Quantitative Chemical Analysis 9e And Sapling Advanced Single Course For Analytical Chemistry (access Card)
Quantitative Chemical Analysis 9e And Sapling Advanced Single Course For Analytical Chemistry (access Card)
9th Edition
ISBN: 9781319090241
Author: Daniel C. Harris, Sapling Learning
Publisher: W. H. Freeman
Question
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Chapter 3, Problem 3.16P

(a)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out.

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3 , the uncertainty (e4) in addition and subtraction can be calculated as follows,

e4=e12+e22+e32

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Find: The absolute and percent relative uncertainty with a reasonable number of significant figures

(a)

Expert Solution
Check Mark

Answer to Problem 3.16P

The absolute and percent relative uncertainty with a reasonable number of significant figures is 10.18±0.07  and 10.18±0.7% respectively.

Explanation of Solution

Given data:

9.23(±0.03)+4.12(±0.02)3.26(±0.06)=?

Calculation of absolute and percent relative uncertainty:

+9.23(±0.03)+4.21(±0.02)3.26(±0.06)10.18(±0.07)

The uncertainty (e) is calculated as follows,

uncertainty =0.032+0.022+0.062      =0.07%

The percent relative uncertainty is calculated as follows,

Percent relative uncertainty  = 100 × relative uncertainty =100×0.0710.18 =0.687 =0.7% (rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 10.18±0.07

The percent relative uncertainty is 10.18±0.7%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is found out as 10.18±0.07 and 10.18±0.7% respectively.

(b)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out.

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3 , the uncertainty (e4) in addition and subtraction can be calculated as follows,

e4=e12+e22+e32

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Find: The absolute and percent relative uncertainty with a reasonable number of significant figures

(b)

Expert Solution
Check Mark

Answer to Problem 3.16P

The absolute and percent relative uncertainty with a reasonable number of significant figures is 174±3 and 174±2% respectively.

Explanation of Solution

Given data:

91.3(±1.0)×40.3(±0.2)/21.1(±0.2)=?

Calculation of absolute and percent relative uncertainty:

For multiplication and division, convert absolute uncertainty to percent relative uncertainty.

For 91.3(±1.0) , percent relative uncertainty is (±1.0/91.3)×100=±1.10%

For 40.3(±0.2) , percent relative uncertainty is (±0.2/40.3)×100=±0.50%

For 21.1(±0.2) , percent relative uncertainty is (±0.2/21.1)×100=±0.95%

The percentage uncertainty (e) is calculated as follows,

%uncertainty =1.102+0.502+0.952      =1.54% =2% (rounded to correct significant figure)

Substitute all the values in the given problem.

91.3(±1.0)×40.3(±0.2)/21.1(±0.2)=91.3(±1.10%)×40.3(±0.50%)21.1(±0.95%)=174.37(±1.54%)=174(±2%) (rounded to correct significant figures)

Convert relative uncertainty into absolute uncertainty as follows,

Absolute uncertainty =±0.0154×174.37 =±2.685 =±3(rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 174±3

The percent relative uncertainty is 174±2%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is found out as 174±3 and 174±2% respectively.

(c)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out.

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3 , the uncertainty (e4) in addition and subtraction can be calculated as follows,

e4=e12+e22+e32

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Find: The absolute and percent relative uncertainty with a reasonable number of significant figures

(c)

Expert Solution
Check Mark

Answer to Problem 3.16P

The absolute and percent relative uncertainty with a reasonable number of significant figures is 0.147±0.003 and 0.147±2% respectively.

Explanation of Solution

Given data:

[4.97(±0.05)1.86(±0.01)]/21.1(±0.2)=?

Calculation of absolute and percent relative uncertainty:

Solve the bracket first.

+4.97(±0.05)1.86(±0.01)3.11(±0.0510)

The uncertainty (e) is calculated as follows,

uncertainty =0.052+0.12      =±0.0510

Substitute the obtained value in the given problem and solve further.

[4.97(±0.05)1.86(±0.01)]/21.1(±0.2)[3.11(±0.0510)]/21.1(±0.2)

For multiplication and division, convert absolute uncertainty to percent relative uncertainty.

For 3.11(±0.0510) , percent relative uncertainty is (±0.0510/3.11)×100=±1.64%

For 21.1(±0.2) , percent relative uncertainty is (±0.2/21.1)×100=±0.95%

Thus,

3.11(±0.0510)]/21.1(±0.2)=3.11(±1.64%)/21.1(±0.95%)=0.147(±1.90%) (since (1.64)2+(0.95)2=1.90%=0.147(±2%) (rounded to correct significant figure)

Convert relative uncertainty into absolute uncertainty as follows,

Absolute uncertainty =±0.02×0.147 =±0.00294 =±0.003(rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 10.18±0.07

The percent relative uncertainty is 10.18±0.7%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is found as 0.147±0.003 and 0.147±2% respectively.

(d)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out.

