interpretation Introduction

(a)

Interpretation: The given compounds in each group are to be ranked in the order of increasing strength of intermolecular forces.

Concept introduction: Intermolecular forces are also known as non-covalent interactions. The interactions present between molecules are known as intermolecular forces. A functional group present in a molecule decides the type of interaction. The increasing order of intermolecular force strength is as follows:

Van der Waals<Dipole−Dipole<Hydrogen bonding

Interpretation Introduction

(b)

Interpretation: The given compounds in each group are to be ranked in the order of increasing strength of intermolecular forces.

Concept introduction: Intermolecular forces are also known as non-covalent interactions. The interactions present between molecules are known as intermolecular forces. A functional group present in a molecule decides the type of interaction. The increasing order of intermolecular force strength is as follows:

Van der Waals<Dipole−Dipole<Hydrogen bonding

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Answer 3

Question

Chapter 3, Problem 39P

Interpretation Introduction

(a)

Interpretation: The given compounds in each group are to be ranked in the order of increasing strength of intermolecular forces.

Concept introduction: Intermolecular forces are also known as non-covalent interactions. The interactions present between molecules are known as intermolecular forces. A functional group present in a molecule decides the type of interaction. The increasing order of intermolecular force strength is as follows:

Van der Waals<Dipole−Dipole<Hydrogen bonding

Interpretation Introduction

(b)

Interpretation: The given compounds in each group are to be ranked in the order of increasing strength of intermolecular forces.

Concept introduction: Intermolecular forces are also known as non-covalent interactions. The interactions present between molecules are known as intermolecular forces. A functional group present in a molecule decides the type of interaction. The increasing order of intermolecular force strength is as follows:

Van der Waals<Dipole−Dipole<Hydrogen bonding

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Answer 4

Question

Chapter 3, Problem 39P

Interpretation Introduction

(a)

Interpretation: The given compounds in each group are to be ranked in the order of increasing strength of intermolecular forces.

Concept introduction: Intermolecular forces are also known as non-covalent interactions. The interactions present between molecules are known as intermolecular forces. A functional group present in a molecule decides the type of interaction. The increasing order of intermolecular force strength is as follows:

Van der Waals<Dipole−Dipole<Hydrogen bonding

Interpretation Introduction

(b)

Interpretation: The given compounds in each group are to be ranked in the order of increasing strength of intermolecular forces.

Concept introduction: Intermolecular forces are also known as non-covalent interactions. The interactions present between molecules are known as intermolecular forces. A functional group present in a molecule decides the type of interaction. The increasing order of intermolecular force strength is as follows:

Van der Waals<Dipole−Dipole<Hydrogen bonding

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Answer 5

Chapter 3, Problem 39P

Interpretation Introduction

(a)

Interpretation: The given compounds in each group are to be ranked in the order of increasing strength of intermolecular forces.

Concept introduction: Intermolecular forces are also known as non-covalent interactions. The interactions present between molecules are known as intermolecular forces. A functional group present in a molecule decides the type of interaction. The increasing order of intermolecular force strength is as follows:

Van der Waals<Dipole−Dipole<Hydrogen bonding

Interpretation Introduction

(b)

Interpretation: The given compounds in each group are to be ranked in the order of increasing strength of intermolecular forces.

Concept introduction: Intermolecular forces are also known as non-covalent interactions. The interactions present between molecules are known as intermolecular forces. A functional group present in a molecule decides the type of interaction. The increasing order of intermolecular force strength is as follows:

Van der Waals<Dipole−Dipole<Hydrogen bonding

Answer 6

Chapter 3, Problem 39P

Interpretation Introduction

(a)

Interpretation: The given compounds in each group are to be ranked in the order of increasing strength of intermolecular forces.

Concept introduction: Intermolecular forces are also known as non-covalent interactions. The interactions present between molecules are known as intermolecular forces. A functional group present in a molecule decides the type of interaction. The increasing order of intermolecular force strength is as follows:

Van der Waals<Dipole−Dipole<Hydrogen bonding

Answer 7

Chapter 3, Problem 39P

Interpretation Introduction

(a)

Interpretation: The given compounds in each group are to be ranked in the order of increasing strength of intermolecular forces.

Concept introduction: Intermolecular forces are also known as non-covalent interactions. The interactions present between molecules are known as intermolecular forces. A functional group present in a molecule decides the type of interaction. The increasing order of intermolecular force strength is as follows:

Van der Waals<Dipole−Dipole<Hydrogen bonding

Answer 8

Interpretation Introduction

(b)

Interpretation: The given compounds in each group are to be ranked in the order of increasing strength of intermolecular forces.

Concept introduction: Intermolecular forces are also known as non-covalent interactions. The interactions present between molecules are known as intermolecular forces. A functional group present in a molecule decides the type of interaction. The increasing order of intermolecular force strength is as follows:

Van der Waals<Dipole−Dipole<Hydrogen bonding

Answer 9

Interpretation Introduction

(b)

Interpretation: The given compounds in each group are to be ranked in the order of increasing strength of intermolecular forces.

Concept introduction: Intermolecular forces are also known as non-covalent interactions. The interactions present between molecules are known as intermolecular forces. A functional group present in a molecule decides the type of interaction. The increasing order of intermolecular force strength is as follows:

Van der Waals<Dipole−Dipole<Hydrogen bonding

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 3.1 - Prob. 1P Ch. 3.2 - (a) Classify the carbon atoms in each compound as...Ch. 3.2 - Problem 3.3 Classify a carbon atom by the number...Ch. 3.2 - Classify each alkyl halide and alcohol as , or...Ch. 3.2 - Prob. 5P Ch. 3.2 - Prob. 6P Ch. 3.2 - Draw the structure of a compound of molecular...Ch. 3.2 - Prob. 8P Ch. 3.2 - Prob. 9P Ch. 3.2 - Draw the structure of a compound fitting each...

Solution Summary: The author explains that the increasing order of intermolecular force strength for the given compounds is shown in Figure 2.

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