(a)
Interpretation:
Conjugate bases of given acids are needed to be drawn.
Concept introduction:
According to Bronsted-Lowry concept, acid is a proton donor. The deprotonated acids are called conjugate base. The stability of this conjugate base determines the location of deprotonation in an acid.
In a conjugate base where the negative charge is carried by a more electronegative atom will show more stability. The greater electronegativity makes lone pair closer to the nucleus hence more stabilized.
The conjugate base having resonance will have greater stability as compared to conjugate base having single anion. Because of the resonance conjugate base will get resonance stabilization.
(a)
Answer to Problem 37PP
Explanation of Solution
The most acidic proton of the given acid (a) is
(b)
Interpretation:
Conjugate bases of given acids are needed to be drawn.
Concept introduction:
According to Bronsted-Lowry concept, acid is a proton donor. The deprotonated acids are called conjugate base. The stability of this conjugate base determines the location of deprotonation in an acid.
In a conjugate base where the negative charge is carried by a more electronegative atom will show more stability. The greater electronegativity makes lone pair closer to the nucleus hence more stabilized.
The conjugate base having resonance will have greater stability as compared to conjugate base having single anion. Because of the resonance conjugate base will get resonance stabilization.
(b)
Answer to Problem 37PP
Explanation of Solution
The most acidic hydrogen atom presented in the given acid is
.
No other
(c)
Interpretation:
Conjugate bases of given acids are needed to be drawn.
Concept introduction:
According to Bronsted-Lowry concept, acid is a proton donor. The deprotonated acids are called conjugate base. The stability of this conjugate base determines the location of deprotonation in an acid.
In a conjugate base where the negative charge is carried by a more electronegative atom will show more stability. The greater electronegativity makes lone pair closer to the nucleus hence more stabilized.
The conjugate base having resonance will have greater stability as compared to conjugate base having single anion. Because of the resonance conjugate base will get resonance stabilization.
(c)
Answer to Problem 37PP
Explanation of Solution
Deprotonation of
(d)
Interpretation:
Conjugate bases of given acids are needed to be drawn.
Concept introduction:
According to Bronsted-Lowry concept, acid is a proton donor. The deprotonated acids are called conjugate base. The stability of this conjugate base determines the location of deprotonation in an acid.
In a conjugate base where the negative charge is carried by a more electronegative atom will show more stability. The greater electronegativity makes lone pair closer to the nucleus hence more stabilized.
The conjugate base having resonance will have greater stability as compared to conjugate base having single anion. Because of the resonance conjugate base will get resonance stabilization.
(d)
Answer to Problem 37PP
Explanation of Solution
Deprotonation of
(e)
Interpretation:
Conjugate bases of given acids are needed to be drawn.
Concept introduction:
According to Bronsted-Lowry concept, acid is a proton donor. The deprotonated acids are called conjugate base. The stability of this conjugate base determines the location of deprotonation in an acid.
In a conjugate base where the negative charge is carried by a more electronegative atom will show more stability. The greater electronegativity makes lone pair closer to the nucleus hence more stabilized.
The conjugate base having resonance will have greater stability as compared to conjugate base having single anion. Because of the resonance conjugate base will get resonance stabilization.
(e)
Answer to Problem 37PP
Explanation of Solution
The most acidic proton of the given acid (e) is
(f)
Interpretation:
Conjugate bases of given acids are needed to be drawn.
Concept introduction:
According to Bronsted-Lowry concept, acid is a proton donor. The deprotonated acids are called conjugate base. The stability of this conjugate base determines the location of deprotonation in an acid.
In a conjugate base where the negative charge is carried by a more electronegative atom will show more stability. The greater electronegativity makes lone pair closer to the nucleus hence more stabilized.
The conjugate base having resonance will have greater stability as compared to conjugate base having single anion. Because of the resonance conjugate base will get resonance stabilization.
(f)
Answer to Problem 37PP
Explanation of Solution
The most acidic proton of the given acid (e) is
(g)
Interpretation:
Conjugate bases of given acids are needed to be drawn.
Concept introduction:
According to Bronsted-Lowry concept, acid is a proton donor. The deprotonated acids are called conjugate base. The stability of this conjugate base determines the location of deprotonation in an acid.
In a conjugate base where the negative charge is carried by a more electronegative atom will show more stability. The greater electronegativity makes lone pair closer to the nucleus hence more stabilized.
The conjugate base having resonance will have greater stability as compared to conjugate base having single anion. Because of the resonance conjugate base will get resonance stabilization.
(g)
Answer to Problem 37PP
Explanation of Solution
Deprotonation of
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Chapter 3 Solutions
ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
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