ACHIEVE/CHEMICAL PRINCIPLES ACCESS 2TERM
ACHIEVE/CHEMICAL PRINCIPLES ACCESS 2TERM
7th Edition
ISBN: 9781319403959
Author: ATKINS
Publisher: MAC HIGHER
Question
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Chapter 3, Problem 3E.10E

(a)

Interpretation Introduction

Interpretation:

Pressure exerted by 1.00 mol C2H6 when it behaves as ideal gas has to be determined.

Concept Introduction:

The expression for ideal gas equation for one mole of gas is as follows:

  PV=RT        (1)

Here,

P is pressure of gas.

V is molar volume of gas.

T is absolute temperature of gas.

R is universal gas constant.

(a)

Expert Solution
Check Mark

Explanation of Solution

Rearrange equation (1) to calculate P.

  P=RTV        (2)

(i) Substitute 1.121 L for V, 273.15 K for T, and 8.3145×102 LbarK1mol1 for R in equation (2).

  P=(8.3145×102 LbarK1mol1)(273.15 K)1.121 L=20.26 bar

(ii) Substitute 40.0 L for V, 1.00×103 K for T, and 8.3145×102 LbarK1mol1 for R in equation (2).

  P=(8.3145×102 LbarK1mol1)(1.00×103 K)40.0 L=2.08 bar

Pressure exerted by 1.00 mol C2H6 in case (i) and (ii) by ideal gas is 20.26 bar and 2.08 bar.

(b)

Interpretation Introduction

Interpretation:

Pressure exerted by 1.00 mol C2H6 when it behaves as van der Waals gas has to be determined.

Concept Introduction:

The formula to calculate pressure of one mole of gas is as follows:

  P=RT(Vb)aV2        (3)

Here,

P is pressure of gas.

V is volume of gas.

T is absolute temperature of gas.

R is universal gas constant.

a and b are van der Waals parameters.

(b)

Expert Solution
Check Mark

Explanation of Solution

(i) Substitute 1.121 L for V 273.15 K for T, 8.3145×102 LbarK1mol1 for R, 5.507 barL2mol2 for a and 6.51×102 Lmol1 for b in equation (3).

  P=((8.3145×102 LbarK1mol1)(273.15 K)(1.121 L6.51×102 Lmol1))(5.507 barL2mol2(1.121 L)2)=17.12 bar

(ii) Substitute 40.0 L for V 273.15 K for T, 8.3145×102 LbarK1mol1 for R, 5.507 barL2mol2 for a and 6.51×102 Lmol1 for b in equation (3).

  P=((8.3145×102 LbarK1mol1)(1.00×103 K)(40.0 L6.51×102 Lmol1))(5.507 barL2mol2(40.0 L)2)=2.08 bar

Pressure exerted by 1.00 mol C2H6 in case (i) and (ii) by van der Waals gas is 17.12 bar and 2.08 bar.

