ORGANIC CHEMISTRY
9th Edition
ISBN: 9780134645704
Author: WADE AND SIMEK
Publisher: PEARSON
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Question
Chapter 3.15, Problem 3.26P
(a)
Interpretation Introduction
To determine: The name of the given compound.
Interpretation: The information regarding the cis and trans position in cyclohexane is given. The name of the given compound is to be stated.
Concept introduction: The rules for the naming of cycloalkanes are stated below.
- If two different cycloalkanes are present, then the one with the more number of carbon atoms acts as the parent chain.
- If the side chain has more number of carbon atoms, then it acts as the parent chain and the cyclic group becomes the substituent and ends with the word”-yl”.
- The numbering is done in such a manner that the substituent groups occupy the lowest position.
- If different types of substituent groups are present, then they are written in an alphabetical order.
- If a substituent is present more than one time, then prefixes like di, tri, tetra are used depending on the number of times that particular substituent group appears in the given compound.
- If geometrical isomerism is possible in the given compound, then cis and trans are used before the name of the compound.
(b)
Interpretation Introduction
To determine: The name of the given compound.
Interpretation: The information regarding the cis and trans position in cyclohexane is given. The name of the given compound is to be stated.
Concept introduction: The rules for the naming of cycloalkanes are stated below.
- If two different cycloalkanes are present, then the one with the more number of carbon atoms acts as the parent chain.
- If the side chain has more number of carbon atoms then it act as the parent chain and the cyclic group becomes the substituent and ends with the word”-yl”.
- The numbering is done in such a manner that the substituent groups occupy the lowest position.
- If different types of substituent groups are present, then they are written in an alphabetical order.
- If a substituent is present more than one time, then prefixes like di, tri, tetra are used depending on the number of times that particular substituent group appears in the given compound.
- If geometrical isomerism is possible in the given compound, then cis and trans are used before the name of the compound.
(c)
Interpretation Introduction
To determine: The name of the given compound.
Interpretation: The information regarding the cis and trans position in cyclohexane is given. The name of the given compound is to be stated.
Concept introduction: The rules for the naming of cycloalkanes are stated below.
- If two different cycloalkanes are present, then the one with the more number of carbon atoms act as the parent chain.
- If the side chain has more number of carbon atoms, then it acts as the parent chain and the cyclic group becomes the substituent and is ended with the word”-yl”.
- The numbering is done in such a manner that the substituent groups occupy the lowest position.
- If different types of substituent groups are present, then they are written in an alphabetical order.
- If a substituent is present more than one time, then prefixes like di, tri, tetra are used depending on the number of times that particular substituent group appears in the given compound.
- If geometrical isomerism is possible in the given compound, then cis and trans are used before the name of the compound.
(d)
Interpretation Introduction
To determine: The name of the given compound.
Interpretation: The information regarding the cis and trans position in cyclohexane is given. The name of the given compound is to be stated.
Concept introduction: The rules for the naming of cycloalkanes are stated below.
- If two different cycloalkanes are present, then the one with the more number of carbon atoms act as the parent chain.
- If the side chain has more number of carbon atoms, then it acts as the parent chain and the cyclic group becomes the substituent and ends with the word”-yl”.
- The numbering is done in such a manner that the substituent groups occupy the lowest position.
- If different types of substituent groups are present, then they are written in an alphabetical order.
- If a substituent is present more than one time, then prefixes like di, tri, tetra are used depending on the number of times that particular substituent group appears in the given compound.
- If geometrical isomerism is possible in the given compound, then cis and trans are used before the name of the compound.
(e)
Interpretation Introduction
To determine: The name of the given compound.
Interpretation: The information regarding the cis and trans position in cyclohexane is given. The name of the given compound is to be stated.
Concept introduction: The rules for the naming of cycloalkanes are stated below.
- If two different cycloalkanes are present, then the one with the more number of carbon atoms acts as the parent chain.
- If the side chain has more number of carbon atoms, then it acts as the parent chain and the cyclic group becomes the substituent and ends with the word”-yl”.
- The numbering is done in such a manner that the substituent groups occupy the lowest position.
- If different types of substituent groups are present, then they are written in an alphabetical order.
- If a substituent is present more than one time, then prefixes like di, tri, tetra are used depending on the number of times that particular substituent group appears in the given compound.
- If geometrical isomerism is possible in the given compound, then cis and trans are used before the name of the compound.
(f)
Interpretation Introduction
To determine: The name of the given compound.
