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Concept explainers
(a)
To determine: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound.
Interpretation: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound are to be stated.
Concept introduction: The rules for the naming of
- Firstly the longest carbon chain is chosen and the naming of chain is done accordingly to the number of carbon atoms that are present in the chain.
- Numbering of the chain is done in such a way that the substituent groups are placed at the lowest position.
- Naming of substituent groups is done by replacing–ane with –yl.
- If different types of substituent groups are present, then they will be written in an alphabetical order.
- If a substituent is present more than one time, then prefixes like di, tri, tetra are used depending on the number of times that particular substituent group appears in the chain.
(b)
To determine: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound.
Interpretation: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound are to be stated.
Concept introduction: The rules for the naming of alkanes are stated below.
- Firstly the longest carbon chain is chosen and the naming of chain is done accordingly to the number of carbon atoms that are present in the chain.
- Numbering of the chain is done in such a way that the substituent groups are placed at the lowest position.
- Naming of substituent groups is done by replacing–ane with –yl.
- If different types of substituent groups are present, then they will be written in an alphabetical order.
- If a substituent is present more than one time, then prefixes like di, tri, tetra are used depending on the number of times that particular substituent group appears in the chain.
(c)
To determine: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound.
Interpretation: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound are to be stated.
Concept introduction: The rules for the naming of alkanes are stated below.
- Firstly the longest carbon chain is chosen and the naming of chain is done accordingly to the number of carbon atoms that are present in the chain.
- Numbering of the chain is done in such a way that the substituent groups are placed at the lowest position.
- Naming of substituent groups is done by replacing –ane with –yl.
- If different types of substituent groups are present, then they will be written in an alphabetical order.
- If a substituent is present more than one time, then prefixes like di, tri, tetra are used depending on the number of times that particular substituent group appears in the chain.
(d)
To determine: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound.
Interpretation: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound are to be stated.
Concept introduction: The rules for the naming of alkanes are stated below.
- Firstly the longest carbon chain is chosen and the naming of chain is done accordingly to the number of carbon atoms that are present in the chain.
- Numbering of the chain is done in such a way that the substituent groups are placed at the lowest position.
- Naming of substituent groups is done by replacing –ane with –yl.
- If different types of substituent groups are present, then they will be written in an alphabetical order.
- If a substituent is present more than one time, then prefixes like di, tri, tetra are used depending on the number of times that particular substituent group appears in the chain.
(e)
To determine: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound.
Interpretation: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound are to be stated.
Concept introduction: The rules for the naming of alkanes are stated below.
- Firstly the longest carbon chain is chosen and the naming of chain is done accordingly to the number of carbon atoms that are present in the chain.
- Numbering of the chain is done in such a way that the substituent groups are placed at the lowest position.
- Naming of substituent groups is done by replacing –ane with –yl.
- If different types of substituent groups are present, then they will be written in an alphabetical order.
- If a substituent is present more than one time, then prefixes like di, tri, tetra are used depending on the number of times that particular substituent group appears in the chain.
(f)
To determine: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound.
Interpretation: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound are to be stated.
Concept introduction: The rules for the naming of alkanes are stated below.
- Firstly the longest carbon chain is chosen and the naming of chain is done accordingly to the number of carbon atoms that are present in the chain.
- Numbering of the chain is done in such a way that the substituent groups are placed at the lowest position.
- Naming of substituent groups is done by replacing–ane with –yl.
- If different types of substituent groups are present, then they will be written in an alphabetical order.
- If a substituent is present more than one time, then prefixes like di, tri, tetra are used depending on the number of times that particular substituent group appears in the chain.
(g)
To determine: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound.
Interpretation: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound are to be stated.
Concept introduction: The rules for the naming of alkanes are stated below.
- Firstly the longest carbon chain is chosen and the naming of chain is done accordingly to the number of carbon atoms that are present in the chain.
- Numbering of the chain is done in such a way that the substituent groups are placed at the lowest position.
- Naming of substituent groups is done by replacing–ane with –yl.
- If different types of substituent groups are present, then they will be written in an alphabetical order.
- If a substituent is present more than one time, then prefixes like di, tri, tetra are used depending on the number of times that particular substituent group appears in the chain.
(h)
To determine: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound.
Interpretation: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound are to be stated.
Concept introduction: The rules for the naming of alkanes are stated below.
- Firstly the longest carbon chain is chosen and the naming of chain is done accordingly to the number of carbon atoms that are present in the chain.
- Numbering of the chain is done in such a way that the substituent groups are placed at the lowest position.
- Naming of substituent groups is done by replacing –ane with –yl.
- If different types of substituent groups are present, then they will be written in an alphabetical order.
- If a substituent is present more than one time, then prefixes like di, tri, tetra are used depending on the number of times that particular substituent group appears in the chain.
(i)
To determine: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound.
Interpretation: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound is to be stated.
Concept introduction: The rules for the naming of alkanes are stated below.
- Firstly the longest carbon chain is chosen and the naming of chain is done accordingly to the number of carbon atoms that are present in the chain.
- Numbering of the chain is done in such a way that the substituent groups are placed at the lowest position.
- Naming of substituent groups is done by replacing–ane with –yl.
- If different types of substituent groups are present, then they will be written in an alphabetical order.
- If a substituent is present more than one time, then prefixes like di, tri, tetra are used depending on the number of times that particular substituent group appears in the chain.
(j)
To determine: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound.
Interpretation: The conversion of given Newman projection into equivalent line-angle formula and the IUPAC name of the given compound is to be stated.
Concept introduction: The rules for the naming of alkanes are stated below.
- Firstly the longest carbon chain is chosen and the naming of chain is done accordingly to the number of carbon atoms that are present in the chain.
- Numbering of the chain is done in such a way that the substituent groups are placed at the lowest position.
- Naming of substituent groups is done by replacing –ane with –yl.
- If different types of substituent groups are present, then they will be written in an alphabetical order.
- If a substituent is present more than one time, then prefixes like di, tri, tetra are used depending on the number of times that particular substituent group appears in the chain.
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Chapter 3 Solutions
ORGANIC CHEMISTRY
- 16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してしarrow_forward3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CNarrow_forwardShow work..don't give Ai generated solution...arrow_forward
- Label the spectrum with spectroscopyarrow_forwardQ1: Draw the most stable and the least stable Newman projections about the C2-C3 bond for each of the following isomers (A-C). Are the barriers to rotation identical for enantiomers A and B? How about the diastereomers (A versus C or B versus C)? enantiomers H Br H Br (S) CH3 H3C (S) (R) CH3 H3C H Br A Br H C H Br H3C (R) B (R)CH3 H Br H Br H3C (R) (S) CH3 Br H D identicalarrow_forwardLabel the spectrumarrow_forward
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