(a) Interpretation: The value of Boltzmann’s constant in units of L ⋅ atm / K is to be calculated. Concept introduction: The term ‘entropy’ is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less order arrangement, then the entropy of the system increases.

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Answer 1

Question

Chapter 3, Problem 3.45E

Interpretation Introduction

(a)

Interpretation:

The value of Boltzmann’s constant in units of L⋅atm/K is to be calculated.

Concept introduction:

The term ‘entropy’ is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less order arrangement, then the entropy of the system increases.

Interpretation Introduction

(b)

Interpretation:

The value of Boltzmann’s constant in units of (cm3⋅mmHg)/K is to be calculated.

Concept introduction:

The term ‘entropy’ is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less order arrangement, then the entropy of the system increases.

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Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction observations conclusions ΔΗ is (pick one) A This reaction is faster above 103. °C than below. AS is (pick one) ΔΗ is (pick one) B This reaction is spontaneous only above -9. °C. AS is (pick one) ΔΗ is (pick one) C The reverse of this reaction is always spontaneous. AS is (pick one) 18 Ar

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Answer 2

Question

Chapter 3, Problem 3.45E

Interpretation Introduction

(a)

Interpretation:

The value of Boltzmann’s constant in units of L⋅atm/K is to be calculated.

Concept introduction:

The term ‘entropy’ is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less order arrangement, then the entropy of the system increases.

Interpretation Introduction

(b)

Interpretation:

The value of Boltzmann’s constant in units of (cm3⋅mmHg)/K is to be calculated.

Concept introduction:

The term ‘entropy’ is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less order arrangement, then the entropy of the system increases.

Expert Solution & Answer

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Answer 3

Question

Chapter 3, Problem 3.45E

Interpretation Introduction

(a)

Interpretation:

The value of Boltzmann’s constant in units of L⋅atm/K is to be calculated.

Concept introduction:

The term ‘entropy’ is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less order arrangement, then the entropy of the system increases.

Interpretation Introduction

(b)

Interpretation:

The value of Boltzmann’s constant in units of (cm3⋅mmHg)/K is to be calculated.

Concept introduction:

The term ‘entropy’ is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less order arrangement, then the entropy of the system increases.

Expert Solution & Answer

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Answer 4

Question

Chapter 3, Problem 3.45E

Interpretation Introduction

(a)

Interpretation:

The value of Boltzmann’s constant in units of L⋅atm/K is to be calculated.

Concept introduction:

The term ‘entropy’ is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less order arrangement, then the entropy of the system increases.

Interpretation Introduction

(b)

Interpretation:

The value of Boltzmann’s constant in units of (cm3⋅mmHg)/K is to be calculated.

Concept introduction:

The term ‘entropy’ is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less order arrangement, then the entropy of the system increases.

Expert Solution & Answer

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Answer 5

Chapter 3, Problem 3.45E

Interpretation Introduction

(a)

Interpretation:

The value of Boltzmann’s constant in units of L⋅atm/K is to be calculated.

Concept introduction:

The term ‘entropy’ is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less order arrangement, then the entropy of the system increases.

Interpretation Introduction

(b)

Interpretation:

The value of Boltzmann’s constant in units of (cm3⋅mmHg)/K is to be calculated.

Concept introduction:

The term ‘entropy’ is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less order arrangement, then the entropy of the system increases.

Answer 6

Chapter 3, Problem 3.45E

Interpretation Introduction

(a)

Interpretation:

The value of Boltzmann’s constant in units of L⋅atm/K is to be calculated.

Concept introduction:

The term ‘entropy’ is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less order arrangement, then the entropy of the system increases.

Answer 7

Chapter 3, Problem 3.45E

Interpretation Introduction

(a)

Interpretation:

The value of Boltzmann’s constant in units of L⋅atm/K is to be calculated.

Concept introduction:

The term ‘entropy’ is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less order arrangement, then the entropy of the system increases.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The value of Boltzmann’s constant in units of (cm3⋅mmHg)/K is to be calculated.

Concept introduction:

The term ‘entropy’ is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less order arrangement, then the entropy of the system increases.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The value of Boltzmann’s constant in units of (cm3⋅mmHg)/K is to be calculated.

Concept introduction:

The term ‘entropy’ is used to represent the randomness in a system. When a system moves from an ordered arrangement to a less order arrangement, then the entropy of the system increases.

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

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Answer 13

Ch. 3 - Decide whether the following processes will be...Ch. 3 - Try to find one additional example of a...Ch. 3 - Consider the following quantities for a...Ch. 3 - Consider the following quantities for a four-step...Ch. 3 - What is the temperature of the low-temperature...Ch. 3 - What is the temperature of the high - temperature...Ch. 3 - Prob. 3.7E Ch. 3 - Explain why the high-temperature reservoir of a...Ch. 3 - Superheated steam is steam with a temperature...Ch. 3 - Prob. 3.10E

Solution Summary: The author explains the value of Boltzmann's constant in units of Lcdot

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