Interpretation: The information regarding the cis and trans position in cyclohexane is given. The name of the given compound is to be stated.
Concept introduction: The rules for the naming of cycloalkanes are stated below.
- If two different cycloalkanes are present, then the one with the more number of carbon atoms act as the parent chain.
- If the side chain has more number of carbon atoms, then it acts as the parent chain and the cyclic group becomes the substituent and ends with the word”-yl”.
- The numbering is done in such a manner that the substituent groups occupy the lowest position.
- If different types of substituent groups are present, then they are written in an alphabetical order.
- If a substituent is present more than one time, then prefixes like di, tri, tetra are used depending on the number of times that particular substituent group appears in the given compound.
- If geometrical isomerism is possible in the given compound, then cis and trans are used before the name of the compound.
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Initial concentration of iodide in reaction (mA)
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Initial Rate (mA's)
Draw the condensed or line-angle structure for an alkene with the formula C5H10.
Note: Avoid selecting cis-/trans- isomers in this exercise.
Draw two additional condensed or line-angle structures for alkenes with the formula C5H10.
Record the name of the isomers in Data Table 1.
Repeat steps for 2 cyclic isomers of C5H10
Explain why the following names of the structures are incorrect.
CH2CH3
CH3-C=CH-CH2-CH3
a. 2-ethyl-2-pentene
CH3
|
CH3-CH-CH2-CH=CH2
b. 2-methyl-4-pentene
Chapter 3 Solutions
ORGANIC CHEMISTRY
Ch. 3.2 - Using the general molecular formula for alkanes:...Ch. 3.3B - Name the following alkanes and haloalkanes. When...Ch. 3.3B - Write structures for the following compounds. a....Ch. 3.3B - Provide IUPAC names for the following compounds....Ch. 3.3B - Prob. 3.5PCh. 3.3B - Prob. 3.6PCh. 3.3B - Prob. 3.7PCh. 3.3B - Draw the structures of the following compounds. a....Ch. 3.3B - Without looking at the structures, give molecular...Ch. 3.4C - Prob. 3.10P
Ch. 3.7B - Prob. 3.11PCh. 3.7C - Draw a graph similar to Figure 3-9, of the...Ch. 3.8B - Draw a graph similar to Figure 3-11, of the...Ch. 3.9 - Draw a perspective representation of the most...Ch. 3.10C - Give IUPAC names for the following compounds.Ch. 3.10C - Draw the structure and give the molecular formula...Ch. 3.11 - Which of the following cycloalkanes are capable of...Ch. 3.11 - Give IUPAC names for the following cycloalkanes.Ch. 3.12B - The heat of combustion of...Ch. 3.12C - Prob. 3.20PCh. 3.13B - The cyclohexane chair shown in Figure 3-22 has the...Ch. 3.13B - Draw 1,2,3,4,5,6-hexamethylcyclohexane with all...Ch. 3.14 - Prob. 3.23PCh. 3.14 - Prob. 3.24PCh. 3.14 - Draw the most stable conformation of a....Ch. 3.15 - Prob. 3.26PCh. 3.15 - a. Draw both chair conformations of cis-1...Ch. 3.15 - Prob. 3.28PCh. 3.15A - Draw the two chair conformations of each of the...Ch. 3.15B - Draw the most stable conformation of a....Ch. 3.16A - Name the following compounds.Ch. 3.16B - Prob. 3.32PCh. 3 - Prob. 3.33SPCh. 3 - Prob. 3.34SPCh. 3 - 3-35 a. Draw and name the five cycloalkane...Ch. 3 - Draw the structure that corresponds with each...Ch. 3 - Each of the following descriptions applies to more...Ch. 3 - Write structures for a homologous series of...Ch. 3 - Prob. 3.39SPCh. 3 - Construct a graph, similar to Figure 3-11, of the...Ch. 3 - The following names are all incorrect or...Ch. 3 - In each pair of compounds, which compound has the...Ch. 3 - There are eight different five-carbon alkyl...Ch. 3 - Use a Newman projection about the indicated bond...Ch. 3 - a. Draw the two chair conformations of...Ch. 3 - Draw the two chair conformations of each compound,...Ch. 3 - Using what you know about the conformational...Ch. 3 - Prob. 3.48SPCh. 3 - Draw Newman projections along the C3C4 bond to...Ch. 3 - Prob. 3.50SPCh. 3 - The most stable form of the common sugar glucose...Ch. 3 - This is a Newman projection of a substituted...
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