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Chapter 3 Solutions

ACHIEVE/CHEMICAL PRINCIPLES ACCESS 2TERM

Ch. 3 - Prob. 3A.5ECh. 3 - Prob. 3A.6ECh. 3 - Prob. 3A.7ECh. 3 - Prob. 3A.8ECh. 3 - Prob. 3A.9ECh. 3 - Prob. 3A.10ECh. 3 - Prob. 3B.1ASTCh. 3 - Prob. 3B.1BSTCh. 3 - Prob. 3B.2ASTCh. 3 - Prob. 3B.2BSTCh. 3 - Prob. 3B.3ASTCh. 3 - Prob. 3B.3BSTCh. 3 - Prob. 3B.4ASTCh. 3 - Prob. 3B.4BSTCh. 3 - Prob. 3B.5ASTCh. 3 - Prob. 3B.5BSTCh. 3 - Prob. 3B.6ASTCh. 3 - Prob. 3B.6BSTCh. 3 - Prob. 3B.7ASTCh. 3 - Prob. 3B.7BSTCh. 3 - Prob. 3B.8ASTCh. 3 - Prob. 3B.8BSTCh. 3 - Prob. 3B.1ECh. 3 - Prob. 3B.2ECh. 3 - Prob. 3B.5ECh. 3 - Prob. 3B.6ECh. 3 - Prob. 3B.9ECh. 3 - Prob. 3B.10ECh. 3 - Prob. 3B.11ECh. 3 - Prob. 3B.12ECh. 3 - Prob. 3B.13ECh. 3 - Prob. 3B.14ECh. 3 - Prob. 3B.15ECh. 3 - Prob. 3B.16ECh. 3 - Prob. 3B.17ECh. 3 - Prob. 3B.18ECh. 3 - Prob. 3B.19ECh. 3 - Prob. 3B.20ECh. 3 - Prob. 3B.21ECh. 3 - Prob. 3B.22ECh. 3 - Prob. 3B.23ECh. 3 - Prob. 3B.24ECh. 3 - Prob. 3B.25ECh. 3 - Prob. 3B.26ECh. 3 - Prob. 3B.27ECh. 3 - Prob. 3B.28ECh. 3 - Prob. 3B.29ECh. 3 - Prob. 3B.30ECh. 3 - Prob. 3B.31ECh. 3 - Prob. 3B.32ECh. 3 - Prob. 3B.33ECh. 3 - Prob. 3B.34ECh. 3 - Prob. 3B.35ECh. 3 - Prob. 3B.36ECh. 3 - Prob. 3B.37ECh. 3 - Prob. 3B.38ECh. 3 - Prob. 3B.39ECh. 3 - Prob. 3B.40ECh. 3 - Prob. 3B.41ECh. 3 - Prob. 3B.42ECh. 3 - Prob. 3C.1ASTCh. 3 - Prob. 3C.1BSTCh. 3 - Prob. 3C.2ASTCh. 3 - Prob. 3C.2BSTCh. 3 - Prob. 3C.3ASTCh. 3 - Prob. 3C.3BSTCh. 3 - Prob. 3C.1ECh. 3 - Prob. 3C.2ECh. 3 - Prob. 3C.3ECh. 3 - Prob. 3C.4ECh. 3 - Prob. 3C.5ECh. 3 - Prob. 3C.6ECh. 3 - Prob. 3C.7ECh. 3 - Prob. 3C.8ECh. 3 - Prob. 3C.9ECh. 3 - Prob. 3C.10ECh. 3 - Prob. 3C.11ECh. 3 - Prob. 3C.12ECh. 3 - Prob. 3C.13ECh. 3 - Prob. 3C.14ECh. 3 - Prob. 3C.15ECh. 3 - Prob. 3C.16ECh. 3 - Prob. 3D.1ASTCh. 3 - Prob. 3D.1BSTCh. 3 - Prob. 3D.2ASTCh. 3 - Prob. 3D.2BSTCh. 3 - Prob. 3D.1ECh. 3 - Prob. 3D.2ECh. 3 - Prob. 3D.3ECh. 3 - Prob. 3D.4ECh. 3 - Prob. 3D.5ECh. 3 - Prob. 3D.6ECh. 3 - Prob. 3D.7ECh. 3 - Prob. 3D.8ECh. 3 - Prob. 3D.9ECh. 3 - Prob. 3D.10ECh. 3 - Prob. 3D.11ECh. 3 - Prob. 3D.12ECh. 3 - Prob. 3D.13ECh. 3 - Prob. 3D.14ECh. 3 - Prob. 3D.15ECh. 3 - Prob. 3D.16ECh. 3 - Prob. 3D.17ECh. 3 - Prob. 3D.18ECh. 3 - Prob. 3E.1ASTCh. 