ORGANIC CHEMISTRY W/BIOLOGICAL TOPICS
6th Edition
ISBN: 9781260325294
Author: SMITH
Publisher: RENT MCG
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Textbook Question
Chapter 3, Problem 37P
Draw seven constitutional isomers with molecular formula
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identify the functional group of each compound.
Name and encircle the functional groups present in each molecule.
Glucose, C6H12O6, contains an aldehyde group but exist predominantly in the form of the cyclic hemiacetal show below.
A cyclic hemiacetal is formed when the —OH group of one carbon bonds to the carbonyl group of another carbon. Identify which carbon provides the —OH group and which provides the —CHO? Give a functional isomer of glucose and draw its structure.
Chapter 3 Solutions
ORGANIC CHEMISTRY W/BIOLOGICAL TOPICS
Ch. 3.1 - Prob. 1PCh. 3.2 - (a) Classify the carbon atoms in each compound as...Ch. 3.2 - Problem 3.3 Classify a carbon atom by the number...Ch. 3.2 - Classify each alkyl halide and alcohol as , or...Ch. 3.2 - Prob. 5PCh. 3.2 - Prob. 6PCh. 3.2 - Draw the structure of a compound of molecular...Ch. 3.2 - Prob. 8PCh. 3.2 - Prob. 9PCh. 3.2 - Draw the structure of a compound fitting each...
Ch. 3.4 - Predict which compound in each pair has the higher...Ch. 3.4 - Prob. 17PCh. 3.4 - a Label the hydrophobic and hydrophilic portions...Ch. 3.5 - Prob. 21PCh. 3 - 3.29
Identify the functional groups in the...Ch. 3 - Prob. 32PCh. 3 - 3.31 For each alkane: (a) classify each carbon...Ch. 3 - 3.32 Identify the functional groups in each...Ch. 3 - 3.33 Identify each functional group located in the...Ch. 3 - 3.34 (a)Identify the functional groups in...Ch. 3 - Draw seven constitutional isomers with molecular...Ch. 3 - Prob. 38PCh. 3 - Prob. 39PCh. 3 - Prob. 40PCh. 3 - Intramolecular force of attraction are often...Ch. 3 - 3.40 (a) Draw four compounds with molecular...Ch. 3 - 3.41 Rank the compounds in each group in order of...Ch. 3 - Explain why CH3CH2NHCH3 has higher boiling point...Ch. 3 - Prob. 45PCh. 3 - 3.44 Rank the following compounds in order of...Ch. 3 - Prob. 47PCh. 3 - 3.50 Predict the solubility of each of the...Ch. 3 - Prob. 52PCh. 3 - Prob. 53PCh. 3 - 3.53 THC is the active component in marijuana, and...Ch. 3 - Prob. 55PCh. 3 - Prob. 56PCh. 3 - 3.60 Quinapril (trade name Accupril) is a drug...Ch. 3 - 3.61 Answer each question about oxycodone, a...Ch. 3 - Prob. 65PCh. 3 - Prob. 66PCh. 3 - 3.64 Explain why A is less water soluble than B,...Ch. 3 - 3.65 Recall from section 1.10B that there is...
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- What functional group distinguishes each of the following hydrocarbon derivatives? a. halohydrocarbons b. alcohols c. ethers d. aldehydes e. ketones f. carboxylic acids g. esters h. amines Give examples of each functional group. What prefix or suffix is used to name each functional group? What are the bond angles in each? Describe the bonding in each functional group. What is the difference between a primary, secondary, and tertiary alcohol? For the functional groups in ah, when is a number required to indicate the position of the functional group? Carboxylic acids are often written as RCOOH. What does COOH indicate and what does R indicate? Aldehydes are sometimes written as RCHO. What does CHO indicate?arrow_forwardThe chemical formula C4H10O results in four alcohols and three ethers for a total of seven structuralisomers. Draw pairs of structural formulas for these molecules that illustrate positional and functional isomerism on a sheet of paper. You will be drawing a total of four formulas. Label each pair as positional or functional.arrow_forwardAn organic compound ‘X’ has the molecular formula C2H4O2. It has a pleasant smell. It does not change colour of the red litmus paper; nor does it react with sodium hydrogen carbonate solution. Predict the compound's functional group and give its IUPAC name.arrow_forward
- Structural isomers are compounds with same molecular formula, same functional groups, but different structural formulas. O True O Falsearrow_forwardTo which family does this organic molecule belong? CH 3 CH 3 | N H₂C Alkane Amide Amine Alcohol CH 3arrow_forwardDraw structures that fit each description and name the functional group in each molecule: (a) two constitutional isomers with molecular formula C5H10O that contain different functional groups; (b) two constitutional isomers with molecular formula C6H10O that contain the same functional group.arrow_forward
- Glucose, C6H12O6, contains an aldehyde group but exist predominantly in the form of the cyclic hemiacetal show below. A cyclic hemiacetal is formed when the —OH group of one carbon bonds to the carbonyl group of another carbon. Identify which carbon provides the —OH group and which provides the —CHO? Give a functional isomer of glucose and draw its structure.arrow_forwardYou were tasked to propose a structure for a compound with a chemical formula of C₂H₂N. In the laboratory, the compound appears as a clear, colorless liquid. To determine the structure of the compound, you subject the compound to several solubility tests and chemical tests. The observations for these tests are summarized: SOLUBILITY GROUP: Group V Insoluble in water and 10% NaOH but soluble in 10% HCI FUNCTIONAL GROUP/CLASS: Amine 1) Based on the results of the solubility tests and chemical tests, what is the most probable structure of C7H9N? Draw your answer in the box below. You may draw the compound using line-bond formula OR Lewis structure. |arrow_forwardname each functional grouparrow_forward
- organicarrow_forward1. The chemical formula C4H100 results in four alcohols and three ethers for a total of seven structural isomers. Draw pairs of structural formulas for these molecules that illustrate positional and functional isomerism on a sheet of paper. You will be drawing a total of four formulas. Label each pair as positional or functional.arrow_forwardIdentify the functional groups in the following structure. H H НС CH3 C. ¿CH НО H Ester O Aldehyde Alkyne Amide Ketone O Alcohol Amine Carboxylic acid O Phenyl Alkene Etherarrow_forward
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