Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 3, Problem 3.63QP
What are the inadequacies of Bohr’s theory?
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f. Predict how the van Deemter curve in Figure 7
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from 40 °C to 55 °C.
Figure 7. van Desmter curves in reduced coordinates for four
nitroalkane homologues (nitropropane, black; nitrobutane, red;
nitropentane, blue; and nitrohexane, green) separated on the FMS
phase. Chromatographic conditions: column dimensions 50 mm × 4.6
mm id, eluent 30/70 ACN/water, flow rates 0.2-5.0 mL/min, injection
volume 0.5 and column temperature 40 °C. No corrections to the
plate heights have been made to account for extracolumn dispersion.
Reduced Plate Height (h)
°
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60
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8. (2) A water sample is analyzed for traces of benzene using headspace analysis. The sample and
standard are spiked with a fixed amount of toluene as an internal standard. The following data are
obtained:
Ppb benzene
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Peak area toluene
10.0
252
376
Sample
533
368
What is the concentration of benzene in the sample?
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Chapter 3 Solutions
Chemistry: Atoms First
Ch. 3.1 - Calculate the kinetic energy of a helium atom...Ch. 3.1 - Calculate the energy in joules of a 5.25-g object...Ch. 3.1 - Prob. 1PPBCh. 3.1 - Prob. 1PPCCh. 3.1 - Prob. 3.2WECh. 3.1 - How much greater is the electrostatic potential...Ch. 3.1 - What must the separation between charges of +2 and...Ch. 3.1 - Prob. 2PPCCh. 3.1 - Calculate the kinetic energy of a 5.0-kg mass...Ch. 3.1 - Prob. 3.1.2SR
Ch. 3.1 - Arrange the following pairs of charged particles...Ch. 3.2 - One type of laser used in the treatment of...Ch. 3.2 - What is the wavelength (in meters) of an...Ch. 3.2 - What is the frequency (in reciprocal seconds) of...Ch. 3.2 - Which of the following sets of waves best...Ch. 3.2 - Calculate the wavelength (in nanometers) of light...Ch. 3.2 - Prob. 3.2.2SRCh. 3.2 - Prob. 3.2.3SRCh. 3.2 - When traveling through a translucent medium, such...Ch. 3.3 - Calculate the energy (in joules) of (a) a photon...Ch. 3.3 - Calculate the energy (in joules) of (a) a photon...Ch. 3.3 - (a) Calculate the wavelength (in nanometers) of...Ch. 3.3 - Calculate the energy per photon of light with...Ch. 3.3 - Calculate the wavelength (in centimeters) of light...Ch. 3.3 - Calculate the maximum kinetic energy of an...Ch. 3.3 - A clean metal surface is irradiated with light of...Ch. 3.3 - Prob. 3.3.5SRCh. 3.4 - Calculate the wavelength (in nanometers) of the...Ch. 3.4 - What is the wavelength (in nanometers) of a photon...Ch. 3.4 - What is the value of ni for an electron that emits...Ch. 3.4 - For each pair of transitions, determine which one...Ch. 3.4 - Calculate the energy of an electron in the n = 3...Ch. 3.4 - Calculate E of an electron that goes from n = 1 to...Ch. 3.4 - What is the wavelength (in meters) of light...Ch. 3.4 - What wavelength (in nanometers) corresponds to the...Ch. 3.5 - Calculate the de Broglie wavelength of the...Ch. 3.5 - Calculate the de Broglie wavelength (in...Ch. 3.5 - Use Equation 3.11 to calculate the momentum, p...Ch. 3.5 - Consider the impact of early electron diffraction...Ch. 3.5 - Calculate the de Broglie wavelength associated...Ch. 3.5 - At what speed must a helium-4 atom be traveling to...Ch. 3.5 - Determine the minimum speed required for a...Ch. 3.6 - An electron in a hydrogen atom is known to have a...Ch. 3.6 - Prob. 7PPACh. 3.6 - (a) Calculate the minimum uncertainty in the...Ch. 3.6 - Using Equation 3.13, we can calculate the minimum...Ch. 3.6 - What is the minimum uncertainty in the position of...Ch. 3.6 - What is the minimum uncertainty in the position of...Ch. 3.7 - What are the possible values for the magnetic...Ch. 3.7 - Prob. 8PPACh. 3.7 - Prob. 8PPBCh. 3.7 - Prob. 8PPCCh. 3.7 - Prob. 3.7.1SRCh. 3.7 - How many subshells are there in the shell...Ch. 3.7 - What is the total number of orbitals in the shell...Ch. 3.7 - What is the minimum value of the principal quantum...Ch. 3.8 - Prob. 3.9WECh. 3.8 - Prob. 9PPACh. 3.8 - Prob. 9PPBCh. 3.8 - Prob. 9PPCCh. 3.8 - Prob. 3.8.1SRCh. 3.8 - Prob. 3.8.2SRCh. 3.8 - In a hydrogen atom, which orbitals are higher in...Ch. 3.8 - Which of the following sets of quantum numbers, n,...Ch. 3.9 - Write the electron configuration and give the...Ch. 3.9 - Prob. 10PPACh. 3.9 - Write the electron configuration and give the...Ch. 3.9 - Prob. 10PPCCh. 3.9 - Which of the following electron configurations...Ch. 3.9 - Prob. 3.9.2SRCh. 3.9 - Which orbital diagram is collect for the...Ch. 3.10 - Without referring to Figure 3.26, write the...Ch. 3.10 - Prob. 11PPACh. 3.10 - Prob. 11PPBCh. 3.10 - Consider again the alternate universe and its...Ch. 3.10 - Which of the following electron configurations...Ch. 3.10 - Prob. 3.10.2SRCh. 3.10 - Prob. 3.10.3SRCh. 3.10 - Prob. 3.10.4SRCh. 3 - Prob. 3.1KSPCh. 3 - Which of the following electron configurations...Ch. 3 - Prob. 3.3KSPCh. 3 - Prob. 3.4KSPCh. 3 - Define these terms: potential energy, kinetic...Ch. 3 - What are the units for energy commonly employed in...Ch. 3 - A truck initially traveling at 60 km/h is brought...Ch. 3 - Describe the interconversions of forms of energy...Ch. 3 - Determine the kinetic energy of (a) a 1.25-kg mass...Ch. 3 - Determine the kinetic energy of (a) a 29-kg mass...Ch. 3 - Prob. 3.7QPCh. 3 - Determine (a) the velocity of an electron that has...Ch. 3 - Prob. 3.9QPCh. 3 - (a) How much greater is the electrostatic energy...Ch. 3 - Prob. 3.11QPCh. 3 - Prob. 3.12QPCh. 3 - List the types of electromagnetic radiation,...Ch. 3 - Prob. 3.14QPCh. 3 - Prob. 3.15QPCh. 3 - Prob. 3.16QPCh. 3 - The SI unit of time is the second, which is...Ch. 3 - Prob. 3.18QPCh. 3 - Prob. 3.19QPCh. 3 - Four waves represent light in four different...Ch. 3 - Prob. 3.21QPCh. 3 - Prob. 3.22QPCh. 3 - Prob. 3.23QPCh. 3 - What is a photon? What role did Einsteins...Ch. 3 - A photon has a wavelength of 705 nm. Calculate the...Ch. 3 - The blue color of the sky results from the...Ch. 3 - A photon has a frequency of 6.5 109 Hz. (a)...Ch. 3 - Prob. 3.28QPCh. 3 - Calculate the difference in energy (in joules)...Ch. 3 - How much more energy per photon is there in green...Ch. 3 - Prob. 3.31QPCh. 3 - A particular form of electromagnetic radiation has...Ch. 3 - Photosynthesis makes use of visible light to bring...Ch. 3 - The retina of a human eye can detect light when...Ch. 3 - Prob. 3.35QPCh. 3 - The binding energy of magnesium metal is 5.86 ...Ch. 3 - What is the kinetic energy of the ejected electron...Ch. 3 - A red light was shined onto a metal sample and the...Ch. 3 - A photoelectric experiment was performed by...Ch. 3 - Which of the following best explains why we see...Ch. 3 - One way to see the emission spectrum of hydrogen...Ch. 3 - How many lines would we see in the emission...Ch. 3 - For a hydrogen atom in which the electron has been...Ch. 3 - Prob. 3.40QPCh. 3 - Prob. 3.41QPCh. 3 - Briefly describe Bohrs theory of the hydrogen atom...Ch. 3 - Explain the meaning of the negative sign in...Ch. 3 - Consider the following energy levels of a...Ch. 3 - Prob. 3.45QPCh. 3 - Calculate the wavelength (in nanometers) of a...Ch. 3 - Calculate the frequency (hertz) and wavelength...Ch. 3 - What wavelength of light is needed to excite the...Ch. 3 - An electron in the hydrogen atom makes a...Ch. 3 - Explain why elements produce their own...Ch. 3 - Some copper-containing substances emit green light...Ch. 3 - Prob. 3.52QPCh. 3 - Prob. 3.53QPCh. 3 - Prob. 3.54QPCh. 3 - Why is Equation 3.11 meaningful only for...Ch. 3 - Prob. 3.56QPCh. 3 - Thermal neutrons are neutrons that move at speeds...Ch. 3 - Protons can be accelerated to speeds near that of...Ch. 3 - Prob. 3.59QPCh. 3 - What is the de Broglie wavelength (in nanometers)...Ch. 3 - Prob. 3.61QPCh. 3 - Prob. 3.62QPCh. 3 - What are the inadequacies of Bohrs theory?Ch. 3 - What is the Heisenberg uncertainty principle? What...Ch. 3 - Prob. 3.65QPCh. 3 - Prob. 3.66QPCh. 3 - Prob. 3.67QPCh. 3 - The speed of a thermal neutron (see Problem 3.57)...Ch. 3 - Alveoli are tiny sacs of air in the lungs. Their...Ch. 3 - In the beginning of the twentieth century, some...Ch. 3 - Suppose that photons of blue light (430 nm) are...Ch. 3 - Prob. 3.72QPCh. 3 - Prob. 3.73QPCh. 3 - Which of the four quantum numbers (n, , m, ms)...Ch. 3 - Prob. 3.75QPCh. 3 - Prob. 3.76QPCh. 3 - Indicate which of the following sets of three...Ch. 3 - Prob. 3.78QPCh. 3 - Describe the shapes of s, p, and d orbitals. How...Ch. 3 - Prob. 3.80QPCh. 3 - Describe the characteristics of an s orbital, p...Ch. 3 - Why is a boundary surface diagram useful in...Ch. 3 - Prob. 3.83QPCh. 3 - Give the values of the four quantum numbers of an...Ch. 3 - Describe how a 1s orbital and a 2s orbital are...Ch. 3 - Prob. 3.86QPCh. 3 - Prob. 3.87QPCh. 3 - Make a chart of all allowable orbitals in the...Ch. 3 - Prob. 3.89QPCh. 3 - Prob. 3.90QPCh. 3 - A 3s orbital is illustrated here. Using this as a...Ch. 3 - Prob. 3.92QPCh. 3 - Prob. 3.93QPCh. 3 - State the Aufbau principle, and explain the role...Ch. 3 - Indicate the total number of (a) p electrons in N...Ch. 3 - Calculate the total number of electrons that can...Ch. 3 - Determine the total number of electrons that can...Ch. 3 - Determine the maximum number of electrons that can...Ch. 3 - Prob. 3.99QPCh. 3 - The electron configuration of an atom in the...Ch. 3 - List the following atoms in order of increasing...Ch. 3 - Determine the number of unpaired electrons in each...Ch. 3 - Determine the number of impaired electrons in each...Ch. 3 - Determine the number of unpaired electrons in each...Ch. 3 - Prob. 3.105QPCh. 3 - Portions of orbital diagrams representing the...Ch. 3 - Prob. 3.107QPCh. 3 - Prob. 3.108QPCh. 3 - Prob. 3.109QPCh. 3 - Define the following terms and give an example of...Ch. 3 - Explain why the ground-state electron...Ch. 3 - Write the election configuration of a xenon core.Ch. 3 - Comment on the correctness of the following...Ch. 3 - Prob. 3.114QPCh. 3 - Prob. 3.115QPCh. 3 - Write the ground-state electron configurations for...Ch. 3 - Write the ground-state electron configurations for...Ch. 3 - What is the symbol of the element with the...Ch. 3 - Prob. 3.119QPCh. 3 - Prob. 3.120QPCh. 3 - Discuss the current view of the correctness of the...Ch. 3 - Distinguish carefully between the following terms:...Ch. 3 - What is the maximum number of electrons in an atom...Ch. 3 - Prob. 3.124QPCh. 3 - Prob. 3.125QPCh. 3 - A baseball pitchers fastball has been clocked at...Ch. 3 - A ruby laser produces radiation of wavelength 633...Ch. 3 - Four atomic energy levels of an atom are shown...Ch. 3 - Prob. 3.129QPCh. 3 - Spectral lines of the Lyman and Balmer series do...Ch. 3 - Only a fraction of the electric energy supplied to...Ch. 3 - The figure here illustrates a series of...Ch. 3 - When one of heliums electrons is removed, the...Ch. 3 - The retina of a human eye can detect light when...Ch. 3 - An electron in an excited state in a hydrogen atom...Ch. 3 - Prob. 3.136QPCh. 3 - The election configurations described in this...Ch. 3 - Draw the shapes (boundary surfaces) of the...Ch. 3 - Prob. 3.139QPCh. 3 - Consider the graph here. (a) Calculate the binding...Ch. 3 - Scientists have found interstellar hydrogen atoms...Ch. 3 - Ionization energy is the minimum energy required...Ch. 3 - Prob. 3.143QPCh. 3 - Prob. 3.144QPCh. 3 - The cone cells of the human eye are sensitive to...Ch. 3 - (a) An electron in the ground state of the...Ch. 3 - Prob. 3.147QPCh. 3 - Prob. 3.148QPCh. 3 - When an election makes a transition between energy...Ch. 3 - Blackbody radiation is the term used to describe...Ch. 3 - Suppose that photons of red light (675 nm) are...Ch. 3 - In an election microscope, electrons are...Ch. 3 - According to Einsteins special theory of...Ch. 3 - The mathematical equation for studying the...
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- This paper describes the use of fullerene molecules, also known as buckyballs, as a stationary phase for liquid chromatography. The performance of the fullerene-modified stationary phase (FMS) is compared to that of a more common C18 stationary phase and to two other carbon-based stationary phases, PGC and COZ. A. 10A OM B. - Figure 1. Idealized drawing of the cross-section of a pore inside a silica particle, showing the relative densities of aminopropylsilyl (red/green) and fullerene (blue) groups: (A) full cross- section; (B) detailed view of covalent bonding of fullerene to the silica surface. Surface densities of silyl and fullerene groups were inferred from elemental composition results obtained at each stage of the synthesis (see Table 1). Absorbance (mAU, 220 nm) 700 600 500 400 300 200 100 a. Define selectivity, a, with words and an equation. b. Explain how the choice of stationary phase affects selectivity. c. Calculate the resolution of the nitrobenzene and toluene peaks in…arrow_forwardNormalized Intensity (a. u.) 0.5 1.0 A 3D-printed GC column (shown below) was created for use with "micro" gas chromatography applications. To prove its utility, it was used to separate a mixture of alkanes (C9-C18, C22, C24). For the separation shown below, the column temperature was ramped from 40 °C to 250 °C at a rate of 30 °C per minute. (a) 9 10 = 1 mm 12 13 15 22 0.0 0 100 200 300 400 Time (sec) a) What detector would you use for this analysis? Justify your selection. b) Explain how the chromatogram would change if the separation was run isothermally. c) Explain how the chromatogram would change if the temperature ramp were increased to 50 °C per minute.arrow_forwardDevise a synthesis of each compound from the indicated starting material. You may also use any organic compounds with one or two carbons and any needed inorganic reagents. a. Brarrow_forward
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