GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS
3rd Edition
ISBN: 9780134466699
Author: FROST
Publisher: PEARSON
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Chapter 3, Problem 3.104AP
Vinyl acetate is used in the production of safety glass for the automotive industry. Determine the shape around each of the carbon atoms in the Lewis structure of vinyl acetate.
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Synthesis of Ibuprofen-Part 2:
1. Some pain relievers including ibuprofen (MotrinⓇ) and naproxen (Aleve®) are "α-arylpropanoic acids." Look up the structure
of naproxen (AleveⓇ), another a-arylpropionic acid. Using the same reactions that we used for making ibuprofen, show how
to make naproxen from the compound below. Show all intermediates and reagents in your synthesis.
Show how you would prepare ibuprofen starting from p-isobutylbenzene rather than p-isobutylacetophenenone. What reaction
steps would need to change/add?
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Acid Catalyzed Aromatization of Carvone:
1. Starting with the ketone, below, draw a mechanism for the reaction to give the phenol as shown.
H2SO4
HO-
H₂O
2. Why do we use CDCl instead of CHCl, for acquiring our NMR spectra?
3. Why does it not matter which enantiomer of carvone is used for this reaction?
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material?
What other impurities are present in your product and how do you know?
Assign this H NMR
Chapter 3 Solutions
GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS
Ch. 3 - How many electrons are in each energy level of the...Ch. 3 - How many electrons are in each energy level of the...Ch. 3 - How many valence electrons are present in the...Ch. 3 - How many valence electrons are present in the...Ch. 3 - Which of the following elements are stable as...Ch. 3 - Which of the following elements are stable as...Ch. 3 - Prob. 3.7PPCh. 3 - Prob. 3.8PPCh. 3 - Prob. 3.9PPCh. 3 - How are the names of a transition metal atom and...
Ch. 3 - Provide the charge on each element when an ion is...Ch. 3 - Provide the charge on each element when an ion is...Ch. 3 - Prob. 3.13PPCh. 3 - How many protons and electrons are present in the...Ch. 3 - Name the ions in Problem 3.13.Ch. 3 - Prob. 3.16PPCh. 3 - Prob. 3.17PPCh. 3 - Give the name and symbol of the ion with the...Ch. 3 - Prob. 3.19PPCh. 3 - Name the following ions: a. Cu2+ b. SO42 c. HPO42Ch. 3 - Prob. 3.21PPCh. 3 - Prob. 3.22PPCh. 3 - Prob. 3.23PPCh. 3 - Prob. 3.24PPCh. 3 - Prob. 3.25PPCh. 3 - Prob. 3.26PPCh. 3 - Prob. 3.27PPCh. 3 - Prob. 3.28PPCh. 3 - Draw the correct Lewis structure for each of the...Ch. 3 - Draw the correct Lewis structure for each of the...Ch. 3 - Draw the correct Lewis structure for each of the...Ch. 3 - Draw the correct Lewis structure for each of the...Ch. 3 - Determine whether each of the following is a...Ch. 3 - Determine whether each of the following is a...Ch. 3 - Prob. 3.35PPCh. 3 - Prob. 3.36PPCh. 3 - Compare (a) the number of atoms and (b) the number...Ch. 3 - Compare (a) the number of atoms and (b) the number...Ch. 3 - Calculate the following: a. the number of Na atoms...Ch. 3 - Calculate the following: a. the number of S atoms...Ch. 3 - Prob. 3.41PPCh. 3 - Determine the molar mass for the following...Ch. 3 - Prob. 3.43PPCh. 3 - Prob. 