3 - Prob. 3E.1BSTCh. 3 - Prob. 3E.1ECh. 3 - Prob. 3E.2ECh. 3 - Prob. 3E.3ECh. 3 - Prob. 3E.4ECh. 3 - Prob. 3E.5ECh. 3 - Prob. 3E.6ECh. 3 - Prob. 3E.7ECh. 3 - Prob. 3E.8ECh. 3 - Prob. 3E.9ECh. 3 - Prob. 3E.10ECh. 3 - Prob. 3E.13ECh. 3 - Prob. 3E.14ECh. 3 - Prob. 3F.1ASTCh. 3 - Prob. 3F.1BSTCh. 3 - Prob. 3F.2ASTCh. 3 - Prob. 3F.2BSTCh. 3 - Prob. 3F.3ASTCh. 3 - Prob. 3F.3BSTCh. 3 - Prob. 3F.1ECh. 3 - Prob. 3F.2ECh. 3 - Prob. 3F.3ECh. 3 - Prob. 3F.4ECh. 3 - Prob. 3F.5ECh. 3 - Prob. 3F.6ECh. 3 - Prob. 3F.7ECh. 3 - Prob. 3F.8ECh. 3 - Prob. 3F.9ECh. 3 - Prob. 3F.10ECh. 3 - Prob. 3F.11ECh. 3 - Prob. 3F.12ECh. 3 - Prob. 3F.13ECh. 3 - Prob. 3F.14ECh. 3 - Prob. 3F.15ECh. 3 - Prob. 3F.16ECh. 3 - Prob. 3F.17ECh. 3 - Prob. 3F.18ECh. 3 - Prob. 3F.19ECh. 3 - Prob. 3F.20ECh. 3 - Prob. 3F.21ECh. 3 - Prob. 3F.22ECh. 3 - Prob. 3G.1ECh. 3 - Prob. 3G.2ECh. 3 - Prob. 3G.3ECh. 3 - Prob. 3G.4ECh. 3 - Prob. 3G.5ECh. 3 - Prob. 3G.6ECh. 3 - Prob. 3G.7ECh. 3 - Prob. 3G.8ECh. 3 - Prob. 3G.9ECh. 3 - Prob. 3G.10ECh. 3 - Prob. 3G.11ECh. 3 - Prob. 3G.12ECh. 3 - Prob. 3G.13ECh. 3 - Prob. 3G.14ECh. 3 - Prob. 3G.15ECh. 3 - Prob. 3G.16ECh. 3 - Prob. 3G.17ECh. 3 - Prob. 3G.18ECh. 3 - Prob. 3H.1ASTCh. 3 - Prob. 3H.1BSTCh. 3 - Prob. 3H.2ASTCh. 3 - Prob. 3H.2BSTCh. 3 - Prob. 3H.3ASTCh. 3 - Prob. 3H.3BSTCh. 3 - Prob. 3H.4ASTCh. 3 - Prob. 3H.4BSTCh. 3 - Prob. 3H.5ASTCh. 3 - Prob. 3H.5BSTCh. 3 - Prob. 3H.1ECh. 3 - Prob. 3H.2ECh. 3 - Prob. 3H.3ECh. 3 - Prob. 3H.4ECh. 3 - Prob. 3H.5ECh. 3 - Prob. 3H.6ECh. 3 - Prob. 3H.7ECh. 3 - Prob. 3H.8ECh. 3 - Prob. 3H.9ECh. 3 - Prob. 3H.10ECh. 3 - Prob. 3H.11ECh. 3 - Prob. 3H.12ECh. 3 - Prob. 3H.13ECh. 3 - Prob. 3H.14ECh. 3 - Prob. 3H.15ECh. 3 - Prob. 3H.16ECh. 3 - Prob. 3H.17ECh. 3 - Prob. 3H.19ECh. 3 - Prob. 3H.20ECh. 3 - Prob. 3H.23ECh. 3 - Prob. 3H.24ECh. 3 - Prob. 3H.25ECh. 3 - Prob. 3H.26ECh. 3 - Prob. 3H.27ECh. 3 - Prob. 3H.28ECh. 3 - Prob. 3H.29ECh. 3 - Prob. 3H.30ECh. 3 - Prob. 3H.31ECh. 3 - Prob. 3H.32ECh. 3 - Prob. 3H.33ECh. 3 - Prob. 3H.34ECh. 3 - Prob. 3H.35ECh. 3 - Prob. 3H.36ECh. 3 - Prob. 3I.1ASTCh. 