Quantitative Chemical Analysis 9e And Sapling Advanced Single Course For Analytical Chemistry (access Card)
Quantitative Chemical Analysis 9e And Sapling Advanced Single Course For Analytical Chemistry (access Card)
9th Edition
ISBN: 9781319090241
Author: Daniel C. Harris, Sapling Learning
Publisher: W. H. Freeman
Question
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Chapter 3, Problem 3.BE

(a)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be written

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3 , the uncertainty (e4) in addition and subtraction can be calculated as follows,

e4=e12+e22+e32

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Write: The absolute and percent relative uncertainty with a reasonable number of significant figures

(a)

Expert Solution
Check Mark

Answer to Problem 3.BE

The absolute and percent relative uncertainty with a reasonable number of significant figures is 2.1±0.2  and 2.1±0.8% respectively.

Explanation of Solution

Given data:

[12.41(±0.09)÷4.16(±0.01)]×7.0682(±0.0004)=?

Calculation of absolute and percent relative uncertainty:

For multiplication and division, convert absolute uncertainty to percent relative uncertainty.

For 12.41(±0.09) , percent relative uncertainty is (±0.09/12.4)×100=±0.725%

For 4.16(±0.01) , percent relative uncertainty is (±0.01/4.16)×100=±0.240%

For 7.0682(±0.0004) , percent relative uncertainty is (±0.0004/7.0682)×100=±0.0057%

The uncertainty (e) is calculated as follows,

uncertainty =0.7252+0.00572+0.2402      =0.764% =0.8% (rounded to correct significant figure)

Substitute all the values in the given problem.

[12.41(±0.09)÷4.16(±0.01)]×7.0682(±0.0004)=12.41(±0.725%)×7.0682(±0.0057%)4.16(±0.240%)=21.086(±0.764%)Since 0.7252+0.00572+0.2402=0.764%

Convert relative uncertainty into absolute uncertainty as follows,

Absolute uncertainty =0.00764×21.086 =0.16 =0.2(rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 2.1±0.2

The percent relative uncertainty is 2.1±0.8%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is written as 2.1±0.2 and 2.1±0.8% respectively.

(b)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be written

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3 , the uncertainty (e4) in addition and subtraction can be calculated as follows,

e4=e12+e22+e32

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Write: The absolute and percent relative uncertainty with a reasonable number of significant figures

(b)

Expert Solution
Check Mark

Answer to Problem 3.BE

The absolute and percent relative uncertainty with a reasonable number of significant figures is 27.4(±0.9) and 27.4(±3.2%) respectively.

Explanation of Solution

Given data:

[3.26(±0.10)×8.47(±0.05)]0.18(±0.06)=?

Calculation of absolute and percent relative uncertainty:

First solve the terms in bracket.

For multiplication and division, convert absolute uncertainty to percent relative uncertainty.

For 3.26(±0.10) , percent relative uncertainty is (±0.10/3.26)×100=±3.07%

For 8.47(±0.05) , percent relative uncertainty is (±0.05/8.47)×100=±0.59%

The uncertainty (e) is calculated as follows,

uncertainty =3.072+0.592      =±3.12%

Substitute all the values in the given problem.

[3.26(±0.10)×8.47(±0.05)]0.18(±0.06)=[3.26(±3.07%)×8.47(±0.59%)]0.18(±0.06)=[27.612(±3.12%)]0.18(±0.06) (Since 3.072+0.592=3.12%)=[27.612(±0.863)]0.18(±0.06) [Since (3.12/100)×27.612=0.863]=27.4(±0.86)=27.4(±0.9)(rounded to correct significant figures)

Therefore, the absolute uncertainty is 27.4(±0.9)

The percent relative uncertainty is calculated as follows,

Percent Relative uncertainty  =0.86327.43×100 =3.2%

Therefore,

The absolute uncertainty is given as 27.4(±0.9)

The percent relative uncertainty is 27.4(±3.2%)

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is written as 27.4(±0.9) and 27.4(±3.2%) respectively.

(c)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be written

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3 , the uncertainty (e4) in addition and subtraction can be calculated as follows,

e4=e12+e22+e32

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Write: The absolute and percent relative uncertainty with a reasonable number of significant figures

(c)

Expert Solution
Check Mark

Answer to Problem 3.BE

The absolute and percent relative uncertainty with a reasonable number of significant figures is 1.49(±0.1)×105 and 1.49(±9.0%)×105 respectively.

Explanation of Solution

Given data:

6.843(±0.008)×104÷[2.09(±0.04)1.63(±0.01)]=?

Calculation of absolute and percent relative uncertainty:

First solve the terms in bracket.

[2.09(±0.04)1.63(±0.01)]=0.46(±0.0412) (Since (0.04)2+(0.01)2=0.0412)

For multiplication and division, convert absolute uncertainty to percent relative uncertainty.

Substitute the above value and rewrite the given equation.

6.843(±0.008)×104÷[0.46(±0.0412)]=?

For 6.843(±0.008) , percent relative uncertainty is (±0.008/6.843)×100=±0.117%

For 0.46(±0.0412) , percent relative uncertainty is (±0.0412/0.46)×100=±8.96%

Substitute all the values in the given problem.