3.44PPCh. 3 - For the molecules shown, indicate whether the...Ch. 3 - For the molecules shown, indicate whether the...Ch. 3 - For the molecules in 3.45, determine the shape...Ch. 3 - For the molecules in 3.46, determine the around...Ch. 3 - Prob. 3.49PPCh. 3 - Prob. 3.50PPCh. 3 - Prob. 3.51PPCh. 3 - For each of the following molecules, (1) draw the...Ch. 3 - Prob. 3.53APCh. 3 - Prob. 3.54APCh. 3 - Prob. 3.55APCh. 3 - How many valence electrons are present in the...Ch. 3 - Prob. 3.57APCh. 3 - Prob. 3.58APCh. 3 - Complete the following statements: a. An anion has...Ch. 3 - Prob. 3.60APCh. 3 - Prob. 3.61APCh. 3 - Prob. 3.62APCh. 3 - Prob. 3.63APCh. 3 - Prob. 3.64APCh. 3 - Prob. 3.65APCh. 3 - Prob. 3.66APCh. 3 - Each of the following ions is isoelectronic with a...Ch. 3 - Each of the following ions is isoelectronic with a...Ch. 3 - Prob. 3.69APCh. 3 - Prob. 3.70APCh. 3 - Give the formula for the ionic compound formed by...Ch. 3 - Prob. 3.72APCh. 3 - Prob. 3.73APCh. 3 - Give the formula for each of the following ionic...Ch. 3 - Name the following ionic compounds: a. Na2O b....Ch. 3 - Prob. 3.76APCh. 3 - Prob. 3.77APCh. 3 - Prob. 3.78APCh. 3 - Prob. 3.79APCh. 3 - Prob. 3.80APCh. 3 - Prob. 3.81APCh. 3 - Prob. 3.82APCh. 3 - Prob. 3.83APCh. 3 - Prob. 3.84APCh. 3 - Prob. 3.85APCh. 3 - Explain the difference between a Lewis structure...Ch. 3 - Draw a Lewis structure for each of the following...Ch. 3 - Draw a Lewis structure for each of the following...Ch. 3 - Prob. 3.89APCh. 3 - Give the name of each of the following covalent...Ch. 3 - Explain the difference between an ionic bond and a...Ch. 3 - What are the units of Avogadros number?Ch. 3 - Prob. 3.93APCh. 3 - Prob. 3.94APCh. 3 - What is the mass of 4.00 moles of the following?...Ch. 3 - How many atoms or molecules are in 5.0 moles of...Ch. 3 - A pencil mark (made with graphite, a form of...Ch. 3 - Prob. 3.98APCh. 3 - Prob. 3.99APCh. 3 - Prob. 3.100APCh. 3 - Aspartic acid, a naturally occurring amino acid...Ch. 3 - Cyanoacrylic acid is one of the compounds used to...Ch. 3 - Methyl isocyanate is used in the manufacturing of...Ch. 3 - Vinyl acetate is used in the production of safety...Ch. 3 - Identify the more electronegative atom in each of...Ch. 3 - Identify the more electronegative atom in each of...Ch. 3 - Prob. 3.107APCh. 3 - Prob. 3.108APCh. 3 - Prob. 3.109CPCh. 3 - Prob. 3.110CPCh. 3 - Prob. 3.111CPCh. 3 - Vinyl chloride, C2H3Cl, is used in the production...Ch. 3 - One of the most common compounds used in...Ch. 3 - Prob. 1IA.1QCh. 3 - Prob. 1IA.2QCh. 3 - Prob. 1IA.3QCh. 3 - Prob. 1IA.4QCh. 3 - Prob. 1IA.5QCh. 3 - Prob. 1IA.6QCh. 3 - Prob. 1IA.7QCh. 3 - Prob. 1IA.8QCh. 3 - Prob. 2IA.1QCh. 3 - Complete the following table: Molecular Formula...Ch. 3 - Complete the following table: Molecular Formula...Ch. 3 - Based on the tables in questions 2 and 3, does the...Ch. 3 - Prob. 3IA.1QCh. 3 - Prob. 3IA.2QCh. 3 - Draw the Lewis structure for ammonia. NH3. Show...Ch. 3 - Draw the Lewis structure for H2O. Show the...Ch. 3 - Draw the Lewis structure for carbon dioxide. What...Ch. 3 - Draw the Lewis structure for carbon tetrachloride,...Ch. 3 - Prob. 3IA.7QCh. 3 - Using a dipole moment arrow (), indicate the...Ch. 3 - Find out which cations and anions are important in...
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