3 - Prob. 3I.1BSTCh. 3 - Prob. 3I.2ASTCh. 3 - Prob. 3I.2BSTCh. 3 - Prob. 3I.3ASTCh. 3 - Prob. 3I.3BSTCh. 3 - Prob. 3I.4ASTCh. 3 - Prob. 3I.4BSTCh. 3 - Prob. 3I.1ECh. 3 - Prob. 3I.2ECh. 3 - Prob. 3I.3ECh. 3 - Prob. 3I.4ECh. 3 - Prob. 3I.5ECh. 3 - Prob. 3I.6ECh. 3 - Prob. 3I.7ECh. 3 - Prob. 3I.8ECh. 3 - Prob. 3I.11ECh. 3 - Prob. 3I.12ECh. 3 - Prob. 3I.13ECh. 3 - Prob. 3I.14ECh. 3 - Prob. 3I.15ECh. 3 - Prob. 3I.16ECh. 3 - Prob. 3J.1ASTCh. 3 - Prob. 3J.1BSTCh. 3 - Prob. 3J.2ASTCh. 3 - Prob. 3J.2BSTCh. 3 - Prob. 3J.3ASTCh. 3 - Prob. 3J.3BSTCh. 3 - Prob. 3J.1ECh. 3 - Prob. 3J.2ECh. 3 - Prob. 3J.3ECh. 3 - Prob. 3J.4ECh. 3 - Prob. 3J.5ECh. 3 - Prob. 3J.6ECh. 3 - Prob. 3J.7ECh. 3 - Prob. 3J.8ECh. 3 - Prob. 3J.9ECh. 3 - Prob. 3J.10ECh. 3 - Prob. 3J.11ECh. 3 - Prob. 3J.12ECh. 3 - Prob. 3J.13ECh. 3 - Prob. 3J.14ECh. 3 - Prob. 3J.15ECh. 3 - Prob. 3J.16ECh. 3 - Prob. 3.1ECh. 3 - Prob. 3.2ECh. 3 - Prob. 3.3ECh. 3 - Prob. 3.4ECh. 3 - Prob. 3.5ECh. 3 - Prob. 3.6ECh. 3 - Prob. 3.7ECh. 3 - Prob. 3.8ECh. 3 - Prob. 3.9ECh. 3 - Prob. 3.10ECh. 3 - Prob. 3.11ECh. 3 - Prob. 3.12ECh. 3 - Prob. 3.13ECh. 3 - Prob. 3.15ECh. 3 - Prob. 3.18ECh. 3 - Prob. 3.19ECh. 3 - Prob. 3.23ECh. 3 - Prob. 3.24ECh. 3 - Prob. 3.25ECh. 3 - Prob. 3.26ECh. 3 - Prob. 3.27ECh. 3 - Prob. 3.29ECh. 3 - Prob. 3.31ECh. 3 - Prob. 3.32ECh. 3 - Prob. 3.35ECh. 3 - Prob. 3.36ECh. 3 - Prob. 3.37ECh. 3 - Prob. 3.38ECh. 3 - Prob. 3.40ECh. 3 - Prob. 3.41ECh. 3 - Prob. 3.42ECh. 3 - Prob. 3.45ECh. 3 - Prob. 3.47ECh. 3 - Prob. 3.49ECh. 3 - Prob. 3.50ECh. 3 - Prob. 3.51ECh. 3 - Prob. 3.53ECh. 3 - Prob. 3.54ECh. 3 - Prob. 3.55ECh. 3 - Prob. 3.56ECh. 3 - Prob. 3.57ECh. 3 - Prob. 3.58ECh. 3 - Prob. 3.59ECh. 3 - Prob. 3.60ECh. 3 - Prob. 3.61ECh. 3 - Prob. 3.62ECh. 3 - Prob. 3.63ECh. 3 - Prob. 3.64ECh. 3 - Prob. 3.65ECh. 3 - Prob. 3.66ECh. 3 - Prob. 3.67ECh. 3 - Prob. 3.68E
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