PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
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Chapter 3, Problem 3.43E
Interpretation Introduction
Interpretation:
The figure
Concept introduction:
The efficiency of a machine is defined as the ratio of fruitful output and the total input. The efficiency of a machine is used to determine the effectiveness of the machine. When the efficiency of the machine is high, the machine is very efficient. The efficiency of a machine cannot be
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k₁
Given the reaction R₂
R + R, indicate
k-1
(A). the rate law with respect to R2:
(B). the rate law with respect to R:
d[R₂]
dt
d[R]
dt
Given the reaction R+ Q → P, indicate
(A). the rate law with respect to P:
(B). the rate law with respect to R:
(C). the rate law with respect to Q:
d[P]
dt
d[R]
dt
d[Q]
dt
The reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism: 1) NO + NO ⇄ N2O2 (fast); 2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.
Chapter 3 Solutions
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
Ch. 3 - Decide whether the following processes will be...Ch. 3 - Try to find one additional example of a...Ch. 3 - Consider the following quantities for a...Ch. 3 - Consider the following quantities for a four-step...Ch. 3 - What is the temperature of the low-temperature...Ch. 3 - What is the temperature of the high - temperature...Ch. 3 - Prob. 3.7ECh. 3 - Explain why the high-temperature reservoir of a...Ch. 3 - Superheated steam is steam with a temperature...Ch. 3 - Prob. 3.10E
Ch. 3 - The Carnot cycle is defined as having a certain...Ch. 3 - In thermodynamics, the pathway in a...Ch. 3 - A refrigerator is the reverse of an engine: Work...Ch. 3 - Efficiency is given by equations 3.5, 3.6, and...Ch. 3 - What is the entropy change for an ideal Carnot...Ch. 3 - What is the entropy change for the melting of...Ch. 3 - What is the entropy change for the solidification...Ch. 3 - Explain why the statement No process is 100...Ch. 3 - What is the change in entropy of 1.00mole of water...Ch. 3 - Prob. 3.20ECh. 3 - One mole of He warms up irreversibly at constant...Ch. 3 - Consider a monatomic ideal gas in a piston...Ch. 3 - A 0.500-mol sample of an ideal gas has an initial...Ch. 3 - SO2 in a piston chamber kept in a...Ch. 3 - A normal breath has a volume of about 1L. The...Ch. 3 - An automobile tire contains 15.6L of air at...Ch. 3 - An automobile tire contains 15.6L of air at...Ch. 3 - A sample of ideal gas from a compressed gas...Ch. 3 - Prob. 3.29ECh. 3 - In Example 3.5, a heat capacity of 20.78J/molK was...Ch. 3 - Prob. 3.31ECh. 3 - 4.00L of Ar and 2.50L of He, each at 298K and...Ch. 3 - Dentists might use a mixture of 40N2O and 60O2 as...Ch. 3 - A 5.33-g piece of Cu metal is heated to 99.7C in...Ch. 3 - A sample of 1.00mol of silver at 150C is placed in...Ch. 3 - Prob. 3.36ECh. 3 - What is the change in entropy when 2.22mol of...Ch. 3 - Estimate the entropy change of an 800-lb engine...Ch. 3 - Calculate the molar entropy change of the gas that...Ch. 3 - A normal breath is about 1L in volume. Assume you...Ch. 3 - The first law of thermodynamics is sometimes...Ch. 3 - Troutons rule states that the entropy of boiling...Ch. 3 - Prob. 3.43ECh. 3 - Argue from Boltzmanns definition for entropy that...Ch. 3 - Prob. 3.45ECh. 3 - Which system has the higher entropy? a A clean...Ch. 3 - Which system has the higher entropy? a 1g of solid...Ch. 3 - The absolute entropy of He at 298.15K is...Ch. 3 - The absolute entropy of Kr at 298.15K is...Ch. 3 - The element helium is thought to remain a liquid...Ch. 3 - Order the following substances in order of...Ch. 3 - The molar entropy change for a process is...Ch. 3 - What is the entropy change of a process if ...Ch. 3 - One mole of ideal gas expands isothermally and...Ch. 3 - Why isnt the entropy of elements in their standard...Ch. 3 - Determine the entropy of formation, fS, of the...Ch. 3 - The thermite reaction has solid aluminum powder...Ch. 3 - Prob. 3.58ECh. 3 - Determine the differences in the rxnS under...Ch. 3 - Calcium carbonate has two crystalline forms,...Ch. 3 - The chemical formula for gasoline can be...Ch. 3 - Prob. 3.62ECh. 3 - Prob. 3.63ECh. 3 - Plants take in CO2(g) and H2O(l) and make glucose,...Ch. 3 - Prob. 3.65ECh. 3 - Prob. 3.66ECh. 3 - Plots of Cp/T versus T are used to determine the...
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- When N,N-dimethylaniline is treated with bromine both the ortho and para products are observed. However when treated with a mixture of nitric acid and sulfuric acid only the meta product is observed. Explain these results and support your answer with the appropriate drawings *Hint amines are bases* N HNO3 H2SO4 N NO2 N Br2 N Br + N 8-8-8 FeBr3 Brarrow_forwardDraw a mechanism that explains the formation of compound OMe SO3H 1. Fuming H2SO4arrow_forwardConsider the following two acid-base reactions: OH OHI Based on what you know about the compounds and their acidity, which direction would you expect both of these reactions to proceed? Show your reasoning. A pKa table has been provided in case you need it. Functional group Example pka CHA -50 Alkane -35 Amine : NH3 Alkyne RH 25 Water HO-H 169 16 10 Protonated amines NH 10 5 Carboxylic acids OH Hydrochloric acid HCI A chemist intends to run the following reaction on the three substrates shown below: H₂O R-CI product room temp. Cl Cl (1) (2) (3) They find one will react quickly, one slowly, and one will not react at all. Which is which, and why? HINT: What is the reaction they're trying to do? Does that mechanism tell you anything about why something would be favored?arrow_forward
- NH3 decomposes through an equilibrium reaction between NH3, H2, and N2. Only one of the options is correct:(A). The mechanism of the NH3 decomposition reaction must necessarily involve the collision of two NH3 molecules to induce a rearrangement of the atoms in this molecule.(B). The molecular weight of the NH3 decomposition reaction is 2 since two NH3 molecules must collide.(C). The rate of the NH3 decomposition reaction must be greater than that of NH3 synthesis, since the former requires two molecules to collide and the latter, four.(D). The NH3 decomposition reaction cannot occur in a single step.arrow_forwardGiven the equilibrium A2 + B2 ⇌ 2 AB where k1 is the rate coefficient of the forward reaction and k-1 is the rate coefficient of the reverse reaction, with the forward reaction being first-order in A2 and B2, and the reverse reaction being second-order in AB. Equilibrium will be reached later if the relative values of the constants are:(A) k1 high and k-1 high(B) k1 high and k-1 low(C) k1 low and k-1 high(D) k1 low and k-1 lowarrow_forwardA 2-step reaction has the following mechanism: | 1. (fast) R2 R+R 2. (slow) R+Q K₂ P k_1 What series does it have? (A). v= - = (k + k1 − k-1)[R2][Q] (B). v=-k₁[R₂] + k₁[R]² - k₂[R][Q] (C). v=k₂[R]²[Q]² (D). v = k[R₂]1/2[Q]arrow_forward
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