6.843(±0.008)×104÷[0.46(±0.0412)]=6.843(±0.117%)×104÷[0.46(±8.96%)]=1.49(±8.96%)×105 (Since 0.1172+8.962=8.96%)=1.49(±9%)×105(rounded to correct significant figure)

Convert relative uncertainty into absolute uncertainty as follows,

Absolute uncertainty =0.0896×1.49 =0.1335 =0.1(rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 1.49(±0.1)×105

The percent relative uncertainty is 1.49(±9.0%)×105

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is written as 1.49(±0.1)×105 and 1.49(±9.0%)×105 respectively.

(d)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be written

Concept Introduction:

Uncertainty for powers and roots:

For the function y=xa , the relative uncertainty in y (%ey) is a times the relative uncertainty in x (%ex)

y=xa  %ey = a(%ex)

To Write: The absolute and percent relative uncertainty with a reasonable number of significant figures

(d)

Expert Solution
Check Mark

Answer to Problem 3.BE

The absolute and percent relative uncertainty with a reasonable number of significant figures is 1.80±0.02 and 1.80±1% respectively.

Explanation of Solution

Given data:

3.24±0.08=?

Calculation of absolute and percent relative uncertainty:

Use y=xa  %ey = a(%ex)

%ey =12%ex =12(0.083.24×100) =1.235%

Now,

(3.24±0.08)12 =1.80±1.235% (Since3.24=1.80) =1.80±1.2%(rounded to correct significant figure) 

Convert relative uncertainty into absolute uncertainty as follows,

Absolute uncertainty =0.01235×1.80 =0.02223 =0.02(rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 1.80±0.02

The percent relative uncertainty is 1.80±1%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is written 1.80±0.02 and 1.80±1% respectively.

(e)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be written

Concept Introduction:

Uncertainty for powers and roots:

For the function y=xa , the relative uncertainty in y (%ey) is a times the relative uncertainty in x (%ex)

y=xa  %ey = a(%ex)

To Write: The absolute and percent relative uncertainty with a reasonable number of significant figures

(e)

Expert Solution
Check Mark

Answer to Problem 3.BE

The absolute and percent relative uncertainty with a reasonable number of significant figures is 1.1(±0.1)×102 and 1.1(±9.9%)×102 respectively.

Explanation of Solution

Given data:

(3.24±0.08)4=?

Calculation of absolute and percent relative uncertainty:

Use y=xa  %ey = a(%ex)

%ey =4%ex =4(0.083.24×100) =9.877%

Now,

(3.24±0.08)4 =110.20±9.877% (Since (3.24)4=110.20) =110.20±9.9% =1.1×102±9.9% (rounded to correct significant figure)

Convert relative uncertainty into absolute uncertainty as follows,

Absolute uncertainty =0.099×1.1 =0.1089 =0.11 =0.1  (rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 1.1(±0.1)×102

The percent relative uncertainty is 1.1(±9.9%)×102

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is written as 1.1(±0.1)×102 and 1.1(±9.9%)×102 respectively.

(f)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be written

Concept Introduction:

Exponents and logarithm:

Consider, y=logx .

Here, the absolute uncertainty in y(ey) is proportional to the relative uncertainty in x, which is ex/x

Uncertainty for logarithm:        y =1ogxey =1ln 10 xexx 0.43429 exx

To Write: The absolute and percent relative uncertainty with a reasonable number of significant figures

(f)

Expert Solution
Check Mark

Answer to Problem 3.BE

The absolute and percent relative uncertainty with a reasonable number of significant figures is 0.51(±0.01) and 0.51±2% respectively.

Explanation of Solution

Given data:

log(3.24±0.08)=?

Calculation of absolute and percent relative uncertainty:

Use y=logxey =0.43429exx

ey =0.43429exx =0.43429(0.083.24) =0.0107

Now,

log(3.24±0.08)=0.5105±0.0107 (Since log 3.24=0.5101)  =0.51±0.01(rounded to correct significant figure)

Calculate percent relative uncertainty as follows,

Percent Relative uncertainty =(0.0107/0.5105)×100 =2.095% =2.1% =2%  (rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 0.51(±0.01)

The percent relative uncertainty is 0.51±2%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is written as 0.51(±0.01) and 0.51±2% respectively.

(g)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be written

Concept Introduction:

Exponents and logarithm:

Consider, y=antilog xy=10x .

Here, the relative uncertainty in y is proportional to the absolute uncertainty in x.

Uncertainty for 10x:        y =10xeyy =(ln 10)ex 2.3026ex

To Write: The absolute and percent relative uncertainty with a reasonable number of significant figures

(g)

Expert Solution
Check Mark

Answer to Problem 3.BE

The absolute and percent relative uncertainty with a reasonable number of significant figures is 1.7(±0.3)×103 and 1.7(±18%)×103 respectively.

Explanation of Solution

Given data:

103.24±0.08=?

Calculation of absolute and percent relative uncertainty:

Use y=antilog xy=10x

eyy =2.3026ex =2.3026(0.08) =0.184 =18.4%

Now,

103.24±0.08 =1.74×103±18.4% (Since 103.24=1734.81.74×103) =1.7×103±18%(rounded to correct significant figure)

Convert percent relative uncertainty into absolute uncertainty as follows,

Absolute uncertainty =0.184×1.74 =0.320 =0.32% =0.3%  (rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 1.7(±0.3)×103

The percent relative uncertainty is 1.7(±18%)×103

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is written as 1.7(±0.3)×103 and 1.7(±18%)×103 respectively.

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