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3 , the uncertainty (e4) in addition and subtraction can be calculated as follows,

e4=e12+e22+e32

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Find: The absolute and percent relative uncertainty with a reasonable number of significant figures

(d)

Expert Solution
Check Mark

Answer to Problem 3.16P

The absolute and percent relative uncertainty with a reasonable number of significant figures is 7.86±0.01 and 7.86±0.1% respectively.

Explanation of Solution

Given data:

2.0164(±0.0008)+1.233(±0.002)+4.61(±0.01)=?

Calculation of absolute and percent relative uncertainty:

+2.0164(±0.0008)+1.233(±0.002)+4.61(±0.01)7.86(±0.01)

The uncertainty (e) is calculated as follows,

uncertainty =0.00082+0.0022+0.012      =0.01

The percent relative uncertainty is calculated as follows,

Percent relative uncertainty  = 100 × relative uncertainty =100×0.017.86 =0.127 =0.1% (rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 7.86±0.01

The percent relative uncertainty is 7.86±0.1%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is found as 7.86±0.01 and 7.86±0.1% respectively.

(e)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out.

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3 , the uncertainty (e4) in addition and subtraction can be calculated as follows,

e4=e12+e22+e32

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Find: The absolute and percent relative uncertainty with a reasonable number of significant figures

(e)

Expert Solution
Check Mark

Answer to Problem 3.16P

The absolute and percent relative uncertainty with a reasonable number of significant figures is 2185.8±0.8 and 2185.8±0.04% respectively.

Explanation of Solution

Given data:

2.0164(±0.0008)×103+1.233(±0.002)×102+4.61(±0.01)×101=?

Calculation of absolute and percent relative uncertainty:

+2016.4(±0.8)+123.3(±0.2)+46.1(±0.1)2185.8(±0.8)

The uncertainty (e) is calculated as follows,

uncertainty =0.82+0.22+0.12      =0.8

The percent relative uncertainty is calculated as follows,

Percent relative uncertainty  = 100 × relative uncertainty =100×0.82185.8 =0.0365 =0.04% (rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 7.86±0.01

The percent relative uncertainty is 7.86±0.1%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is found as 2185.8±0.8 and 2185.8±0.04% respectively.

(f)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out.

Concept Introduction:

Uncertainty for powers and roots:

For the function y=xa , the relative uncertainty in y (%ey) is a times the relative uncertainty in x (%ex)

y=xa  %ey = a(%ex)

To Find: The absolute and percent relative uncertainty with a reasonable number of significant figures

(f)

Expert Solution
Check Mark

Answer to Problem 3.16P

The absolute and percent relative uncertainty with a reasonable number of significant figures is 1.464±0.007 and 1.464±0.5% respectively.

Explanation of Solution

Given data:

[3.14(±0.05)]1/3=?

Calculation of absolute and percent relative uncertainty:

Use y=xa  %ey = a(%ex)

x=3.14±0.05%ex=(0.05/3.14)×100=1.592%

%ey =13%ex =13(1.592%) =0.531%

Now,

(3.24±0.08)12 =1.4643±0.531% (Since3.14=1.4643) =1.464±0.5%(rounded to correct significant figure) 

Convert relative uncertainty into absolute uncertainty as follows,

Absolute uncertainty =0.00531×1.464 =0.007773 =0.0078 =0.007(rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 1.464±0.007

The percent relative uncertainty is 1.464±0.5%

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is found out as 1.464±0.007 and 1.464±0.5% respectively.

(g)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out.

Concept Introduction:

Exponents and logarithm:

Consider, y=logx .

Here, the absolute uncertainty in y(ey) is proportional to the relative uncertainty in x, which is ex/x

Uncertainty for logarithm:        y =1ogxey =1ln 10 xexx 0.43429 exx

To Find: The absolute and percent relative uncertainty with a reasonable number of significant figures

(g)

Expert Solution
Check Mark

Answer to Problem 3.16P

The absolute and percent relative uncertainty with a reasonable number of significant figures is 0.496(±0.006) and 0.496(±1.3%) respectively.

Explanation of Solution

Given data:

log[3.14±0.05]=?

Calculation of absolute and percent relative uncertainty:

Use y=logxey =0.43429exx

ey =0.43429exx =0.43429(0.053.14) =0.006915 =0.006 (round to correct significant figure)

Now,

log(3.14±0.05)=0.4969±0.006915 (Since log 3.14=0.5101)  =0.496±0.006(rounded to correct significant figure)

Calculate percent relative uncertainty as follows,

Percent Relative uncertainty =(0.000069/0.496)×100 =0.0139% =1.39% =1.3%  (rounded to correct significant figure)

Therefore,

The absolute uncertainty is given as 0.496(±0.006)

The percent relative uncertainty is 0.496(±1.3%)

Conclusion

The absolute and percent relative uncertainty with a reasonable number of significant figures is found out as 0.496(±0.006) and 0.496(±1.3%) respectively.

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