(a)
Interpretation:
Conjugate bases of given acids are needed to be drawn.
Concept introduction:
According to Bronsted-Lowry concept, acid is a proton donor. The deprotonated acids are called conjugate base. The stability of this conjugate base determines the location of deprotonation in an acid.
In a conjugate base where the negative charge is carried by a more electronegative atom will show more stability. The greater electronegativity makes lone pair closer to the nucleus hence more stabilized.
The conjugate base having resonance will have greater stability as compared to conjugate base having single anion. Because of the resonance conjugate base will get resonance stabilization.
(a)
Answer to Problem 37PP
Explanation of Solution
The most acidic proton of the given acid (a) is
(b)
Interpretation:
Conjugate bases of given acids are needed to be drawn.
Concept introduction:
According to Bronsted-Lowry concept, acid is a proton donor. The deprotonated acids are called conjugate base. The stability of this conjugate base determines the location of deprotonation in an acid.
In a conjugate base where the negative charge is carried by a more electronegative atom will show more stability. The greater electronegativity makes lone pair closer to the nucleus hence more stabilized.
The conjugate base having resonance will have greater stability as compared to conjugate base having single anion. Because of the resonance conjugate base will get resonance stabilization.
(b)
Answer to Problem 37PP
Explanation of Solution
The most acidic hydrogen atom presented in the given acid is
.
No other
(c)
Interpretation:
Conjugate bases of given acids are needed to be drawn.
Concept introduction:
According to Bronsted-Lowry concept, acid is a proton donor. The deprotonated acids are called conjugate base. The stability of this conjugate base determines the location of deprotonation in an acid.
In a conjugate base where the negative charge is carried by a more electronegative atom will show more stability. The greater electronegativity makes lone pair closer to the nucleus hence more stabilized.
The conjugate base having resonance will have greater stability as compared to conjugate base having single anion. Because of the resonance conjugate base will get resonance stabilization.
(c)
Answer to Problem 37PP
Explanation of Solution
Deprotonation of
(d)
Interpretation:
Conjugate bases of given acids are needed to be drawn.
Concept introduction:
According to Bronsted-Lowry concept, acid is a proton donor. The deprotonated acids are called conjugate base. The stability of this conjugate base determines the location of deprotonation in an acid.
In a conjugate base where the negative charge is carried by a more electronegative atom will show more stability. The greater electronegativity makes lone pair closer to the nucleus hence more stabilized.
The conjugate base having resonance will have greater stability as compared to conjugate base having single anion. Because of the resonance conjugate base will get resonance stabilization.
(d)
Answer to Problem 37PP
Explanation of Solution
Deprotonation of
(e)
Interpretation:
Conjugate bases of given acids are needed to be drawn.
Concept introduction:
According to Bronsted-Lowry concept, acid is a proton donor. The deprotonated acids are called conjugate base. The stability of this conjugate base determines the location of deprotonation in an acid.
In a conjugate base where the negative charge is carried by a more electronegative atom will show more stability. The greater electronegativity makes lone pair closer to the nucleus hence more stabilized.
The conjugate base having resonance will have greater stability as compared to conjugate base having single anion. Because of the resonance conjugate base will get resonance stabilization.
(e)
Answer to Problem 37PP
Explanation of Solution
The most acidic proton of the given acid (e) is
(f)
Interpretation:
Conjugate bases of given acids are needed to be drawn.
Concept introduction:
According to Bronsted-Lowry concept, acid is a proton donor. The deprotonated acids are called conjugate base. The stability of this conjugate base determines the location of deprotonation in an acid.
In a conjugate base where the negative charge is carried by a more electronegative atom will show more stability. The greater electronegativity makes lone pair closer to the nucleus hence more stabilized.
The conjugate base having resonance will have greater stability as compared to conjugate base having single anion. Because of the resonance conjugate base will get resonance stabilization.
(f)
Answer to Problem 37PP
Explanation of Solution
The most acidic proton of the given acid (e) is
(g)
Interpretation:
Conjugate bases of given acids are needed to be drawn.
Concept introduction:
According to Bronsted-Lowry concept, acid is a proton donor. The deprotonated acids are called conjugate base. The stability of this conjugate base determines the location of deprotonation in an acid.
In a conjugate base where the negative charge is carried by a more electronegative atom will show more stability. The greater electronegativity makes lone pair closer to the nucleus hence more stabilized.
The conjugate base having resonance will have greater stability as compared to conjugate base having single anion. Because of the resonance conjugate base will get resonance stabilization.
(g)
Answer to Problem 37PP
Explanation of Solution
Deprotonation of
Want to see more full solutions like this?
Chapter 3 Solutions
ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
- When anisole is treated with excess bromine, the reaction gives a product which shows two singlets in 1H NMR. Draw the product.arrow_forward(ii) Draw a reasonable mechanism for the following reaction: CI NaOH heat OH (hint: SNAr Reaction) :arrow_forwardDraw the major product in each of the following reaction:arrow_forward
- Draw the mechanism for the following Friedel-Craft reaction. AlBr3 Brarrow_forward(a) Draw the structures of A and B in the following reaction. (i) NaNH2, NH3(1) A + B (ii) H3O+arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forward
- Consider the following decomposition reaction of N2O5(g): For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 → NO2 + NO3 (K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → NO2 + O2 + NO (K2) NO + N2O5 → NO2 + NO2 + NO2 (K3) Indicate whether the following rate expression is acceptable: d[N2O5] = -k₁[N₂O₂] + K¸₁[NO₂][NO3] - K¸[NO₂]³ dtarrow_forwardIn a reaction of A + B to give C, another compound other than A, B or C may appear in the kinetic equation.arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forward
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY