Chemistry: The Central Science (14th Edition)
14th Edition
ISBN: 9780134414232
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 3, Problem 34E
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Chapter 3 Solutions
Chemistry: The Central Science (14th Edition)
Ch. 3.1 - In the following diagram, the white spheres...Ch. 3.1 - In the following digram, the white spheres...Ch. 3.1 - The unbalanced equation for the reaction between...Ch. 3.1 - Balance these equations by providing the missing...Ch. 3.2 - Which of the following reactions is the balanced...Ch. 3.2 - Write a balanced equation for (a) solid...Ch. 3.2 - Write the balanced equation for the reaction that...Ch. 3.2 - Prob. 3.4.2PECh. 3.3 - Which of the following is the correct formula...Ch. 3.3 - Prob. 3.5.2PE
Ch. 3.3 - What is the percentage of nitrogen, by mass, in...Ch. 3.3 - Calculate the percentage of potassium by mass in...Ch. 3.4 - Which of the following samples contains the fewest...Ch. 3.4 - Without using a calculator, arrange these samples...Ch. 3.4 -
How many sulfur are in (a) 0.45 mol BaSo4 and (b)...Ch. 3.4 -
How many oxygen atoms are in (a) 0.25 mol...Ch. 3.4 - A sample of an ionic compound containing iron and...Ch. 3.4 - Calculate the molar mass of Ca(NO3)2Ch. 3.4 - A 508-g sample of sodium bicarbonate (NaHCO3)...Ch. 3.4 - Prob. 3.10.2PECh. 3.4 - What is the mass, in grams, of 6.33 mol of NaHC03...Ch. 3.4 - What is the mass, in grams, of (a) 0.50 mol of...Ch. 3.4 - How many chlorine atoms are in 12.2 g of CCL4? a....Ch. 3.4 -
a. How many nitric acid molecules are in 4.20 g...Ch. 3.5 - A 2.144-g sample of phosgene, a compound used as a...Ch. 3.5 - A 5.325-g sample of methyl benzoate, a compound...Ch. 3.5 -
Cyclohexane a commonly used organic solvent, is...Ch. 3.5 - Prob. 3.14.2PECh. 3.5 -
The compound dioxane, which is used as a solvent...Ch. 3.5 -
a. Caproic acid, responsible for the odor of...Ch. 3.6 - Sodium hydroxide reacts with carbon dioxide to...Ch. 3.6 - Decomposition of KCIO3 is sometimes used to...Ch. 3.6 - Propane, C3 H8 (Figure 3.8), is a common fuel used...Ch. 3.6 -
Methanol, CH3OH, reacts with oxygen from air in a...Ch. 3.7 - When 24 mol of methanol and 15 mol of oxygen...Ch. 3.7 - a. When 1.50 mol of Al and 3.00 mol of Cl2 combine...Ch. 3.7 - Molten gallium reacts with arsenic to form the...Ch. 3.7 -
When a 2.00-g strip of zinc metal is placed in...Ch. 3.7 - If 3.00 g of titanium metal is reacted with 6.00 g...Ch. 3.7 - Imagine you are working on ways to improve the...Ch. 3 - The reaction between reactant A (blue spheres) and...Ch. 3 - The following diagram shows the combination...Ch. 3 -
3.3 The following diagram represents the...Ch. 3 -
3.4 The following diagram represents the...Ch. 3 - Glycine, an amino acid used by organisms to make...Ch. 3 - The following diagram represents a...Ch. 3 -
3.7 Nitrogen (N2) and hydrogen (H2) react to form...Ch. 3 -
3.8 Nitrogen monoxide and oxygen react to form...Ch. 3 - Write "true" or "false" for each statement. a. We...Ch. 3 - A key step in balancing chemical equations is...Ch. 3 - Balance the following equations: a. CO(g)...Ch. 3 - Balance the following equations 3. Li(s) + N2(g)...Ch. 3 -
3.13 Balance the following equations:
A14C3(s) +...Ch. 3 -
3.14 Balance the following equations:
a. Ca3P2(s)...Ch. 3 -
3.15 Write balanced chemical equations...Ch. 3 - Prob. 16ECh. 3 - Prob. 17ECh. 3 -
318
a. When a compound containing C, H, and O is...Ch. 3 - Write a balanced chemical equation for the...Ch. 3 -
3.20 Write a balanced chemical equation for the...Ch. 3 - Balance the following equations and indicate...Ch. 3 - Balance the following equations and indicate...Ch. 3 - Determine the formula weights of each of the...Ch. 3 - 3.24 Determine the formula weights of each of the...Ch. 3 - Calculate the percentage by mass of oxygen in the...Ch. 3 - Calculate the percentage by mass of the indicated...Ch. 3 - Based on the following structural formulas,...Ch. 3 - Calculate the percentage of carbon by mass In each...Ch. 3 - Write "true' or 'Yalse' for each statement a- A...Ch. 3 - a. What is the mass, in grams, of one mole of 12C?...Ch. 3 - Without doing any detailed calculations (but using...Ch. 3 - Without doing any detailed calculations {but using...Ch. 3 - What is the mass, m Iqlograms, of an Avogadro“s...Ch. 3 - If Avogadro’s number of pennies is divided equally...Ch. 3 - Calculate the following quantities: a. mass, in...Ch. 3 - Calculate the following quantities: a. mass, in...Ch. 3 - a. What is the mass, in grams, of 2.50 x 10-3 mol...Ch. 3 - a. What is the mass, in grams, of 1.223 mol of...Ch. 3 -
339 The molecular formula of allicin, the...Ch. 3 -
3.40 The molecular formula of aspartame, the...Ch. 3 -
3.41 A sample of glucose, C6H12O6, contains 1.250...Ch. 3 - A sample of the male sex hormone testosterone,...Ch. 3 -
343 The allowable concentration level of vinyl...Ch. 3 - At least 25 g oftetrahydrocannabinol (THC), the...Ch. 3 - Give the empirical formula of each of the...Ch. 3 - Determine the empirical formula of each of the...Ch. 3 - Determine the empirical formulas of the compounds...Ch. 3 - Determine the empirical formulas of the compounds...Ch. 3 -
3.49 A compound whose empirical formula is XF3...Ch. 3 - The compound XCL4contains 75.0% CI by mass What is...Ch. 3 -
3.51 What is the molecular formula of each of the...Ch. 3 - What is the molecular formula of each of the...Ch. 3 - Determine the empirical and molecular formulas of...Ch. 3 - Determine the empirical and molecular formulas of...Ch. 3 - a. Combustion analysis of toluene, a common...Ch. 3 - a. The characteristic odor of pineapple is due to...Ch. 3 -
3.57 Valproic acid, used to treat seizures and...Ch. 3 - Propenoic acid, C3H4O2, is a reactive organic...Ch. 3 -
3.59 Washing soda, a compound used to prepare...Ch. 3 -
3.60 Epsom salts, a strong laxative used in...Ch. 3 - f 3461 Hydrofluoric acid, HF(aq), cannot be stored...Ch. 3 - The reaction between potassium superoxide, KO2,...Ch. 3 -
3,63 Several brands of antacids use Al(OH)3 to...Ch. 3 -
3.64 An iron ore sample contains Fe2O3 together...Ch. 3 - Aluminum sulfides reacts with water to form...Ch. 3 - Calcium hydride reacts with water to form calcium...Ch. 3 -
3.67 Automotive air bags infilate when sodium...Ch. 3 - The complete combustion of octane, Cngs, a...Ch. 3 -
3.69 A piece of aluminum foil 1.00 cm2 and...Ch. 3 - Detonation of nitroglycerin proceeds as follows:...Ch. 3 -
3.71 The combustion of one mole of liquid...Ch. 3 - The combustion of one mole of liquid octane,...Ch. 3 - a. Define the terms limiting reactant and excess...Ch. 3 - Define the terms theoretical yield, actual yield,...Ch. 3 -
3-75 Consider the mixture of ethanol, C2H5OH, and...Ch. 3 - Consider the mixture of propane, C3H8, and O2...Ch. 3 -
3-77 Sodium hydroxide reacts with carbon doxidc...Ch. 3 -
3.78 Aluminum hydroxide reacts with sulfuric acid...Ch. 3 - The fizz produced when an Alka-Seltzer tablet is...Ch. 3 - One of the steps in the commercial procas for...Ch. 3 - Solutions of sodium carbonate and silver nitrate...Ch. 3 - Solutions of sulfuric acid and Iead (ll) acetate...Ch. 3 - When benzene (C6H6) reacts with bromine (Br2),...Ch. 3 - When ethane (C6H6) reacts with chlorine (Cl2), the...Ch. 3 -
3.85 Hydrogen sulfide is an impurity in natural...Ch. 3 -
386 When hydrogen sulfide gas is bubbled into a...Ch. 3 -
387 Write the balanced chemical equations for
a....Ch. 3 - If 1.5 mol C2H5OH, 1.5 mol C3H8, and 1.5 mol...Ch. 3 -
3.89 The effectiveness of nitrogen fertilizers...Ch. 3 -
3.90
a. The molecular formula of acetylsalicylic...Ch. 3 - Very small semiconductor crystals, composed of...Ch. 3 - a. One molecule of the antibiotic penicillin G has...Ch. 3 - Serotonin is a compound that conducts nerve...Ch. 3 -
3.94 The koala dines exclusively on eucalyptus...Ch. 3 -
3.95 Vanillin, the dominant flavoring in vanilla,...Ch. 3 -
3.96 An organic compound was found to contain...Ch. 3 -
3.97 A compound, KBrO,, where x is unknown, is...Ch. 3 - 398 An element X forms an iodide (X13) and a...Ch. 3 - A method used by the U.S. Environmental Protection...Ch. 3 -
3.100 A chemical plant uses electrical energy to...Ch. 3 - The fat stored in a camel’s hump is a source of...Ch. 3 -
3.102 When hydrocarbons are burned in a limited...Ch. 3 -
3.103 A mixture of N2(g) and H2(g) reacts in a...Ch. 3 -
3.104 A mixture containing KClO3, K2CO3, KHCO3,...Ch. 3 - When a mixture of 10.0 g of acetylene (C2H2) and...Ch. 3 -
3.106 The semiconductor gallium arsenide, GaAs,...Ch. 3 -
3.107 Paclitaxel, C47H51NO14, is an anticancer...Ch. 3 -
3.108 Consider a sample of calcium carbonate in...Ch. 3 -
3.109
a. You are given a cube of silver metal...Ch. 3 -
3.110
a. If an automobile travels 225 mi with a...Ch. 3 - Prob. 111IECh. 3 -
3.112 A particular coal contains 2.596 sulfur by...Ch. 3 - Hydrogen cyanide, HCN, is a poisonous gas. The...Ch. 3 -
3.114 The source of oxygen that drives he...Ch. 3 -
3.115 The therrnite reaction, Fe2O3 +Al Al2O3 +...Ch. 3 -
3.116 One of the most bizarre reactions in...
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- 3.83 For the reaction of nitrogen, N2, and hydrogen, H2, to form ammonia, NH3, a student is attempting to draw a particulate diagram, as shown below. Did the student draw a correct representation of the reaction? If not, what was the error the student made?arrow_forwardChlorine exists mainly as two isotopes, 37Cl and 33Cl. Which is more abundant? How do you know?arrow_forwardPropane, C3H8, is the fuel of choice in a gas barbecue. When burning, the balanced equation is C3H8+5O23CO2+4H2O a What is the limiting reactant in cooking with a gas grill? b If the grill will not light and you know that you have an ample flow of propane to the burner, what is the limiting reactant? c When using a gas grill you can sometimes turn the gas up to the point at which the flame becomes yellow and smokey. In terms of the chemical reaction, what is happening?arrow_forward
- 4.69 The pictures below show a molecular-scale view of a chemical reaction between H2 and CO to produce methanol, CH3OH. The box on the left represents the reactants at the instant of mixing, and the box on the right shows what is left once the reaction has gone to completion. Was there a limiting reactant in this reaction? If so, what was it? Write a balanced chemical equation for this reaction. As usual, your equation should use the smallest possible whole number coefficients for all substances.arrow_forwardhat do the coefficients of a balanced chemical equation tell us about the proportions in which atoms and molecules react on an individual (microscopic) basis?arrow_forward3.96 Methyl cyanoacrylate is the chemical name for the substance sold as Super Glue, and it has the chemical formula C5H5NO2. Calculate the number of molecules of this substance in a 1.0-ounce tube of Super Glue, assuming that the glue is 80% methyl cyanoacrylate by mass.arrow_forward
- The present average concentration (mass percent) of magnesium ions in seawater is 0.13%. A chemistry textbook estimates that if 1.00 × 108 tons Mg were taken out of the sea each year, it would take one million years for the Mg concentration to drop to 0.12%. Do sufficient calculations to either verify or refute this statement. Assume that Earth is a sphere with a diameter of 8000 mi, 67% of which is covered by oceans to a depth of 1 mi, and that no Mg is washed back into the oceans at any time.arrow_forwardAccording to the law of conservation of mass, mass cannot be gained or destroyed in a chemical reaction. Why can't you simply add the masses of two reactants to determine the total mass of product? Choose the best answer and explain. One of the reactants could be present in excess, and not all of it will be used to make the product(s). The masses of the reactants must be converted to moles first and then added. Not all chemical reactions follow the law of conservation of mass, especially ones with mixed physical states present. The masses of the two reactants cannot be added until they are each multiplied by their coefficient in the balanced equation. It is only the molar masses that are conserved in chemical reactions, not the actual mass amounts given in the laboratory.arrow_forwardChalky, white crystals in mineral collections are often labeled borax, which has the molecular formula Na2B4O7 10H2O, when actually they are partially dehydrated samples with the molecular formula Na2B4O7 5H2O, which is more stable under the storage conditions. Real crystals of borax are colorless and transparent. (a) Calculate the percent mass that the mineral has lost when it partially dehydrates. (b) Is the percent boron by mass the same in both compounds?arrow_forward
- When washing soda, Na2CO3, reacts with sulfuric acid, H2SO4, the equation is Na2CO3(aq) + H2SO4(aq) CO2(g) + H2O() + Na2SO4(aq) (a) Describe in words the meaning of this chemical equation. (b) Verify that the equation conforms to the law of conservation of matter.arrow_forward3.117 For the oxides of iron, FeO, Fe2O3, and Fe3O4, describe how you would determine which has the greatest percentage by mass of oxygen. Would you need to look up any information to solve this problem?arrow_forward3.115 The average person exhales 1.0 kg of carbon dioxide in a day. Describe how you would estimate the number of CO2 molecules exhaled per breath for this average person.arrow_forward
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